Hydrogen Sulfide Test Kit With CO2 Bubble-Assisted Detection

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Solution Overview

Problem

Current methods for detecting hydrogen sulfide in aqueous samples are limited to offsite testing and lack accuracy, especially in detecting low concentrations, posing health risks due to hydrogen sulfide's odorless nature and corrosive properties.

Innovation Solution

A hydrogen sulfide test kit comprising citric acid and sodium bicarbonate powders, stored separately to prevent premature reaction, which are added to an aqueous sample to release hydrogen sulfide into gas form, allowing detection using a color-changing test paper.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If acid displacement procedure with gas chromatography is used to detect hydrogen sulfide, then detection accuracy is improved, but portability and ease of operation deteriorate (offsite testing only)

Engineering Contradiction:
Improvedetection accuracyVSAvoidportability
Core Design Contradiction:
Measurement precisionVSEase of operation

Solution Approach 1:

The test system is divided into separate functional components: reactant powders (citric acid and sodium bicarbonate) in one container, and test paper in another. This segmentation allows the complex analytical function to be distributed across simple, portable components that can be easily handled and transported while maintaining detection accuracy through the chemical reaction mechanism.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent introduces an intermediary chemical reaction system using citric acid and sodium bicarbonate powders that react to produce CO2 bubbles. These bubbles serve as a mediator to strip hydrogen sulfide from the water sample and transfer it to the test paper, enabling accurate detection without requiring complex gas chromatography equipment.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Ease of operation

If dip strip techniques are used for hydrogen sulfide detection, then portability is improved, but measurement precision deteriorates (low accuracy)

Engineering Contradiction:
ImproveportabilityVSAvoiddetection accuracy
Core Design Contradiction:
Ease of operationVSMeasurement precision

Solution Approach 1:

The patent changes the operational parameters of the test system by using a two-stage process: first generating CO2 bubbles through chemical reaction to actively strip and concentrate hydrogen sulfide from the sample, then transferring the gas to the test paper. This parameter change (from passive dipping to active gas stripping) maintains portability while significantly improving detection accuracy and resolution.

Inventive Principle:
Principle #35Parameter changes

3Productivity

If citric acid and sodium bicarbonate are stored together to enable quick testing, then productivity is improved, but reliability deteriorates (premature reaction)

Engineering Contradiction:
Improvetesting speedVSAvoidreaction stability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The reactant powders are segmented into separate storage compartments within the same device. This physical separation prevents premature reaction while maintaining quick access during testing. The segmentation allows the system to be both reliable (no premature reaction) and productive (quick testing when needed).

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

One of the reactant powders (sodium bicarbonate) is extracted and stored separately from citric acid in a dedicated compartment. This extraction eliminates the risk of premature reaction between the two chemicals while allowing both to be readily available for immediate use when testing is required.

Inventive Principle:
Principle #2Taking out (Extraction)

Data Source

PatentUS20250216367A1Hydrogen sulfide test kit and method for detecting hydrogen sulfide in an aqueous sample
Publication Date: 2025.07.03 HACH
  • US20250216367A1 patent drawing
  • US20250216367A1 patent drawing

AI summary

A hydrogen sulfide test kit includes a first reactant powder that includes citric acid, a second reactant powder that includes sodium bicarbonate, and a test paper that changes color upon contact with hydrogen sulfide. The first and second reactant powders are physically separated from each other. A method of using the hydrogen sulfide test kit and a method for detecting hydrogen sulfide in an aqueous sample bot include allowing the citric acid and the sodium bicarbonate to react in the aqueous sample to form air bubbles that release any hydrogen sulfide in the aqueous sample into gas form; contacting the released hydrogen sulfide in gas form, if present, with the test paper; and detecting the presence of hydrogen sulfide in the aqueous sample based on the color of the test paper.