Hygroscopic Material in Lithium Battery Electrode Pores

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Solution Overview

Problem

Lithium secondary batteries face performance degradation due to moisture presence, which is not effectively removed by existing methods, leading to side reactions and reduced battery reliability.

Innovation Solution

Incorporating a hygroscopic material into the active material layer of the electrode, allowing it to be disposed in pores formed by the active material, effectively absorbing and removing moisture from both the electrode and electrolyte.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If high-temperature drying process is used to remove moisture from electrode, then moisture removal efficiency is improved, but manufacturing complexity and energy consumption increase

Engineering Contradiction:
Improvemoisture removal efficiencyVSAvoidmanufacturing process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The hygroscopic material is incorporated into the electrode structure before battery assembly, performing moisture absorption in advance. This preliminary action eliminates the need for complex post-manufacturing drying processes, as the moisture removal function is built into the electrode itself during the coating step.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The electrode becomes self-service regarding moisture removal through the integrated hygroscopic material. The electrode automatically absorbs and removes moisture from the electrolyte solution during battery operation without requiring external drying equipment or additional manufacturing steps.

Inventive Principle:
Principle #25Self-service

2Reliability

If hygroscopic material is added to active material layer, then moisture removal capability is improved, but electrode structure complexity increases

Engineering Contradiction:
Improvemoisture management capabilityVSAvoidelectrode structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The hygroscopic material is merged with the active material layer during the coating process, combining moisture removal functionality with the electrode structure. This integration avoids adding separate moisture removal components, maintaining structural simplicity while achieving dual functionality.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The active material layer is given multi-functionality by incorporating hygroscopic material, allowing it to perform both its primary electrochemical function and moisture absorption. This universal approach eliminates the need for dedicated moisture removal structures.

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Ease of manufacture

If moisture is present in electrolyte solution, then battery assembly is simplified, but side reactions occur reducing battery reliability

Engineering Contradiction:
Improvebattery assembly easeVSAvoidbattery performance stability
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The hygroscopic material converts the harmful presence of moisture into a beneficial process by actively absorbing and removing it during battery operation. Instead of requiring perfect moisture-free assembly, the system uses the moisture-absorbing capability to maintain reliability even when moisture is present during manufacturing.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances battery performance by preventing side reactions caused by moisture, improving capacity retention and overall battery reliability by effectively managing moisture content.

Implementation Method 1

a hygroscopic material for removing microscopic moisture of an electrode

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS10490821B2Electrode for lithium secondary battery comprising hygroscopic material and lithium secondary battery comprising the same
Publication Date: 2019.11.26 LG ENERGY SOLUTION LTD
  • US10490821B2 patent drawing
  • US10490821B2 patent drawing
  • US10490821B2 patent drawing

AI summary

Provided is an electrode for a lithium secondary battery in which a hygroscopic material is disposed in pores which are formed by arranging an active material in an active material layer, wherein, since the electrode for a lithium secondary battery according to the present invention may remove moisture present in the electrode and an electrolyte solution by disposing the hygroscopic material in the pores which are formed by the active material in the active material layer, a side reaction due to the presence of moisture in the battery may be excluded, and thus, the performance of the battery may be improved.