Hydrophobic Coating Fabrication via Particle Embedding

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Solution Overview

Problem

Existing methods for creating hydrophobic coatings to prevent corrosion in harsh environments, such as marine environments, face challenges in achieving long-term adhesion and economic scalability, particularly due to difficulties in forming the Lotus effect morphology and the lack of strong adhesion of particle additives.

Innovation Solution

A method involving the deposition of a deformable layer of layer-integrable material onto a substrate, forcibly embedding particles within the layer, and solidifying them to create a hierarchical morphology, ensuring particles are embedded at varying depths, which enhances adhesion and hydrophobicity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If particle additives are added to provide surface roughness and hydrophobicity, then hydrophobic performance is improved, but adhesion to substrate deteriorates

Engineering Contradiction:
Improvehydrophobic performanceVSAvoidadhesion
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent applies preliminary action by depositing a deformable layer onto the substrate before adding particles. This preparatory step creates a bonding interface that will later secure the particles, preventing adhesion failure while maintaining hydrophobic performance.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent uses composite materials by combining the deformable layer with particles to create a hierarchical structure. This composite approach integrates materials with different functions: the deformable layer provides adhesion and the particles provide hydrophobicity, resolving the contradiction between these two properties.

Inventive Principle:
Principle #40Composite materials

2Manufacturing precision

If nano-fabrication procedures or molds are used to form Lotus effect morphology, then surface morphology is improved, but manufacturing complexity and cost increase

Engineering Contradiction:
Improvesurface morphologyVSAvoidfabrication complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent applies copying by using particles as templates or copies of the desired microscopic protrusions. Instead of complex nano-fabrication to create the morphology, simple particles are deposited to replicate the Lotus effect structure, achieving the desired surface morphology with much simpler manufacturing processes.

Inventive Principle:
Principle #26Copying

Solution Approach 2:

The patent applies parameter changes by controlling particle size distribution (1 nm to 50 μm range) and deposition parameters to achieve the desired hierarchical morphology. By adjusting these parameters, the complex Lotus effect structure is obtained through simple particle deposition rather than complex fabrication procedures.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If particles are embedded deeply within the deformable layer, then adhesion is improved, but hydrophobic performance deteriorates

Engineering Contradiction:
ImproveadhesionVSAvoidhydrophobic performance
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent applies local quality by creating a hierarchical particle distribution where particles at different depths serve different functions. Particles embedded deeper provide adhesion and structural support, while particles near the surface provide hydrophobic performance. This spatial differentiation of particle functions resolves the contradiction between adhesion and hydrophobicity.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent applies dimensionality change by transitioning from a single-layer particle coating to a hierarchical three-dimensional structure with particles distributed at multiple depths. This vertical dimensionality allows simultaneous optimization of adhesion (deeper particles) and hydrophobicity (surface particles), resolving the contradiction between these properties.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method results in a hydrophobic coating with improved long-term corrosion resistance and economic viability, maintaining high hydrophobicity even after surface wear, with contact angles reaching up to 150 degrees, suitable for protecting structures in harsh environments.

Implementation Method 1

depositing a deformable layer of the layer-integrable material onto the surface of the solid substrate

Methodology Applied
Scientific EffectDeposition: Deposition (physical)

Implementation Method 2

solidifying the deformable layer including the plurality of particles so as to be integral with the surface of the solid substrate

Methodology Applied
Scientific EffectSolidification: Freezing

Implementation Method 3

The high surface tension of water on the Lotus leaves causes droplets to form a nearly spherical shape with a high contact angle

Methodology Applied
Scientific EffectHydrophobic effect: Hydrophobe

Implementation Method 4

The high surface tension of water on the Lotus leaves causes droplets to form a nearly spherical shape with a high contact angle

Methodology Applied
Scientific EffectSurface tension: Surface Tension

Data Source

PatentUS11634593B2Method for fabricating a hydrophobic coating for corrosion protection
Publication Date: 2023.04.25 SAUDI ARABIAN OIL CO
  • US11634593B2 patent drawing
  • US11634593B2 patent drawing
  • US11634593B2 patent drawing

AI summary

A method of fabricating a hydrophobic coating on a surface of a solid substrate which includes a layer-integrable material includes the steps of depositing a deformable layer of the layer-integrable material onto the surface of the solid substrate, forcibly embedding a plurality of particles within the deformable layer, and solidifying the deformable layer including the plurality of particles so as to be integral with the surface of the solid substrate. At least a portion of the plurality of particles is embedded at a threshold depth within the deformable layer prior to solidification.