Image Sensor Trench Isolation for Photoelectron Trapping

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Solution Overview

Problem

Image sensors suffer from photoelectron loss due to trap sites on the interfacial surface between thermal oxide layers and substrates, leading to reduced light sensitivity and fill factor of photodiodes.

Innovation Solution

The method involves forming selective epitaxial growth (SEG) channel stop layers doped with boron within trenches to prevent photoelectrons from being trapped at these sites, using a shallow trench isolation process, and filling the trenches with high-density plasma oxide to enhance the separation of photodiodes from trap sites.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If thermal oxide layers are formed on trenches through rounding oxidation process, then inner surfaces of trenches are cured, but trap sites still exist on interfacial surface between thermal oxide layers and substrate causing photoelectron loss

Engineering Contradiction:
Improvephotoelectron trapping preventionVSAvoidtrap sites on interfacial surface
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The harmful interfacial surface between thermal oxide layer and substrate is removed by eliminating the need for rounding oxidation process. The patent forms trenches with vertical walls and directly fills them with isolation material, extracting the problematic thermal oxide layer formation step that created trap sites on curved interfaces.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

Instead of forming rounded trenches and then filling them (which creates interface trap sites), the patent inverts the approach by forming vertical-walled trenches and directly filling them with isolation material, eliminating the thermal oxide layer formation step that caused the harmful effect.

Inventive Principle:
Principle #13The other way round (Inversion)

2Reliability

If boron is implanted into sidewall and bottom surfaces of trenches to form NCST impurity regions, then photoelectrons are prevented from being trapped in trap sites, but horizontal portion of NCST impurity regions has thickness of 0.1-0.2 μm reducing photodiode area

Engineering Contradiction:
Improvephotoelectron trapping preventionVSAvoidphotodiode area
Core Design Contradiction:
ReliabilityVSArea of stationary object

Solution Approach 1:

The patent extracts and eliminates the need for NCST impurity regions by removing the source of trap sites (thermal oxide layers on rounded trenches). Since vertical-walled trenches filled with isolation material do not create interface trap sites, the additional boron implantation step and associated horizontal impurity regions are no longer necessary, preserving photodiode area.

Inventive Principle:
Principle #2Taking out (Extraction)

3Stability of the object's composition

If rounding oxidation process is performed to form thermal oxide layers on trenches, then inner surfaces are cured, but light characteristic is deteriorated due to reduced photodiode area

Engineering Contradiction:
Improvetrench inner surface stabilityVSAvoidlight characteristic
Core Design Contradiction:
Stability of the object's compositionVSIllumination intensity

Solution Approach 1:

The patent removes the rounding oxidation process entirely, extracting the thermal oxide layer formation step that consumed photodiode area. Vertical-walled trenches provide sufficient structural stability without requiring thermal oxide curing, thus preserving light characteristics and photodiode area.

Inventive Principle:
Principle #2Taking out (Extraction)

4Ease of manufacture

If shallow trench isolation process is used to form trenches in substrate, then isolation structure is created, but micro defects result on inner walls of trenches due to damages during etching

Engineering Contradiction:
Improveisolation structure formationVSAvoidtrench inner wall quality
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent changes the etching parameters to achieve vertical walls instead of rounded walls. By adjusting etching conditions (such as using selective etchants or controlling etch depth), vertical-walled trenches are formed that reduce micro defects on inner walls while maintaining the isolation function, eliminating the need for subsequent rounding oxidation.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach reduces photoelectron loss and increases the fill factor of photodiodes by minimizing trap sites and improving light sensing efficiency.

Implementation Method 1

forming selective epitaxial growth (SEG) channel stop layers doped with boron within trenches

Methodology Applied
Scientific EffectEpitaxial growth: Epitaxy

Implementation Method 2

filling the trenches with high-density plasma oxide

Methodology Applied
Scientific EffectPlasma deposition: Plasma

Data Source

PatentUS8476685B2Image sensor and method for fabricating the same
Publication Date: 2013.07.02 INTELLECTUAL VENTURES II LLC
  • US8476685B2 patent drawing
  • US8476685B2 patent drawing
  • US8476685B2 patent drawing

AI summary

An image sensor includes a trench formed by a shallow trench isolation (STI) process, a channel stop layer formed over a substrate in the trench, an isolation structure filled in the trench, and a photodiode formed in the substrate adjacent to a sidewall of the trench. In more detail of the image sensor, a trench is formed in a substrate through a STI process, and a channel stop layer is formed over the substrate in the trench. An isolation structure is formed in the trench, and a photodiode is fanned in the substrate adjacent to a sidewall of the trench.