ICP Etching of SiC and GaN for Deep Vertical Features

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Solution Overview

Problem

Current etching technologies are inadequate for achieving deep, high-aspect ratio features in silicon carbide (SiC) and gallium nitride (GaN) materials, resulting in limited etch depths, small aspect ratios, and non-vertical sidewalls, which hinders the development of advanced semiconductor devices and systems.

Innovation Solution

An Inductively-Coupled Plasma (ICP) etch process technology is employed to etch deep, high-aspect ratio features with near vertical sidewalls into SiC and GaN materials, using a method that involves a chemically reactive gas plasma and controlled process gases like Sulfur Hexafluoride (SF6) and Oxygen, with RF electromagnetic fields to generate high plasma densities and achieve high etch anisotropy.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Length of stationary object

If conventional etching technologies are used on SiC and GaN materials, then the etching process can be performed, but the etch depth is limited and aspect ratio is small

Engineering Contradiction:
Improveetch depthVSAvoidetch rate
Core Design Contradiction:
Length of stationary objectVSProductivity

Solution Approach 1:

The patent applies parameter changes by optimizing plasma power, gas flow rates, pressure, and temperature to achieve both deep etching and high aspect ratios in SiC and GaN materials. The ICP etch process uses specific parameter combinations (e.g., high plasma power for etch rate, controlled gas flows for anisotropy) to resolve the contradiction between etch depth and productivity.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs periodic action through pulsed etching cycles with alternating etch and passivation steps. This allows the formation of deep features with high aspect ratios by periodically removing material and then protecting sidewalls, enabling continued deep etching without sacrificing sidewall integrity or overall productivity.

Inventive Principle:
Principle #19Periodic action

2Shape

If conventional etching technologies are used on SiC and GaN materials, then the etching process can be performed, but the sidewalls are not vertical

Engineering Contradiction:
Improvesidewall verticalityVSAvoidfeature dimensional control
Core Design Contradiction:
ShapeVSManufacturing precision

Solution Approach 1:

The patent applies preliminary action by performing a sidewall passivation step before the main etching process. A protective layer is deposited on the sidewalls in advance, which prevents lateral etching and ensures vertical sidewall formation during the subsequent anisotropic etching step, thereby maintaining both shape and manufacturing precision.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent segments the etching process into multiple distinct steps: sidewall passivation, anisotropic etching, and cleanup. This segmentation allows each step to be optimized independently - the passivation step ensures vertical sidewalls while the etching step controls dimensional precision, resolving the contradiction between shape and manufacturing precision.

Inventive Principle:
Principle #1Segmentation

3Productivity

If SiC material is plasma etched using conventional methods, then etching can be performed, but the etch rate is slow due to strong Si-C bond energy

Engineering Contradiction:
Improveetch rateVSAvoidSi-C bond strength
Core Design Contradiction:
ProductivityVSStrength

Solution Approach 1:

The patent overcomes the strong Si-C bond strength by applying parameter changes including high plasma power, optimized gas composition (e.g., CF4, SF6 with O2 or H2), and controlled temperature. These parameters enhance the plasma reactivity and ion energy to break Si-C bonds more effectively, achieving high etch rates in SiC materials.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite plasma chemistry combining fluorocarbon gases (for Si-C bond breaking) with oxygen or hydrogen (for byproduct removal and sidewall protection). This composite approach enables simultaneous achievement of high etch rates and good feature quality by leveraging the complementary actions of different gas components.

Inventive Principle:
Principle #40Composite materials

4Reliability

If deep, high-aspect ratio features are etched into SiC and GaN, then advanced device fabrication is enabled, but current technologies result in defects in etched features

Engineering Contradiction:
Improveetched feature qualityVSAvoidfeature defect density
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent uses periodic etch-passivation cycles to maintain feature quality during deep etching. The periodic passivation step prevents defect formation by protecting sidewalls from damage, while the etch step progresses the feature depth. This periodic action ensures both high reliability and low defect density in the final etched features.

Inventive Principle:
Principle #19Periodic action

Solution Approach 2:

The patent performs preliminary sidewall passivation before main etching to prevent defect formation during the etching process. This preliminary protective layer prevents particulate generation, sidewall damage, and other defects, ensuring high feature quality and reliability while maintaining manufacturing precision.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables the fabrication of devices with high aspect ratios and vertical sidewalls, significantly improving the performance and cost-effectiveness of semiconductor devices, particularly in MMICs, MEMS, and high-power electronics, by allowing for deeper and more precise etching of features.

Implementation Method 1

Inductively-Coupled Plasma (ICP) etch process technology

Methodology Applied
Scientific EffectInductive coupling: Electromagnetic Induction

Implementation Method 2

chemically reactive gas plasma

Methodology Applied
Scientific EffectPlasma: Plasma

Implementation Method 3

chemically reactive gas plasma

Methodology Applied
Scientific EffectChemical reactions: Chemical Bonding

Implementation Method 4

RF bias power on the substrate of between 50 and 200 Watts

Methodology Applied
Scientific EffectIon acceleration: Lorentz Force

Data Source

PatentUS11984321B1Method for etching deep, high-aspect ratio features into silicon carbide and gallium nitride
Publication Date: 2024.05.14 CORP FOR NATIONAL RESEARCH INITIATIVES
  • US11984321B1 patent drawing
  • US11984321B1 patent drawing
  • US11984321B1 patent drawing

AI summary

A method for the etching of deep, high-aspect ratio features into silicon carbide (SiC), gallium nitride (GaN) and similar materials using an Inductively-Coupled Plasma (ICP) etch process technology is described. This technology can also be used to etch features in silicon carbide and gallium nitride having near vertical sidewalls. The disclosed method has application in the fabrication of electronics, microelectronics, power electronics, Monolithic Microwave Integrated Circuits (MMICs), high-voltage electronics, high-temperature electronics, high-power electronics, Light-Emitting Diodes (LEDs), Micro-Electro-Mechanical Systems (MEMS), micro-mechanical devices, microelectronic devices and systems, nanotechnology devices and systems, Nano-Electro-Mechanical Systems (NEMS), photonic devices, and any devices and/or structures made from silicon carbide and/or gallium nitride. The disclosed method also has application in the fabrication of through-substrate vias and through-wafer vias, including those that are subsequently filled with electrically conductive materials.