Impactor Ion Source Target Electrodes for High Gas Flow

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Solution Overview

Problem

Conventional impactor spray atmospheric pressure ionization ion sources experience significant ion signal loss at high cone gas flow rates, which is problematic for mass spectrometry applications.

Innovation Solution

The ion source incorporates one or more nebulizers emitting a stream of droplets that impact on targets with electrodes having apertures, notches, or cut-outs, which helps to maintain or enhance ion signal intensity by shaping the electric field and reducing dispersive gas flow, even at high cone gas flow rates.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If high cone gas flow rate is used to reduce ion inlet contamination and background chemical noise, then purity is improved, but ion signal intensity deteriorates due to significant ion signal loss

Engineering Contradiction:
Improveion inlet contamination and background chemical noiseVSAvoidion signal intensity
Core Design Contradiction:
Object-affected harmful factorsVSQuantity of substance

Solution Approach 1:

The ion source is segmented into distinct functional zones: a nebulization region, an impactor region with target rod, and an extraction region with electrodes. This segmentation allows the curtain gas to effectively protect the inlet while electrostatic fields in the extraction region recover and guide ions toward the detector, preventing signal loss despite high gas flow rates.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Electrodes positioned around the target rod act as intermediaries that create electrostatic fields to guide ions through the high-velocity gas flow. These electrodes mediate between the ionization region and the detector, ensuring ions are efficiently extracted and transmitted even when curtain gas flow is high enough to block neutral contaminants.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Productivity

If high velocity liquid spray is used to enhance ionization efficiency, then productivity is improved, but ion signal loss increases due to stronger interaction with curtain gas

Engineering Contradiction:
Improveionization efficiencyVSAvoidion signal intensity
Core Design Contradiction:
ProductivityVSQuantity of substance

Solution Approach 1:

The liquid spray is pre-nebulized into fine droplets before reaching the target rod, creating a dispersed cloud that ionizes more efficiently upon impact. This preliminary nebulization ensures high ionization efficiency while the subsequent electrostatic extraction quickly collects the generated ions before they can be dispersed by the curtain gas flow.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The mechanical momentum of the high-velocity spray is replaced by electrostatic forces for ion extraction and guidance. Instead of relying solely on the spray's kinetic energy to overcome gas flow, electrostatic fields are used to accelerate and guide ions toward the detector, maintaining signal intensity despite high curtain gas rates that would otherwise cause loss.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration improves ion signal intensity and reduces source contamination and chemical background noise, allowing for effective interfacing with mass spectrometers even under conditions of strong curtain gas flow.

Implementation Method 1

a stream predominantly of droplets which are caused to impact upon the one or more targets and to ionise the droplets to form a plurality of ions

Methodology Applied
Scientific EffectImpact ionization: Ionisation

Implementation Method 2

one or more electrodes arranged adjacent to and/or attached to the one or more targets wherein the one or more electrodes comprise one or more apertures, notches or cut-outs wherein at least some of the plurality of ions pass

Methodology Applied
Scientific EffectElectric field: Electric Field

Data Source

PatentUS9953819B2Impactor spray atmospheric pressure ion source with target paddle
Publication Date: 2018.04.24 MICROMASS UK LTD
  • US9953819B2 patent drawing
  • US9953819B2 patent drawing
  • US9953819B2 patent drawing

AI summary

An ion source is provided comprising one or more nebulizers and one or more targets, wherein the one or more nebulizers are arranged and adapted to emit, in use, a stream predominantly of droplets which are caused to impact upon the one or more targets and to ionise the droplets to form a plurality of ions. The ion source further comprises one or more electrodes arranged adjacent to and/or attached to the one or more targets wherein the one or more electrodes comprise one or more apertures, notches or cut-outs wherein at least some of the plurality of ions pass, in use, through the one or more apertures, notches or cut-outs.