Non-digestible Hydroxypropyl Starch Hydrolysate Production

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Solution Overview

Problem

Existing hydroxypropyl starch hydrolysates contain digestible components, limiting their effectiveness as low-calorie dietary fibers.

Innovation Solution

Hydrolyzing hydroxypropyl starch with specific degree of substitution using α-amylase and glucoamylase, followed by glucose removal through chromatographic or membrane fractionation, results in a non-digestible hydroxypropyl starch hydrolysate with high dietary fiber content.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If hydroxypropyl starch is hydrolyzed with enzyme or acid to obtain hydrolysate, then the hydrolysate can be produced as a sugar substitute, but the hydrolysate contains many digestible components and cannot serve as effective low calorie dietary fiber

Engineering Contradiction:
Improvedietary fiber contentVSAvoiddigestible component content
Core Design Contradiction:
Quantity of substanceVSObject-affected harmful factors

Solution Approach 1:

The patent applies extraction by removing glucose (digestible component) from the hydrolysate mixture through chromatographic fractionation or membrane fractionation. This separates the desired non-digestible dietary fiber components from the harmful digestible glucose, achieving high purity non-digestible hydroxypropyl starch hydrolysate with dietary fiber content of 80% or more and glucose content of less than 5% by mass

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent controls the degree of substitution parameter of hydroxypropyl starch within 0.05 to 0.4 to optimize the balance between digestibility resistance and hydrolysis efficiency. This parameter control ensures the hydrolysate maintains non-digestible properties while allowing effective separation of digestible components

Inventive Principle:
Principle #35Parameter changes

2Ease of manufacture

If conventional hydrolysis methods are used to produce hydroxypropyl starch hydrolysate, then the production process is simple, but the product contains digestible components that limit its effectiveness as dietary fiber

Engineering Contradiction:
Improveproduction process simplicityVSAvoidnon-digestible dietary fiber purity
Core Design Contradiction:
Ease of manufactureVSQuantity of substance

Solution Approach 1:

The patent introduces chromatographic fractionation or membrane fractionation as an intermediary separation step between hydrolysis and final product formation. This intermediary process effectively removes digestible glucose while preserving non-digestible dietary fiber components, transforming a simple but impure process into a refined purification sequence that maintains ease of manufacture while achieving high purity

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The process produces a water-soluble dietary fiber with low viscosity, non-retrogradation, and high moisture retention, suitable for various food and cosmetic applications.

Implementation Method 1

hydrolyzing the hydroxypropyl starch having a specific degree of substitution using an α-amylase, and then a glucoamylase

Methodology Applied
Scientific EffectEnzyme hydrolysis: Enzyme

Implementation Method 2

removing glucose by a procedure, such as chromatographic fractionation or membrane fractionation

Methodology Applied
Scientific EffectChromatography: Chromatography

Implementation Method 3

removing glucose by a procedure, such as chromatographic fractionation or membrane fractionation

Methodology Applied
Scientific EffectMembrane separation: Semipermeable Membrane

Data Source

PatentUS9237765B2Non-digestible hydroxypropyl starch hydrolysate, method for production thereof and food and beverage
Publication Date: 2016.01.19 MATSUTANI CHEM IND CO LTD
  • US9237765B2 patent drawing
  • US9237765B2 patent drawing

AI summary

The present invention provides a non-digestible hydroxypropyl starch hydrolysate which can be used as novel water soluble dietary fiber, a method for producing it, as well as food products and beverages containing the non-digestible hydroxypropyl starch hydrolysate. The present invention provides the non-digestible hydroxypropyl starch hydrolysate characterized by having a DE value of less than 20 and a glucose content of less than 3% by mass; food products and beverages containing it; and the method for producing the non-digestible hydroxypropyl starch hydrolysate comprising the steps of: (A) hydrolyzing a hydroxypropyl starch with a degree of substitution of 0.05 to 0.4 with α-amylase and then with glucoamylase; and (B) removing glucose from the hydrolysate obtained in the step (A).