Hyperbranched Olefinic Fluid Thermal Grease

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Solution Overview

Problem

Conventional thermal greases face issues such as high cost, thermal resistance limitations, and migration problems due to the use of silicone oils, and mineral oils have low fire points, restricting their application in high-temperature devices.

Innovation Solution

A thermal grease composition incorporating a hyperbranched ethylene-based or ethylene-propylene-based olefinic fluid with a thermally conductive filler, which offers improved thermal conductivity and resistance at a lower cost, and can be blended with silicone fluid to enhance stability and reduce filler segregation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If silicone oil is used as the base material for thermal grease, then chemical resistance and wide operating temperature range are improved, but cost increases and physical migration occurs leading to contamination

Engineering Contradiction:
Improvechemical resistanceVSAvoidcontamination
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent replaces expensive silicone oil with cheaper alternative base materials such as hydrocarbon oils or esters that can achieve the required performance at lower cost, effectively substituting a high-cost material with a more economical one that still meets the application requirements

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent modifies the chemical composition parameters of the base material by using hyperbranched olefinic fluids with specific molecular weight ranges (200-10,000 Daltons) and branching structures, which change the physical and chemical properties to reduce migration while maintaining thermal performance

Inventive Principle:
Principle #35Parameter changes

2Ease of manufacture

If mineral oil is used to avoid silicone oil problems, then cost is reduced, but fire point decreases limiting high temperature application

Engineering Contradiction:
ImprovecostVSAvoidfire point
Core Design Contradiction:
Ease of manufactureVSTemperature

Solution Approach 1:

The patent changes the chemical structure parameters by using hyperbranched olefinic fluids with controlled molecular weight (200-10,000 Daltons) and specific branching architectures, which increase the fire point compared to linear hydrocarbons while maintaining low cost and good流动性

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite thermal grease system combining hyperbranched olefinic fluid base material with thermally conductive filler particles, where the unique molecular structure of the base material provides both cost-effectiveness and high-temperature stability

Inventive Principle:
Principle #40Composite materials

3Reliability

If highly filled thermal grease is used to improve thermal conductivity, then thermal resistance decreases, but viscosity increases affecting ease of application

Engineering Contradiction:
Improvethermal conductivityVSAvoidviscosity
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The patent changes the rheological parameters by using hyperbranched olefinic fluids with controlled molecular weight and branching density, which provide optimal viscosity characteristics that allow high filler loading while maintaining acceptable spreadability and applicability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent optimizes the local distribution and sizing of filler particles within the base material, using specific filler-to-base material ratios and particle size distributions to maximize thermal conductivity pathways while minimizing viscosity increase

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The hyperbranched olefinic fluid-based thermal greases provide higher thermal conductivity and resistance compared to silicone oil-based greases, with a reduced tendency to migrate and contaminate, while being more cost-effective and suitable for a wide range of temperature applications.

Implementation Method 1

thermal grease often exhibits a higher effective thermal conductivity and lower thermal resistance as a result of the fact that it is being used in particularly narrow spaces between components

Methodology Applied
Scientific EffectThermal conduction: Conduction (thermal)

Implementation Method 2

thermal grease composition comprising an admixture of (a) a hyperbranched, ethylene-based or ethylene- and propylene-based, olefinic fluid... and (b) a thermally conductive filler

Methodology Applied
Scientific EffectThermal conduction: Conduction (thermal)

Data Source

PatentEP3209755B1Thermal grease based on hyperbranched olefinic fluid
Publication Date: 2019.05.22 DOW GLOBAL TECHNOLOGIES LLC
  • EP3209755B1 patent drawing
  • EP3209755B1 patent drawing
  • EP3209755B1 patent drawing

AI summary

Disclosed is an effective thermal grease comprising a hyperbranched olefinic fluid and a thermally conductive filler. Property- modifying additives and fillers may also be included. The hyperbranched olefinic fluid is selected to have an average of at least 1.5 methine carbons per oligomer molecule and at least 40 methine carbons per one thousand total carbons. The thermal grease exhibits a flash point of 180 °C or higher, a pour point of 0 °C or lower, and a kinematic viscosity at 40 °C of no more than 200 cSt (0.0002 m 2/s). The composition may offer improved thermal conductivity, reduced tendency to migrate, and lower cost when compared with many other thermal greases, including silicone-based thermal greases.