Hydrophobized Modified Starch Coating for Stable Paper Application

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Solution Overview

Problem

Existing oil-resistant agents for paper face challenges in achieving both high concentration application and effective oil resistance, as high concentrations lead to increased viscosity, making stable application difficult, while low concentrations fail to impart sufficient oil resistance.

Innovation Solution

A water- and oil-repellent agent comprising a hydrophobized modified starch with a viscosity of 60 cps or less at 50°C in a 20% aqueous solution, accounting for 60% or more of the modified starch content, which facilitates easy application and enhances both water and oil repellencies on paper.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If high concentration of modified starch is used in oil-resistant agent, then oil resistance performance is improved, but viscosity increases making stable application difficult

Engineering Contradiction:
Improveoil resistance performanceVSAvoidstable application
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The patent applies parameter changes by controlling the viscosity of the modified starch aqueous solution to be 60 cps or less at 50°C, and specifying that hydrophobized modified starch accounts for 60% or more of the total modified starch. These parameter specifications allow high concentration application (15% or more modified starch) while maintaining low viscosity for stable application, thus resolving the contradiction between oil resistance performance and ease of application.

Inventive Principle:
Principle #35Parameter changes

2Ease of operation

If low concentration of modified starch is used in oil-resistant agent, then viscosity remains low facilitating application, but oil resistance performance becomes insufficient

Engineering Contradiction:
Improveapplication stabilityVSAvoidoil resistance performance
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The patent resolves this contradiction by establishing specific parameter ranges: modified starch content at 15% or more, hydrophobized modified starch at 60% or more of total modified starch, and viscosity of 60 cps or less at 50°C. These parameters enable the formulation to achieve both sufficient oil resistance performance and stable application characteristics simultaneously.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The agent effectively imparts excellent water and oil repellencies to paper, even at high concentrations, ensuring stable application and improved performance.

Implementation Method 1

a hydrophobized modified starch that exhibits a viscosity of 60 cps or less at 50° C. in a 20 mass % aqueous solution

Methodology Applied
Scientific EffectHydrophobe: Hydrophobe

Data Source

PatentUS20250230608A1Water- and oil-repellent agent
Publication Date: 2025.07.17 DAIKIN INDUSTRIES LTD

AI summary

A water- and oil-repellent agent including: a modified starch, the modified starch including a hydrophobized modified starch that exhibits a viscosity of 60 cps or less at 50° C. in a 20 mass % aqueous solution, the hydrophobized modified starch accounting for 60% by mass or more of the modified starch contained in the water- and oil-repellent agent, where the amount of the modified starch in the water- and oil-repellent agent is 15% by mass or more.