Hydrophilic Polymer Lens Surface Modification via Compound Radical Reaction

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Solution Overview

Problem

Existing methods for hydrophilizing contact lenses, such as plasma treatment, are complex, costly, and difficult to control, and there is a need for a simpler and more cost-effective method to produce lenses with high oxygen permeability and moisture retention.

Innovation Solution

A method for producing a lens to be fitted to an eye by hydrophilizing a polymer lens surface using a compound radical containing Group 15, Group 16, and Group 17 elements, which introduces hydrophilic groups into the lens surface, allowing for simpler and more cost-effective production.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If plasma treatment is used to hydrophilize the lens surface, then the lens becomes more hydrophilic, but the operation becomes complicated and the treatment cost increases

Engineering Contradiction:
Improvehydrophilicity of lens surfaceVSAvoidoperation complexity
Core Design Contradiction:
Ease of operationVSDevice complexity

Solution Approach 1:

The invention changes the chemical parameters of the lens surface by introducing specific functional groups (carboxyl, hydroxyl, carbonyl, or amine groups) through reaction with compound radicals. This chemical modification achieves hydrophilization without requiring complex plasma treatment equipment or procedures, thereby improving ease of operation while avoiding increased device complexity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses a simple chemical treatment approach that can be performed with basic chemical reagents rather than expensive plasma treatment equipment. The treatment process is straightforward and can be completed in a simple apparatus, reducing both operational complexity and treatment cost while achieving the desired hydrophilic surface properties

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

2Ease of operation

If plasma treatment is used to hydrophilize the lens surface, then the lens becomes more hydrophilic, but the treatment cost increases

Engineering Contradiction:
Improvehydrophilicity of lens surfaceVSAvoidtreatment cost
Core Design Contradiction:
Ease of operationVSEase of manufacture

Solution Approach 1:

The invention achieves hydrophilization through chemical parameter changes by introducing hydrophilic functional groups via reaction with compound radicals. This chemical approach uses simple, inexpensive reagents and can be performed in basic laboratory or manufacturing equipment, significantly reducing treatment cost compared to plasma treatment while maintaining effective hydrophilic surface properties

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention replaces expensive plasma treatment equipment and procedures with a cost-effective chemical treatment method using readily available chemical reagents. The simple chemical reaction process can be performed in basic apparatus, making the treatment much more affordable while achieving the same hydrophilic surface modification effect

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Ease of operation

If plasma treatment is used to hydrophilize the lens surface, then the lens becomes more hydrophilic, but the reaction control becomes difficult

Engineering Contradiction:
Improvehydrophilicity of lens surfaceVSAvoidreaction control
Core Design Contradiction:
Ease of operationVSDifficulty of detecting and measuring

Solution Approach 1:

The invention achieves precise control over the hydrophilization reaction by carefully controlling the chemical reaction parameters such as reagent concentration, reaction time, temperature, and pH. These chemical parameters are easier to measure and control in a standard laboratory or manufacturing setting compared to plasma treatment parameters, providing better reaction control while achieving the desired hydrophilic surface properties

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method enables the production of lenses with improved hydrophilicity and oxygen permeability, reducing the risk of eye drying and simplifying the manufacturing process while maintaining stability over time.

Implementation Method 1

hydrophilizing a surface of a polymer lens by reacting with a compound radical

Methodology Applied
Scientific EffectHydrophilization:

Implementation Method 2

reacting with a compound radical, wherein the compound radical is a radical containing one element selected from the group consisting of Group 15 elements and Group 16 elements, and a Group 17 element

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Implementation Method 3

a surface of the polymer is an oxidized surface

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 4

hydrophilizing a surface of a polymer lens by reacting with a compound radical

Methodology Applied
Scientific EffectSurface oxidation: Photo-oxidation

Data Source

PatentUS12202218B2Method for producing lens to be fitted to eye and lens to be fitted to eye
Publication Date: 2025.01.21 OSAKA UNIVERSITY
  • US12202218B2 patent drawing
  • US12202218B2 patent drawing
  • US12202218B2 patent drawing

AI summary

The present invention provides a new method for producing a lens to be fitted to an eye in a simple manner at a low cost. In order to achieve the aforementioned object, the present invention provides a method for producing a lens to be fitted to an eye, including the step of: hydrophilizing a surface of a polymer lens by reacting with a compound radical, wherein the compound radical is a radical containing one element selected from the group consisting of Group 15 elements and Group 16 elements, and a Group 17 element.