Hydrophilic Gel Layer for Low Elastic Modulus Substrates

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Solution Overview

Problem

Existing methods for surface modification of materials to enhance hydrophilicity, lubricity, and biocompatibility, such as surface graft polymerization and composite hydrogel compositions, are costly and limited to specific materials like hydrous hydrogels, making it difficult to achieve a moderate elastic modulus and wide applicability.

Innovation Solution

A device with a substrate coated by a hydrophilic polymer gel layer having a hydroxyl group, where the gel layer is fixed through chemical bonds, allowing for a simple production process that imparts moderate elastic modulus and hydrophilicity to both hydrous and non-hydrous substrates, including metals and glass.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If surface graft polymerization is used to hydrophilize the surface, then hydrophilicity is improved, but the production process is prolonged and production cost increases

Engineering Contradiction:
ImprovehydrophilicityVSAvoidproduction process duration
Core Design Contradiction:
Object-affected harmful factorsVSLoss of time

Solution Approach 1:

The invention extracts the essential function of surface hydrophilization from the complex graft polymerization process. By using a simple coating method with hydrophilic polymers containing hydroxyl groups, it achieves the desired hydrophilicity without the time-consuming steps of introducing functional groups and performing graft polymerization.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention employs a simple, cost-effective coating approach using readily available hydrophilic polymers. This method avoids expensive and time-consuming chemical modification processes, making it economically viable for widespread application.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

2Object-affected harmful factors

If surface graft polymerization is used to hydrophilize the surface, then hydrophilicity is improved, but production cost increases

Engineering Contradiction:
ImprovehydrophilicityVSAvoidproduction cost
Core Design Contradiction:
Object-affected harmful factorsVSEase of manufacture

Solution Approach 1:

The invention uses simple, inexpensive hydrophilic polymers that can be directly coated onto substrates. This eliminates the need for costly chemical reagents, functional group introductions, and complex polymerization processes, significantly reducing production costs.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The invention extracts only the essential hydrophilic function from complex chemical processes. By using pre-formed hydrophilic polymers with hydroxyl groups, it achieves surface modification without the expensive intermediate steps of graft polymerization.

Inventive Principle:
Principle #2Taking out (Extraction)

3Strength

If composite hydrogel composition is used to adjust elastic modulus, then elastic modulus is improved, but the production process is prolonged and production cost increases

Engineering Contradiction:
Improveelastic modulusVSAvoidproduction process duration
Core Design Contradiction:
StrengthVSLoss of time

Solution Approach 1:

The invention controls the elastic modulus by adjusting parameters such as polymer concentration, molecular weight, and crosslinking density within a single hydrogel formulation. This eliminates the need for time-consuming crosslinking processes between multiple hydrogels while achieving the desired mechanical properties.

Inventive Principle:
Principle #35Parameter changes

4Strength

If composite hydrogel composition is used to adjust elastic modulus, then elastic modulus is improved, but production cost increases

Engineering Contradiction:
Improveelastic modulusVSAvoidproduction cost
Core Design Contradiction:
StrengthVSEase of manufacture

Solution Approach 1:

The invention achieves different elastic moduli by varying parameters such as polymer concentration, molecular weight, and crosslinking degree within a single hydrogel system. This simplifies manufacturing by eliminating the need for multiple hydrogel preparations and crosslinking processes, reducing production costs.

Inventive Principle:
Principle #35Parameter changes

5Object-affected harmful factors

If surface modification is performed to improve biocompatibility, then biocompatibility is improved, but the production process becomes more complex

Engineering Contradiction:
ImprovebiocompatibilityVSAvoidproduction process complexity
Core Design Contradiction:
Object-affected harmful factorsVSDevice complexity

Solution Approach 1:

The invention extracts the essential biocompatibility function from complex surface modification processes. By using hydrophilic polymers with hydroxyl groups that naturally provide good biocompatibility, it achieves the desired effect without complex chemical modifications, functional group introductions, or multi-step processing.

Inventive Principle:
Principle #2Taking out (Extraction)

6Strength

If hydrophilic polymer coating is applied to achieve moderate elastic modulus, then elastic modulus is improved, but applicability is limited to hydrous hydrogels

Engineering Contradiction:
Improveelastic modulusVSAvoidmaterial applicability
Core Design Contradiction:
StrengthVSAdaptability or versatility

Solution Approach 1:

The invention creates a universal surface coating method that can be applied to various substrate materials including metals, glass, and both hydrous and non-hydrous hydrogels. The hydrophilic polymer coating with hydroxyl groups provides consistent elastic modulus improvement across different material types, eliminating the limitation to only hydrous hydrogels.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method enables the creation of a surface with improved water wettability, lubricity, and cushioning properties, reducing production costs and expanding material applicability beyond hydrous hydrogels, while maintaining low elastic modulus for biocompatibility.

Implementation Method 1

a gel layer made of a hydrophilic polymer having a hydroxyl group, and the gel layer is fixed to at least a part of the surface of the substrate

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

disposing a substrate in a solution containing a hydrophilic polymer having a hydroxyl group adjusted to an initial pH of 2.3 or lower and heating the solution

Methodology Applied
Scientific EffectHeating: Heating

Data Source

PatentUS11045574B2Device and production method for the same
Publication Date: 2021.06.29 TORAY INDUSTRIES INC
  • US11045574B2 patent drawing

AI summary

Disclosed is a device including a substrate and a gel layer made of a hydrophilic polymer having a hydroxyl group. The gel layer is fixed to at least a part on a surface of the substrate in a thickness of 1 nm to 3,000 nm and an elastic modulus of a device surface is 6.00×103 Pa or less.