Hydrogen Sensor Zeolite Adsorption Water Vapor

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Solution Overview

Problem

Existing hydrogen sensors are not reliable in determining hydrogen content due to interference from water and water vapor, which can lead to inaccurate measurements and potential explosive hydrogen/oxygen mixtures.

Innovation Solution

A hydrogen sensor with a housing containing a cavity and a sorption element with open pores, specifically zeolite, placed at the passage opening to absorb water vapor, and a heater for regeneration, along with a temperature sensor and optional secondary sorption and heating elements for continuous operation, to prevent water interference and ensure accurate hydrogen detection.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If water and water vapor are allowed to enter the sensor cavity, then the sensor structure remains simple and open, but measurement accuracy deteriorates due to interference with hydrogen detection

Engineering Contradiction:
Improvehydrogen content measurement accuracyVSAvoidsensor structure complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The patent employs a sorption element with porous structure (such as zeolite or molecular sieve) placed in the passage opening. The porous material allows hydrogen molecules to pass through while adsorbing water vapor molecules due to their different molecular sizes and adsorption properties, thus achieving selective filtration without complex mechanical structures

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The sorption element acts as an intermediary component between the external environment and the sensor cavity. It selectively interacts with water vapor molecules through adsorption while permitting hydrogen molecules to pass through, thereby protecting the measurement element from water interference without directly blocking the hydrogen detection path

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If a sorption element is placed in the passage opening to block water vapor, then measurement reliability improves, but device complexity increases due to additional components

Engineering Contradiction:
Improveoperational reliability of hydrogen detectionVSAvoidnumber of sensor components
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The sorption element serves multiple functions simultaneously: it acts as a water vapor filter, a protective barrier for the measurement element, and can be integrated with the housing structure. This multi-functionality reduces the need for separate protective components, thereby limiting the increase in device complexity

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The patent integrates the sorption element directly into the passage opening structure of the housing, merging the filtration function with the structural component. This integration approach eliminates the need for separate filter housings or mounting mechanisms, thus minimizing the increase in device complexity

Inventive Principle:
Principle #5Merging (Combining)

3Measurement precision

If the sorption element is continuously used to absorb water vapor, then measurement accuracy is maintained, but the sorption element becomes saturated and requires regeneration

Engineering Contradiction:
Improveconsistent hydrogen measurement accuracyVSAvoidtime for sorption element regeneration
Core Design Contradiction:
Measurement precisionVSLoss of time

Solution Approach 1:

The patent implements periodic heating cycles to regenerate the sorption element. During normal operation, the sorption element filters water vapor; periodically, it is heated to desorb accumulated moisture and restored to its drying capacity. This periodic action ensures continuous measurement accuracy while managing the regeneration requirement

Inventive Principle:
Principle #19Periodic action

Solution Approach 2:

The sorption element is designed to be replaceable or regenerable. When saturated, it can be removed, regenerated through heating, and reused. This approach allows the system to maintain high measurement precision by replacing or regenerating the sorption element rather than attempting to continuously operate it beyond saturation

Inventive Principle:
Principle #34Discarding and recovering

4Reliability

If the passage opening is completely closed by the sorption element to prevent water entry, then measurement reliability improves, but gas transport to the cavity is restricted

Engineering Contradiction:
Improveprotection against water interferenceVSAvoidgas transport efficiency to sensor cavity
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The sorption element utilizes a porous structure that provides numerous pathways for gas molecules to pass through. While the pores are small enough to adsorb water vapor, they remain large enough to allow efficient transport of hydrogen molecules to the sensor cavity, thus maintaining productivity while improving reliability

Inventive Principle:
Principle #31Porous materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively prevents water interference, allowing for reliable hydrogen content measurement by ensuring only hydrogen enters the sensor, enhancing operational reliability and enabling continuous operation with regeneration of the sorption elements.

Implementation Method 1

a first sorption element for sorption of water and/or water vapor

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

a first heater for bakeout of the first sorption element

Methodology Applied
Scientific EffectDesorption: Desorption

Data Source

PatentUS20240027412A1Hydrogen sensor
Publication Date: 2024.01.25 INFINEON TECHNOLOGIES AG
  • US20240027412A1 patent drawing
  • US20240027412A1 patent drawing
  • US20240027412A1 patent drawing

AI summary

What is disclosed is a hydrogen sensor (100) having a housing (101) that includes a cavity (102) and has a passage opening (103) from the cavity (102) to a gas connection of the hydrogen sensor (100) or an environment, having a first hydrogen sensor element (104), disposed in the cavity (102), for measurement of a hydrogen content in the cavity (102), having a first sorption element (105) for sorption of water and/or water vapor, especially an adsorption element (105) for adsorption of water and/or water vapor, and having a first heater (106) for bakeout of the first sorption element (105), wherein the first sorption element (105) has open pores and is disposed in the passage opening (103).