Imide-Functionalized Comb Polymers for Engine Oil Friction Reduction

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Solution Overview

Problem

Current lubricant compositions, including engine oils, face challenges in reducing fuel consumption and friction while maintaining effective viscometric properties, as existing comb polymers primarily focus on viscosity index improvement without significant friction reduction.

Innovation Solution

A polyalkyl(meth)acrylate based comb polymer with specific composition and imide functionality, achieved through grafting maleic anhydride and primary amines, is introduced to reduce friction coefficients and enhance fuel economy in lubricating oil compositions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If conventional comb polymers are used as viscosity index improvers, then viscometric properties are improved, but friction reduction effect is not achieved

Engineering Contradiction:
Improveviscometric propertiesVSAvoidfriction
Core Design Contradiction:
Stability of the object's compositionVSObject-generated harmful factors

Solution Approach 1:

The patent combines viscosity index improvement function and friction reduction function into a single comb polymer molecule. The polymer backbone provides viscometric properties while grafted imide functional groups provide friction reduction, eliminating the need for separate additives

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The comb polymer is designed to perform multiple functions simultaneously: it acts as both a viscosity index improver and a friction modifier. The imide functional groups enable the polymer to interact with metal surfaces to reduce friction while the overall polymer structure maintains viscometric properties

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Object-generated harmful factors

If friction modifiers are added to reduce friction, then friction coefficients are reduced, but the complexity of lubricant composition increases

Engineering Contradiction:
Improvefriction coefficientsVSAvoidlubricant composition
Core Design Contradiction:
Object-generated harmful factorsVSDevice complexity

Solution Approach 1:

The comb polymer serves as a multi-functional additive that simultaneously provides viscosity index improvement and friction reduction. This eliminates the need for separate friction modifier additives, simplifying the overall lubricant composition

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The patent merges the functions of viscosity index improver and friction modifier into a single polymer molecule. The comb structure with imide functional groups integrates both functionality, reducing the number of components needed in the lubricant formulation

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The described comb polymer significantly reduces friction coefficients and improves fuel economy by balancing viscometric properties, leading to lower fuel consumption and cost-effective engine oil formulations without the need for additional friction modifiers.

Implementation Method 1

The comb polymers can be used in lubricant compositions, in order to reduce friction coefficients

Methodology Applied
Scientific EffectFriction modification: Friction

Implementation Method 2

The main mechanism of the fuel saving properties of combs are their superior viscometric properties in a typical engine oil or driveline formulation

Methodology Applied
Scientific EffectViscosity modification: Viscometer

Data Source

PatentUS11072677B2Comb polymers comprising imide functionality
Publication Date: 2021.07.27 EVONIK OPERATIONS GMBH
  • US11072677B2 patent drawing
  • US11072677B2 patent drawing
  • US11072677B2 patent drawing

AI summary

Selected comb polymers include specified amounts of macromonomer and imide functionalization. Further, a method is useful for the preparation of such comb polymers. Lubricant compositions including such comb polymers are useful for reducing wear and fuel consumption of lubricant compositions, especially of engine oil (EO) compositions.