Hydrogen Fuel Receiver Protection with 1 ppm Contaminant Detection

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Solution Overview

Problem

Current protective systems for hydrogen fuel cells are inadequate in detecting and preventing contamination, particularly water vapor, which can lead to reduced operation time and degradation, due to low sensitivity and slow measurement times, hindering the widespread adoption of hydrogen fuel cells.

Innovation Solution

A flow-through protective system with a controllable valve and a sensory unit equipped with semiconductor, terahertz, and photonic spectrometers, allowing for rapid detection of contaminants at the 1 ppm level, ensuring smooth refueling by regulating gas conditions and using multiple sensors for enhanced accuracy and sensitivity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If conventional sensors are used for contaminant detection, then the system structure is simple, but the measurement precision and sensitivity are insufficient to detect contaminants at 1 ppm level

Engineering Contradiction:
Improvecontaminant detection sensitivityVSAvoidsensory unit structure
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The patent combines multiple sensor types (subterahertz semiconductor sensor, terahertz spectrometer, and photonic spectrometer) into a single sensory unit. This merging of different sensing technologies enables the system to detect contaminants at 1 ppm level by leveraging the complementary strengths of each sensor type, thereby achieving high measurement precision while managing device complexity through integrated design.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The sensory unit is designed with multi-functional capabilities by incorporating sensors that operate across different frequency bands (subterahertz, terahertz, and photonic ranges). This universal approach allows a single sensory unit to detect various types of contaminants simultaneously, improving measurement precision without requiring multiple separate detection systems.

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Loss of time

If conventional thermal resistance sensors are used, then the device complexity is low, but the measurement time is too long causing significant negative impact on receiver

Engineering Contradiction:
Improvemeasurement timeVSAvoidcontaminant detection accuracy
Core Design Contradiction:
Loss of timeVSMeasurement precision

Solution Approach 1:

The system performs preliminary sampling of hydrogen fuel through the branching unit before actual measurement. This preliminary action allows the sensory unit to be pre-loaded with a representative sample, enabling rapid analysis without delaying the main measurement process. The sampling occurs in parallel with system operation, reducing overall measurement time while maintaining detection accuracy.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The protective system operates continuously by maintaining a constant flow of hydrogen through the branching unit to the sensory unit. This continuous operation eliminates idle measurement cycles and ensures that contaminant detection is performed without interruption, thereby reducing loss of time while maintaining high measurement precision through uninterrupted monitoring.

Inventive Principle:
Principle #20Continuity of useful action

3Productivity

If measurement systems with long analysis time are used, then the sensor complexity is low, but the productivity of refuelling process is reduced

Engineering Contradiction:
Improverefuelling speedVSAvoidsensory unit configuration
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The measurement system is segmented into independent functional modules: a branching unit that separates a portion of the hydrogen flow, a sensory unit with multiple sensors operating in parallel, and a control unit. This segmentation allows each module to operate independently and simultaneously, enabling rapid contaminant detection without bottlenecking the overall refuelling process, thereby improving productivity while managing device complexity through modular architecture.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The system uses a branching unit to divert only a partial flow of hydrogen (not the entire flow) to the sensory unit for analysis. This partial action approach allows the majority of the refuelling process to continue uninterrupted while still obtaining sufficient sample for accurate contaminant detection, thereby maintaining high refuelling speed while using a moderately complex sensory configuration.

Inventive Principle:
Principle #16Partial or excessive action

4Reliability

If simple pressure sensors are used, then the ease of operation is high, but the reliability of contamination detection is insufficient

Engineering Contradiction:
Improvecontaminant detection reliabilityVSAvoidsystem control complexity
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The control unit receives signals from all sensor types (subterahertz, terahertz, and photonic) and processes this feedback information to make informed decisions about contaminant presence. The feedback mechanism integrates data from multiple sensing modalities, cross-validating results to improve detection reliability. The control unit automatically adjusts system operation based on sensor feedback, maintaining ease of operation despite the complex multi-sensor configuration.

Inventive Principle:
Principle #23Feedback

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The system effectively cuts off contaminated hydrogen supply, providing real-time protection and maintaining fuel cell performance by utilizing subterahertz and terahertz spectrometers to detect contaminants, ensuring stable measurement conditions and high sensitivity, thus preventing detrimental effects on the fuel cells.

Implementation Method 1

a sensory unit, comprising a measuring chamber with a semiconductor sensor with an operating band falling within the range of 100 GHz to 1000 GHz and at least one sensor chosen from the group comprising a terahertz or photonic spectrometer

Methodology Applied
Scientific EffectAbsorption Spectroscopy: Absorption Spectroscopy

Data Source

PatentEP4111516B1Flow-through protective system of hydrogen fuel receiver and method of protection of hydrogen fuel receiver
Publication Date: 2023.12.06 INST WYSOKICH CISNIEN POLSKIEJ AKADI NAUK
  • EP4111516B1 patent drawingFigure 1~2
  • EP4111516B1 patent drawingFigure 3
  • EP4111516B1 patent drawingFigure 4a

AI summary

A flow-through protective system of hydrogen fuel receiver comprising a line (H2) for carrying hydrogen fuel, secured with a protective valve (VZ), wherein on the line (H2) a branching unit (T1) is provided, discharging a part of the hydrogen fuel to a sensory unit (K1), and a control unit (C1) receiving on the input a signal from the sensory unit (K1) and having an output connected to a control input of the protective valve (VZ), according to the invention is characterized in that the sensory unit (K1) comprises a measuring chamber with at least one sensor chosen from the group comprising: subteraherz, teraherz and photonic spectrometer. A method of protection of hydrogen fuel receiver comprising a detection of transgression of parameters and cutting off the supply of hydrogen by closing a controllable valve, according to the invention is characterized in that a system according to the invention is used in it, and hydrogen supply in a line (H2) is cut off if a molar concentration of contaminants is detected above a predefined value.