Hydrogen Sulfide Reactor Control for Sulfur Excess Suppression

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Conventional methods for producing hydrogen sulfide face inefficiencies due to local sulfur excess states in the reaction tank, which inhibit the reaction between sulfur and hydrogen gas.

Innovation Solution

A method and device that measure the sulfur amount in the reaction tank and adjust the supply of hydrogen gas accordingly to prevent local sulfur excess, maintaining constant internal pressure and using a porous material like activated alumina to promote the reaction.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If sulfur vapor supply is increased to maintain reaction throughput, then productivity is improved, but local sulfur excess state occurs reducing reaction efficiency

Engineering Contradiction:
Improvereaction throughputVSAvoidlocal sulfur excess state
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The patent implements a feedback control system where sulfur amount measurement units continuously monitor the sulfur content in the reaction tank, and the supply adjustment unit automatically adjusts the sulfur vapor supply rate based on these measurements. This closed-loop feedback mechanism prevents local sulfur excess states while maintaining high productivity by dynamically balancing sulfur supply with reaction consumption rate.

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The patent changes the supply parameters of sulfur vapor and hydrogen gas based on real-time sulfur amount measurements. By adjusting the supply rate parameters dynamically rather than using fixed rates, the system optimizes the gas supply to match reaction conditions, preventing sulfur excess while maintaining throughput.

Inventive Principle:
Principle #35Parameter changes

2Productivity

If sulfur vapor supply is increased to maintain reaction throughput, then productivity is improved, but hydrogen sulfide production efficiency deteriorates

Engineering Contradiction:
Improvereaction throughputVSAvoidreaction efficiency reduction
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The feedback control system measures sulfur amount in real-time and adjusts sulfur vapor supply accordingly, ensuring optimal sulfur-to-hydrogen ratio for maximum hydrogen sulfide production efficiency. This prevents the sulfur excess condition that would otherwise reduce reaction efficiency while maintaining high throughput.

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The system transitions from static fixed-rate gas supply to dynamic supply rates that adapt to changing reaction conditions. The sulfur vapor supply rate is continuously adjusted based on real-time sulfur amount measurements, optimizing the reaction efficiency at each moment while maintaining overall productivity.

Inventive Principle:
Principle #15Dynamics

3Productivity

If sulfur vapor supply rate is increased, then productivity is improved, but uniform gas interaction is compromised

Engineering Contradiction:
Improvereaction throughputVSAvoidgas mixture uniformity
Core Design Contradiction:
ProductivityVSStability of the object's composition

Solution Approach 1:

The system uses dynamic adjustment of sulfur vapor supply rate based on real-time feedback to maintain uniform gas interaction. By adapting the supply rate to current reaction conditions rather than using a fixed high rate, the system ensures proper mixing and uniform interaction between sulfur vapor and hydrogen gas throughout the reaction tank.

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The supply parameters of sulfur vapor are dynamically changed based on measured sulfur amounts, optimizing the gas supply conditions to maintain uniformity. This parameter adjustment ensures that sulfur vapor is supplied at rates that promote uniform mixing and interaction with hydrogen gas, preventing localized excess regions.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach suppresses sulfur excess states, enhancing the reaction efficiency and hydrogen sulfide generation by promoting uniform gas interaction.

Implementation Method 1

the sulfur amount measurement unit measures the amount of sulfur by infrared rays

Methodology Applied
Scientific EffectInfrared absorption: Absorption (EM radiation)

Implementation Method 2

a porous material is installed in the reaction tank. the porous material includes activated alumina

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 3

a porous material is installed in the reaction tank. the porous material includes activated alumina

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 4

a step of heating sulfur in a molten sulfur tank to generate sulfur gas

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 5

a step of heating sulfur in a molten sulfur tank to generate sulfur gas

Methodology Applied
Scientific EffectMelting: Melting

Data Source

PatentEP4647397A1Method for producing hydrogen sulfide and hydrogen sulfide production device
Publication Date: 2025.11.12 FURUKAWA COMPANY
  • EP4647397A1 patent drawingFigure 1
  • EP4647397A1 patent drawingFigure 2
  • EP4647397A1 patent drawingFigure 3

AI summary

A method for producing hydrogen sulfide, in which hydrogen sulfide is synthesized by causing sulfur gas and hydrogen gas to react in a reaction tank (101), the method comprising: a step (A) of supplying a mixed gas of sulfur gas and hydrogen gas to the reaction tank (101) ; a step (B) of supplying hydrogen gas to the reaction tank (101); and a step (C) of synthesizing hydrogen sulfide by causing sulfur gas and hydrogen gas to react, wherein an amount of sulfur in the reaction tank (101) is measured, and a supply amount of the hydrogen gas in the step (B) is adjusted based on a result of the measurement.