Multi-Sensor Hydrogen Gas Detection With Cross-Sensitivity Correction

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Solution Overview

Problem

Conventional hydrogen sensors in automotive engineering face challenges such as inadequate response time, limited measuring range, cross-sensitivity to other gases, and high electronic packaging costs, which hinder their effectiveness in accurately detecting hydrogen concentrations in fuel cell vehicles.

Innovation Solution

A multi-sensor system comprising a heat conductivity sensor, a semiconducting metal oxide sensor, and additional sensors for relative humidity, temperature, and pressure, integrated with an electronic evaluation unit using machine learning algorithms, particularly artificial neural networks, to correct and optimize sensor signals for precise hydrogen fraction detection.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If conventional sensor elements (heat conductivity, catalytic pellistor, electrochemical cell, semiconducting metal oxide, chemiresistor, field effect transistor) are used for hydrogen detection, then the sensor can detect hydrogen concentration, but the response time is inadequate and cross-sensitivity to other gases (helium, volatile organic components) occurs

Engineering Contradiction:
Improvehydrogen detection accuracyVSAvoidresponse time
Core Design Contradiction:
Measurement precisionVSLoss of time

Solution Approach 1:

The patent combines multiple sensor elements (heat conductivity sensor, semiconducting metal oxide sensor, and at least one additional sensor for a different physical property) into a single sensor system. This merging allows the system to leverage the strengths of each sensor type while compensating for their individual weaknesses, achieving both fast response time and high measurement precision for hydrogen detection.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The sensor system is designed to detect multiple properties of the fluid medium simultaneously - heat conductivity, electrical resistance (from metal oxide), and at least one additional physical property. This multi-functionality enables the system to distinguish hydrogen from other gases more effectively while maintaining fast response characteristics.

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Adaptability or versatility

If conventional sensor elements are used for hydrogen detection, then the sensor can operate in various conditions, but the measuring range is limited above the minimum measuring range

Engineering Contradiction:
Improveoperating condition rangeVSAvoidmeasuring range
Core Design Contradiction:
Adaptability or versatilityVSMeasurement precision

Solution Approach 1:

By merging multiple sensor elements with different detection mechanisms, the system achieves extended measuring range capability. Each sensor element contributes to detecting different concentration ranges or different gas compositions, allowing the combined system to maintain precision across a broader measuring range while adapting to various operating conditions.

Inventive Principle:
Principle #5Merging (Combining)

3Measurement precision

If conventional sensor elements are used for hydrogen detection, then the sensor can provide basic detection capability, but cross-sensitivity with respect to further components such as helium or volatile organic components occurs

Engineering Contradiction:
Improvehydrogen detection capabilityVSAvoidcross-sensitivity to other gases
Core Design Contradiction:
Measurement precisionVSObject-affected harmful factors

Solution Approach 1:

The detection task is segmented across multiple sensor elements, each responsible for detecting specific physical properties. The heat conductivity sensor detects one aspect of the gas composition, the metal oxide sensor detects another, and the additional sensor detects a third physical property. This segmentation allows the system to differentiate hydrogen from other gases like helium or volatile organic components by analyzing the pattern of responses across all sensors.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The additional sensor element acts as an intermediary that detects a physical property different from the first two sensors. This intermediary sensor provides complementary information that helps distinguish hydrogen signals from cross-sensitivity effects of other gases, enabling more accurate hydrogen detection despite the presence of interfering components.

Inventive Principle:
Principle #24Intermediary (Mediator)

4Measurement precision

If conventional sensor elements are used for hydrogen detection, then the sensor can provide basic measurement function, but costly electronic packaging is required

Engineering Contradiction:
Improvesensor measurement functionVSAvoidelectronic packaging cost
Core Design Contradiction:
Measurement precisionVSEase of manufacture

Solution Approach 1:

The patent merges multiple sensor elements into a single integrated sensor unit with shared packaging and electronics. Instead of requiring separate packaging for each sensor type, the system combines them in a unified structure, reducing the overall packaging complexity and cost while maintaining the measurement precision benefits of multiple sensor elements.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The system achieves accurate hydrogen concentration measurement with low error (<0.1 vol%) and fast response time (<1 second) by leveraging machine learning to account for cross-sensitivity and environmental factors, optimizing sensor performance and reducing costs.

Implementation Method 1

a first sensor element that is designed to detect a heat conductivity of the fluid medium and to output a first measuring signal

Methodology Applied
Scientific EffectHeat conductivity: Conduction (thermal)

Implementation Method 2

The MOX sensor element is made up of a semiconducting metal oxide such as SnO2 or WO3, whose electrical resistance decreases when a gas having a chemically reducing effect, for example hydrogen, methane, or water vapor, is contained in air

Methodology Applied
Scientific EffectElectrical resistance change: Electrical Resistance

Data Source

PatentUS20230361325A1Sensor for detecting at least one property of a fluid medium in at least one measuring chamber
Publication Date: 2023.11.09 ROBERT BOSCH GMBH
  • US20230361325A1 patent drawing

AI summary

A sensor for detecting at least one property of a fluid medium in at least one measuring chamber, for detecting an H2 fraction in a measuring gas. The sensor includes at least a first sensor element to detect a heat conductivity of the fluid medium and output a first measuring signal, a second sensor element including a semiconducting metal oxide and designed to output a second measuring signal, a third sensor element for detecting a physical property of the fluid medium, the third sensor element differing from the first sensor element and the second sensor element with regard to the detected physical property and being designed to output a third measuring signal, and an electronic evaluation unit for evaluating the first, second, and third measuring signal. The electronic evaluation unit is designed to change operating parameters of the first and/or second and/or third sensor element.