Hydrophilic Silicone Impression Material with Improved Storage Stability

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Solution Overview

Problem

Current dental impression materials face challenges in achieving a low contact angle before setting while maintaining adequate tear strength and storage stability, particularly in thin marginal areas, and existing surfactant combinations often interfere with the curing process or result in incomplete reactions.

Innovation Solution

A two-part addition silicone composition combining a fluoroaliphatic polyoxyethylene surfactant with a monofunctional alcohol alkoxylate surfactant, optimized to provide a low contact angle and high tear strength, minimizing surfactant concentration to avoid interference with the platinum catalyst and ensuring uniform mixing.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If fluorosurfactants and silicone ether compounds are used to reduce contact angle, then wettability is improved, but storage stability deteriorates

Engineering Contradiction:
Improvestorage stabilityVSAvoidcontact angle
Core Design Contradiction:
Stability of the object's compositionVSManufacturing precision

Solution Approach 1:

The patent combines fluorosurfactant and fatty alcohol ethoxylate in specific proportions to create a composite surfactant system that achieves both low contact angle and high storage stability, resolving the contradiction between wettability improvement and storage stability maintenance

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes the concentration ratio of fluorosurfactant to fatty alcohol ethoxylate and controls the molecular weight parameters of the ethoxylate chain to achieve the desired balance between contact angle and storage stability

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If surfactant concentration is increased to achieve low contact angle, then wettability is improved, but curing process interference increases

Engineering Contradiction:
Improvecontact angleVSAvoidcuring process integrity
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent identifies and controls critical parameters including the surfactant concentration ratio, molecular weight of ethoxylate, and composition proportions to achieve low contact angle while maintaining curing process reliability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The fatty alcohol ethoxylate acts as an intermediary that enables the fluorosurfactant to achieve low contact angle without interfering with the platinum catalyst, mediating between wettability requirements and curing process integrity

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves a contact angle below 20 degrees and a tear strength of at least 270 PSI, with improved stability and shelf life, as demonstrated by accelerated aging tests, while maintaining the integrity of the curing process.

Implementation Method 1

a surfactant system composed of a fluorosurfactant and a fatty alcohol ethoxylate

Methodology Applied
Scientific EffectSurfactant: Surfactant

Implementation Method 2

improves the ability of the impression material to displace oral fluids during curing. Wettability or hydrophilicity of an impression material is usually characterized by a contact angle method

Methodology Applied
Scientific EffectSurface tension: Surface Tension

Implementation Method 3

a catalyst for enabling the addition polymerization reaction

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 4

addition curing silicone composition

Methodology Applied
Scientific EffectAddition polymerization: Chemical Bonding

Data Source

PatentEP3370679B1Hydrophilic impression material with improved storage stability
Publication Date: 2022.06.22 DENTSPLY SIRONA INC
  • EP3370679B1 patent drawing
  • EP3370679B1 patent drawing
  • EP3370679B1 patent drawing

AI summary

Disclosed herein is a dental impression material that includes a two part addition curing silicone composition. The disclosed impression material contains a surfactant system composed of a fluorosurfactant and a fatty alcohol ethoxylate. The impression material disclosed herein exhibits improved storage stability than known systems using fluorosurfactants and silicone ether compounds.