2D-Coated Hydrogen Tanks and Pipes for Leak Barrier Adhesion

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Solution Overview

Problem

Hydrogen leaks through the walls of tanks and distribution pipes due to the small size of hydrogen molecules, leading to potential explosions and hydrogen embrittlement, which existing barrier layers do not adequately prevent, and existing ventilation or neutralization systems increase the mass of hydrogen distribution installations, particularly in aircraft applications.

Innovation Solution

A hydrogen distribution system where at least one surface of the hydrogen tank or distribution pipe is coated with a two-dimensional material mixed with a polydopamine-type polymer, forming an impermeable barrier to hydrogen and improving adhesion properties, using materials like graphene, graphene oxide, or Hexagonal Boron Nitride, applied in a thin layer with a mass proportion of 0.5% to 2% and a thickness of less than 500 micrometers.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If traditional metal tank and pipeline walls are used, then structural strength is maintained, but hydrogen leakage occurs through the walls due to small hydrogen molecule size

Engineering Contradiction:
Improvehydrogen leakage preventionVSAvoidstructural integrity
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent applies a composite coating structure consisting of a polydopamine polymer layer combined with two-dimensional material (graphene, graphene oxide, or HBN platelets) on the metal surface. This composite structure provides both hydrogen leakage prevention through the impermeable two-dimensional material and maintains structural integrity through the polymer matrix and metal substrate.

Inventive Principle:
Principle #40Composite materials

2Reliability

If barrier coatings are applied to reduce hydrogen leakage, then leakage is partially reduced, but the effectiveness is not perfect and hydrogen embrittlement still occurs

Engineering Contradiction:
Improvehydrogen leakage preventionVSAvoidhydrogen embrittlement
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent changes the material parameters at the surface level by introducing two-dimensional materials with unique atomic structures that provide complete hydrogen barrier properties. The polydopamine polymer provides adhesive properties with a specific surface area and chemical composition, creating a coating system that prevents both leakage and embrittlement by blocking hydrogen diffusion paths.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If ventilation or neutralization systems are added to handle hydrogen leaks, then safety is improved, but the mass of the hydrogen distribution system increases

Engineering Contradiction:
ImprovesafetyVSAvoidsystem mass
Core Design Contradiction:
ReliabilityVSWeight of moving object

Solution Approach 1:

The patent extracts and eliminates the need for ventilation or neutralization systems by implementing a preventive barrier coating that stops hydrogen leakage at the source. The two-dimensional material/polydopamine composite coating on tank and pipeline surfaces prevents hydrogen escape, making safety systems unnecessary and reducing overall system mass.

Inventive Principle:
Principle #2Taking out (Extraction)

4Reliability

If a two-dimensional material coating is applied to prevent hydrogen leakage, then leakage is prevented, but adhesion to the surface may be insufficient

Engineering Contradiction:
Improvehydrogen barrier propertyVSAvoidcoating adhesion
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent creates a composite coating system where polydopamine polymer serves as the adhesive matrix providing strong bonding to the metal surface, while dispersed two-dimensional material platelets (graphene, graphene oxide, or HBN) provide the hydrogen barrier function. This composite structure simultaneously achieves both adhesion and impermeability.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively prevents hydrogen leaks and enhances adhesion, reducing the risk of explosions and embrittlement while minimizing the mass of the hydrogen distribution system, making it suitable for aircraft installations.

Implementation Method 1

The two-dimensional material forms a barrier preventing the passage of gases such as hydrogen. Thus, the surface covered by the two-dimensional material is impermeable to hydrogen

Methodology Applied
Scientific EffectPermeation barrier: Permeation

Implementation Method 2

a polydopamine-type polymer offers the advantage of high adhesion properties to the surface to which it is applied

Methodology Applied
Scientific EffectAdhesion: Adhesive

Data Source

PatentEP3933249B1Hydrogen tank and hydrogen pipe covered with a two-dimensional material, and installation for dispensing hydrogen
Publication Date: 2023.08.02 AIRBUS (SAS)
  • EP3933249B1 patent drawingFigure 1A~1B

AI summary

The hydrogen distribution system (1) comprises a hydrogen tank (10) and at least one hydrogen distribution pipeline (20a, 20b). At least one surface of the hydrogen tank or the hydrogen distribution pipeline is coated with a two-dimensional material (30a, 30b) blended with a polydopamine-type polymer. The invention also relates to a hydrogen tank (10) and a hydrogen distribution pipeline (20a, 20b) having one surface coated with a two-dimensional material (30a, 30b) blended with a polydopamine-type polymer.