Hydrogen Sorbent Leak Detection via Thermal Monitoring

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Solution Overview

Problem

Existing hydrogen leak detection methods in devices operated with hydrogen, such as condensing boilers, require frequent maintenance and do not effectively prevent the accumulation of hazardous hydrogen concentrations without additional ventilation systems, which are costly and prone to contamination.

Innovation Solution

A method utilizing a sorbent with integrated temperature sensors to absorb and detect hydrogen leaks, where the sorbent can absorb up to 90% of escaping hydrogen within minutes, allowing for early detection and safe absorption, reducing the risk of explosive mixtures without the need for regular maintenance or additional ventilation systems.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If electrochemical hydrogen sensors are used for leak detection, then hydrogen leakage can be detected, but the sensors require regular maintenance and calibration

Engineering Contradiction:
Improvehydrogen leak detection capabilityVSAvoidmaintenance requirement
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The patent replaces electrochemical sensors with a thermal-based detection system using temperature sensors to monitor heat release from hydrogen combustion. This substitution eliminates the maintenance issues of electrochemical sensors while maintaining reliable leak detection capability through passive thermal monitoring.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The system uses the exothermic combustion of leaked hydrogen itself as the detection mechanism. The hydrogen leak automatically generates heat that is detected by temperature sensors, requiring no active sensing components that need calibration or maintenance. The leaked substance serves its own detection purpose.

Inventive Principle:
Principle #25Self-service

2Reliability

If electrochemical gas sensors are used to detect hydrogen leaks, then leaks can be detected, but contamination from sulfur-containing odorants damages the sensors

Engineering Contradiction:
Improvehydrogen leak detectionVSAvoidsensor contamination
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent replaces electrochemical sensors that are vulnerable to chemical contamination with inert temperature sensors. The thermal detection method is immune to sulfur-containing odorants and other chemical contaminants, as temperature measurement does not involve chemical reactions with the sensed substance.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Object-affected harmful factors

If ventilation systems are installed to remove hydrogen buildup, then hydrogen accumulation can be prevented, but the systems require regular maintenance and are costly

Engineering Contradiction:
Improvehydrogen accumulation riskVSAvoidventilation system requirement
Core Design Contradiction:
Object-affected harmful factorsVSDevice complexity

Solution Approach 1:

The patent extracts the active ventilation system and replaces it with a passive thermal detection approach. Instead of actively removing hydrogen through mechanical ventilation, the system passively detects leaks through temperature monitoring of combusted hydrogen, eliminating complex mechanical components.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent replaces mechanical ventilation systems with a thermal-field-based detection system. The complex mechanical ventilation infrastructure is substituted with simple temperature sensors that monitor the thermal signature of hydrogen combustion, dramatically reducing system complexity.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

4Object-affected harmful factors

If sorbent is used to absorb hydrogen leaks, then hydrogen can be absorbed and detected, but the sorbent requires replacement after use

Engineering Contradiction:
Improvehydrogen concentration reductionVSAvoidsorbent service life
Core Design Contradiction:
Object-affected harmful factorsVSDuration of action of stationary object

Solution Approach 1:

The patent utilizes the phase transition and exothermic reaction of hydrogen combustion. Instead of using sorbent materials that physically absorb hydrogen and require replacement, the system detects the thermal energy released during hydrogen's phase change from gas to combustion products, providing continuous detection without consumable materials.

Inventive Principle:
Principle #36Phase transitions

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides reliable, low-maintenance hydrogen leak detection and absorption, reducing the risk of hazardous concentrations and eliminating the need for costly ventilation systems, while allowing for easy replacement and regeneration of the sorbent.

Implementation Method 1

a predefinable quantity of hydrogen sorbent is arranged in at least one area of the device where escaping hydrogen can concentrate

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

the temperature in the sorbent is measured with at least one temperature sensor and transmitted to a safety electronics system

Methodology Applied
Scientific EffectTemperature measurement:

Data Source

PatentEP4137737A1Method and assembly for detecting hydrogen leakage, computer program product and use of an absorbent
Publication Date: 2023.02.22 VAILLANT GMBH(DE)
  • EP4137737A1 patent drawingFigure 1
  • EP4137737A1 patent drawing
  • EP4137737A1 patent drawing

AI summary

The invention relates to a method and an arrangement for detecting a hydrogen leak in a hydrogen-powered device (1; 2; 3), wherein a predefinable quantity of hydrogen sorbent (10.1, 10.2; 11; 12; 13) is arranged in at least one area (27; 28; 29; 30) of the device (1; 2; 3) where escaping hydrogen can concentrate, and wherein the temperature in the sorbent (10.1, 10.2; 11; 12; 13) is measured by at least one temperature sensor (17.1, 17.2; 18; 19; 20, 21; 22) and transmitted to a safety electronics unit (25). The present invention enables safe and low-maintenance monitoring of hydrogen-powered devices for leaks and simultaneously reduces the risks associated with a leakage. In addition, the use of a sorbent (10.1, 10.2; 11; 12; 13) on a hydrogen-powered device (1; 2; 3) for capturing or storing a hydrogen leak.