Composite Hydrogen Tank Wall Sensing for In-Service Leak Detection

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Solution Overview

Problem

Composite storage tanks for gaseous hydrogen at high pressure face challenges in measuring hydrogen leakage rates and assessing the physical condition of the composite wall, leading to inefficiencies and potential safety issues.

Innovation Solution

Incorporating a metal hydride element within the composite wall of the storage tank, which allows for the measurement of electrical characteristics such as resistance or dielectric constant to infer hydrogen leakage and wall condition.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Weight of moving object

If composite storage tanks are used for hydrogen storage, then gravimetric efficiency is improved, but hydrogen leakage increases over time due to microcracking and delamination

Engineering Contradiction:
Improvegravimetric efficiencyVSAvoidhydrogen leakage rate
Core Design Contradiction:
Weight of moving objectVSReliability

Solution Approach 1:

The patent incorporates sensing elements during the manufacturing of the composite tank wall, before the tank is put into service. These sensors are embedded within the composite structure itself, allowing for continuous monitoring of hydrogen leakage and structural integrity from the outset, enabling early detection of microcracking and delamination issues.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent introduces sensing elements as intermediaries between the hydrogen storage function and the monitoring function. These sensors act as mediators that detect hydrogen leakage and structural changes without interfering with the tank's primary function of storing hydrogen, providing real-time data on the tank's condition.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Measurement precision

If traditional leak testing methods are used, then leakage detection is achieved, but tank removal from service is required even when performance is satisfactory

Engineering Contradiction:
Improveleakage detection accuracyVSAvoidtank downtime
Core Design Contradiction:
Measurement precisionVSLoss of time

Solution Approach 1:

The patent implements a continuous feedback system through embedded sensors that monitor hydrogen leakage and structural condition in real-time. This feedback mechanism allows operators to assess tank health without removing the tank from service, enabling condition-based maintenance decisions rather than scheduled or precautionary removals.

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The tank performs self-diagnosis through the embedded sensing elements that continuously monitor its own condition. The tank essentially monitors itself for leakage and structural integrity issues, eliminating the need for external testing equipment and tank removal for routine assessments.

Inventive Principle:
Principle #25Self-service

3Device complexity

If no monitoring system is installed, then device complexity is reduced, but information on leakage rate and wall condition is lost

Engineering Contradiction:
Improvesystem simplicityVSAvoidleakage and condition data
Core Design Contradiction:
Device complexityVSLoss of information

Solution Approach 1:

The sensing elements serve multiple functions: they detect hydrogen leakage, monitor structural integrity, and provide data on tank condition. This multi-functionality is achieved through a relatively simple embedded sensor system that simultaneously performs several monitoring tasks, minimizing the added complexity while maximizing the information gained.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables real-time monitoring of hydrogen leakage and the physical condition of the composite wall, allowing for timely maintenance and reducing hydrogen wastage.

Implementation Method 1

a metal hydride element or a metal element capable of forming a metal hydride in the presence of hydrogen

Methodology Applied
Scientific EffectHydrogen absorption by metal hydride: Absorption (physical)

Implementation Method 2

measuring apparatus arranged to measure an electrical characteristic of the metal hydride element or the metal element. The extent of historical leakage of hydrogen from the tank, and its current physical condition, at the position of the metal or metal hydride element, may be inferred from an electrical characteristic of the metal or metal hydride element, for example its electrical resistance

Methodology Applied
Scientific EffectElectrical resistance measurement: Electrical Resistance

Data Source

PatentUS12209706B2Composite storage tank system for gaseous hydrogen
Publication Date: 2025.01.28 ROLLS ROYCE PLC
  • US12209706B2 patent drawing
  • US12209706B2 patent drawing

AI summary

A composite storage tank system for gaseous hydrogen comprises a composite storage tank having composite wall enclosing a gas storage volume, the composite wall including a metal hydride element, or a metal element capable of forming a metal hydride in the presence of hydrogen, the system further comprising measuring apparatus arranged to measure an electrical characteristic of the metal hydride element or the metal element. The history of leakage of gaseous hydrogen from the tank, the current rate of leakage and the physical condition of the composite wall in the vicinity of the metal or metal hydride element may be inferred from a measurement of the electrical characteristic, without taking the tank out of service as is required in the case of known leaks tests such as a vacuum test, helium leak test or hydrogen sniffing test.