IGZO Thin-Film Gas Sensor for Room-Temperature NO2 Detection

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Solution Overview

Problem

Existing MOS gas sensors for NO2 detection require high temperatures or continuous light activation, leading to power inefficiency and impractical recovery times, making them unsuitable for real-time monitoring and deployment in critical environments.

Innovation Solution

A CMOS-compatible gas sensor using an IGZO thin-film with specific elemental concentrations (In, Ga, Zn, O) that allows for NO2 detection at room temperature without continuous light exposure, utilizing blue light for quick recovery and minimizing power consumption.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If MOS gas sensors are operated at high temperatures to achieve sensitive NO2 detection, then detection sensitivity is improved, but power consumption increases and the sensor cannot be used in environments with flammable gases

Engineering Contradiction:
Improvedetection sensitivityVSAvoidpower consumption
Core Design Contradiction:
Measurement precisionVSUse of energy by moving object

Solution Approach 1:

The patent changes the operating temperature parameter from high temperature (>200°C) to room temperature operation. This is achieved by using a thin-film transistor structure with specific material composition (In-Ga-Zn-O) that enables sensitive gas detection at lower temperatures, thereby reducing power consumption while maintaining detection capability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs a composite material approach by using a thin-film transistor structure with In-Ga-Zn-O semiconductor layer combined with appropriate gate dielectric and electrode materials. This composite structure enhances the sensing performance at room temperature while maintaining low power operation

Inventive Principle:
Principle #40Composite materials

2Loss of time

If MOS gas sensors are operated at high temperatures to achieve fast recovery time, then recovery speed is improved, but the sensor becomes unsafe for use in environments with flammable or explosive gases

Engineering Contradiction:
Improverecovery timeVSAvoidsafety in flammable environments
Core Design Contradiction:
Loss of timeVSObject-affected harmful factors

Solution Approach 1:

The patent changes the operating temperature parameter from high temperature to room temperature, enabling fast recovery through the thin-film transistor structure's inherent properties rather than thermal activation. This eliminates the safety hazard of igniting flammable gases while maintaining rapid response and recovery capabilities

Inventive Principle:
Principle #35Parameter changes

3Object-affected harmful factors

If light-activated MOS devices are used to operate at room temperature, then safety in flammable environments is improved, but detection sensitivity decreases due to limited optical response

Engineering Contradiction:
Improvesafety in flammable environmentsVSAvoiddetection sensitivity
Core Design Contradiction:
Object-affected harmful factorsVSMeasurement precision

Solution Approach 1:

The patent extracts the light activation requirement from the sensing mechanism. The thin-film transistor structure enables room temperature operation without continuous light exposure, taking out the optical activation step while maintaining both safety and sensitivity through the semiconductor material's electrical properties

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent substitutes the optical activation mechanism with an electrical field-based sensing mechanism. Instead of relying on light to activate the sensing response, the thin-film transistor uses electrical field effects to achieve sensitive detection at room temperature without continuous illumination

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

4Reliability

If continuous light activation is used to maintain sensor activity at room temperature, then detection capability is maintained, but power consumption increases

Engineering Contradiction:
Improvesensing activityVSAvoidpower consumption
Core Design Contradiction:
ReliabilityVSUse of energy by moving object

Solution Approach 1:

The patent extracts the continuous light activation requirement from the system. The thin-film transistor structure maintains sensing activity through its inherent electrical properties at room temperature, eliminating the need for continuous optical illumination and thereby reducing power consumption while maintaining reliability

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution enables sensitive and selective NO2 detection with rapid recovery times, reducing power consumption and making it suitable for real-time monitoring and large-scale deployment in air quality monitoring stations.

Implementation Method 1

the gas interacts with the IGZO thin-film and changes a current through the IGZO thin-film

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

utilizing blue light for quick recovery

Methodology Applied
Scientific EffectPhotodesorption: Desorption

Data Source

PatentUS11867657B2InGaZnO (IGZO) based system for gas detection at room temperature
Publication Date: 2024.01.09 KING ABDULLAH UNIV OF SCI & TECH
  • US11867657B2 patent drawing
  • US11867657B2 patent drawing
  • US11867657B2 patent drawing

AI summary

A gas sensor includes a gate electrode; a dielectric layer covering one surface of the gate electrode; an indium (In) gallium (Ga) zinc (Zn) oxide (O) (IGZO) thin-film formed over the dielectric layer, and first and second metallic electrodes formed on a surface of the IGZO thin-film to act as source and drain, respectively. The IGZO thin-film has an In concentration of 11%+/−3%, Ga concentration of 11%+/−3%, Zn concentration of 7%+/−3%, and O concentration of 71%+/−3%, with a sum of the concentrations being 100%, and the gas interacts with the IGZO thin-film and changes a current through the IGZO thin-film.