ICP Etching of SiC and GaN for Deep Vertical Features
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Solution Overview
Problem
Current etching technologies are inadequate for achieving deep, high-aspect ratio features in silicon carbide (SiC) and gallium nitride (GaN) materials, resulting in limited etch depths, small aspect ratios, and non-vertical sidewalls, which hinders the development of advanced semiconductor devices and systems.
Innovation Solution
An Inductively-Coupled Plasma (ICP) etch process technology is employed to etch deep, high-aspect ratio features with near vertical sidewalls into SiC and GaN materials, using a method that involves a chemically reactive gas plasma and controlled process gases like Sulfur Hexafluoride (SF6) and Oxygen, with RF electromagnetic fields to generate high plasma densities and achieve high etch anisotropy.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Length of stationary object
If conventional etching technologies are used on SiC and GaN materials, then the etching process can be performed, but the etch depth is limited and aspect ratio is small
Solution Approach 1:
The patent applies parameter changes by optimizing plasma power, gas flow rates, pressure, and temperature to achieve both deep etching and high aspect ratios in SiC and GaN materials. The ICP etch process uses specific parameter combinations (e.g., high plasma power for etch rate, controlled gas flows for anisotropy) to resolve the contradiction between etch depth and productivity.
Solution Approach 2:
The patent employs periodic action through pulsed etching cycles with alternating etch and passivation steps. This allows the formation of deep features with high aspect ratios by periodically removing material and then protecting sidewalls, enabling continued deep etching without sacrificing sidewall integrity or overall productivity.
2Shape
If conventional etching technologies are used on SiC and GaN materials, then the etching process can be performed, but the sidewalls are not vertical
Solution Approach 1:
The patent applies preliminary action by performing a sidewall passivation step before the main etching process. A protective layer is deposited on the sidewalls in advance, which prevents lateral etching and ensures vertical sidewall formation during the subsequent anisotropic etching step, thereby maintaining both shape and manufacturing precision.
Solution Approach 2:
The patent segments the etching process into multiple distinct steps: sidewall passivation, anisotropic etching, and cleanup. This segmentation allows each step to be optimized independently - the passivation step ensures vertical sidewalls while the etching step controls dimensional precision, resolving the contradiction between shape and manufacturing precision.
3Productivity
If SiC material is plasma etched using conventional methods, then etching can be performed, but the etch rate is slow due to strong Si-C bond energy
Solution Approach 1:
The patent overcomes the strong Si-C bond strength by applying parameter changes including high plasma power, optimized gas composition (e.g., CF4, SF6 with O2 or H2), and controlled temperature. These parameters enhance the plasma reactivity and ion energy to break Si-C bonds more effectively, achieving high etch rates in SiC materials.
Solution Approach 2:
The patent uses composite plasma chemistry combining fluorocarbon gases (for Si-C bond breaking) with oxygen or hydrogen (for byproduct removal and sidewall protection). This composite approach enables simultaneous achievement of high etch rates and good feature quality by leveraging the complementary actions of different gas components.
4Reliability
If deep, high-aspect ratio features are etched into SiC and GaN, then advanced device fabrication is enabled, but current technologies result in defects in etched features
Solution Approach 1:
The patent uses periodic etch-passivation cycles to maintain feature quality during deep etching. The periodic passivation step prevents defect formation by protecting sidewalls from damage, while the etch step progresses the feature depth. This periodic action ensures both high reliability and low defect density in the final etched features.
Solution Approach 2:
The patent performs preliminary sidewall passivation before main etching to prevent defect formation during the etching process. This preliminary protective layer prevents particulate generation, sidewall damage, and other defects, ensuring high feature quality and reliability while maintaining manufacturing precision.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
This approach enables the fabrication of devices with high aspect ratios and vertical sidewalls, significantly improving the performance and cost-effectiveness of semiconductor devices, particularly in MMICs, MEMS, and high-power electronics, by allowing for deeper and more precise etching of features.
Implementation Method 1
Inductively-Coupled Plasma (ICP) etch process technology
Implementation Method 2
chemically reactive gas plasma
Implementation Method 3
chemically reactive gas plasma
Implementation Method 4
RF bias power on the substrate of between 50 and 200 Watts
Data Source
AI summary
A method for the etching of deep, high-aspect ratio features into silicon carbide (SiC), gallium nitride (GaN) and similar materials using an Inductively-Coupled Plasma (ICP) etch process technology is described. This technology can also be used to etch features in silicon carbide and gallium nitride having near vertical sidewalls. The disclosed method has application in the fabrication of electronics, microelectronics, power electronics, Monolithic Microwave Integrated Circuits (MMICs), high-voltage electronics, high-temperature electronics, high-power electronics, Light-Emitting Diodes (LEDs), Micro-Electro-Mechanical Systems (MEMS), micro-mechanical devices, microelectronic devices and systems, nanotechnology devices and systems, Nano-Electro-Mechanical Systems (NEMS), photonic devices, and any devices and/or structures made from silicon carbide and/or gallium nitride. The disclosed method also has application in the fabrication of through-substrate vias and through-wafer vias, including those that are subsequently filled with electrically conductive materials.


