IGZO Hard Mask Damascene Etching for Low-Roughness Metal Wiring

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Solution Overview

Problem

Existing substrate processing methods using metal masks like TiN for etching metal wirings in semiconductor manufacturing face issues such as roughness, increased resistance, and high costs due to the use of expensive chemicals, which affect the integrity and efficiency of metal wiring.

Innovation Solution

Employing an IGZO-based metal oxide film as a hard mask with a predetermined amorphous composition to etch dielectric films, reducing roughness and resistance by using a combination of physical vapor deposition and atomic layer deposition, and employing specific etching and cleaning processes to form a damascene or dual damascene structure.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If metal masks like TiN are used for etching metal wirings, then etching precision is improved, but manufacturing cost increases and surface roughness worsens

Engineering Contradiction:
Improveetching precisionVSAvoidmanufacturing cost
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The patent replaces expensive reusable metal masks (TiN) with a disposable organic insulating film hard mask that can be formed through standard semiconductor fabrication processes. This disposable mask approach eliminates the need for costly metal mask materials and reduces manufacturing expenses while maintaining etching precision.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent changes the material parameter from inorganic metal oxide (TiN) to organic insulating film, and controls the crystalline state parameter to ensure the metal oxide layer remains amorphous rather than crystalline. These parameter changes reduce manufacturing cost while preserving etching performance.

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If metal masks like TiN are used for etching metal wirings, then etching precision is improved, but surface roughness increases

Engineering Contradiction:
Improveetching precisionVSAvoidsurface roughness
Core Design Contradiction:
Manufacturing precisionVSShape

Solution Approach 1:

The patent changes the crystalline state parameter of the metal oxide layer from crystalline to amorphous. This parameter change is critical because amorphous metal oxide provides a smoother surface finish during etching, reducing surface roughness while maintaining the necessary etching precision through the organic insulating film hard mask.

Inventive Principle:
Principle #35Parameter changes

3Manufacturing precision

If expensive chemicals are used in substrate processing, then processing quality is improved, but production cost increases

Engineering Contradiction:
Improveprocessing qualityVSAvoidproduction cost
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The patent employs standard organic insulating films and conventional cleaning agents instead of expensive specialized chemicals. The disposable nature of the organic hard mask allows using readily available, cost-effective materials that can be removed through standard cleaning processes, thereby reducing production costs while maintaining processing quality.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent enables the substrate processing system to use its own existing resources - organic insulating films already present in the fabrication process and standard cleaning facilities - rather than requiring external expensive chemicals. This self-service approach reduces dependency on costly specialized materials while maintaining processing quality.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method effectively reduces the roughness and resistance of metal wirings, enhancing the propagation efficiency of electromagnetic signals and reducing production costs by avoiding the need for expensive chemicals.

Implementation Method 1

using a combination of physical vapor deposition and atomic layer deposition

Methodology Applied
Scientific EffectPhysical vapor deposition: Physical Vapour Deposition

Implementation Method 2

forming a resist-related first film in which a first pattern is formed

Methodology Applied
Scientific EffectPhotolithography: Photography

Implementation Method 3

etching the first hard mask to form a recess corresponding to the first pattern in the first hard mask; etching the dielectric film to form the recess corresponding to the first pattern in the dielectric film

Methodology Applied
Scientific EffectPlasma etching: Plasma

Data Source

PatentUS20250372394A1Substrate processing method and substrate processing apparatus
Publication Date: 2025.12.04 TOKYO ELECTRON LTD
  • US20250372394A1 patent drawing
  • US20250372394A1 patent drawing
  • US20250372394A1 patent drawing

AI summary

A substrate processing method includes: providing a substrate having first and second surfaces; forming a dielectric film on the first surface; forming a metal oxide film including one or two or more metal elements with a predetermined composition on the dielectric film; subsequently, forming a resist-related first film in which a first pattern is formed; subsequently, etching the first hard mask to form a recess corresponding to the first pattern in the metal oxide film; etching the dielectric film to form the recess corresponding to the first pattern in the dielectric film; subsequently, cleaning the substrate to remove the metal oxide film; embedding a metal in the recess formed in the dielectric film; and planarizing the metal.