Ion Mobility Spectrometer Field Switching Ion Gate

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Solution Overview

Problem

Ion mobility spectrometers face limitations in resolution capability and sensitivity due to the absence of additional electrodes, leading to inefficiencies in ion transfer and potential field interference, which complicates the analysis of samples.

Innovation Solution

Incorporating a first additional electrode between the ion gate and the drift chamber to enable extended field switching methods, such as double field switching and extended double field switching, which improves ion packet compression and shielding, thereby enhancing resolution and sensitivity without increasing the device's length.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If additional electrodes are added to improve resolution and sensitivity, then analytical capability is improved, but device complexity increases

Engineering Contradiction:
Improveresolution capabilityVSAvoiddevice complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

A field switching ion gate is introduced as an intermediary component between the ionization chamber and drift chamber. This ion gate uses electric field switching to control ion transfer, replacing what would otherwise require complex additional electrodes for ion packet compression and shielding, thus improving resolution without proportionally increasing device complexity

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent applies parameter changes by dynamically switching electric field parameters (voltage, timing) to achieve different functional states. The field switching ion gate uses controlled voltage changes to compress ion packets and shield against field interference, enhancing measurement precision through parameter optimization rather than structural complexity

Inventive Principle:
Principle #35Parameter changes

2Measurement precision

If drift chamber length is increased to improve resolution, then resolution capability is improved, but device length increases

Engineering Contradiction:
Improveresolution capabilityVSAvoiddrift chamber length
Core Design Contradiction:
Measurement precisionVSLength of moving object

Solution Approach 1:

Ion packet compression is performed preliminarily in the field switching ion gate before ions enter the drift chamber. By compressing the ion packets in advance using electric field switching, the required drift chamber length for achieving high resolution is reduced, thus improving resolution capability without increasing overall device length

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent replaces mechanical extension of the drift chamber with an electric field-based compression mechanism. Instead of lengthening the drift chamber mechanically to improve resolution, electric field switching is used to compress ion packets, achieving high resolution in a more compact configuration

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Ease of manufacture

If field switching ion gate is used to reduce device complexity, then ease of manufacture is improved, but ion transfer control capability deteriorates

Engineering Contradiction:
Improveease of manufactureVSAvoidion transfer control capability
Core Design Contradiction:
Ease of manufactureVSAdaptability or versatility

Solution Approach 1:

The field switching ion gate implements dynamic control of ion transfer through time-dependent voltage switching. The ion gate can dynamically adjust its state (open/closed, compression/shielding) by changing electric field parameters in real-time, maintaining versatile ion transfer control capability while using a simpler structure that is easier to manufacture compared to static multi-electrode systems

Inventive Principle:
Principle #15Dynamics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The additional electrode allows for increased resolution and sensitivity in ion mobility spectrometry by efficiently compressing and shielding ions, allowing for compact and cost-effective construction of the spectrometer while maintaining high analytical performance.

Implementation Method 1

the first ion gate is embodied as a field switching ion gate comprising at least a first counter electrode and a first injection electrode

Methodology Applied
Scientific EffectField switching: Electric Field

Implementation Method 2

ions to be transferred into the first drift chamber by means of the first ion gate additionally being able to be influenced by said first additional electrode

Methodology Applied
Scientific EffectIon packet compression: Compression

Implementation Method 3

ions to be transferred into the first drift chamber by means of the first ion gate additionally being able to be influenced by said first additional electrode

Methodology Applied
Scientific EffectField shielding: Electric Field

Data Source

PatentUS11366078B2Ion mobility spectrometer and method for analyzing samples by ion mobility spectrometry
Publication Date: 2022.06.21 GOTTFRIED WILHELM LEIBNIZ UNIV HANNOVER
  • US11366078B2 patent drawing
  • US11366078B2 patent drawing
  • US11366078B2 patent drawing

AI summary

The invention relates to an ion mobility spectrometer which has at least a first drift chamber and a first switchable ion gate for the controlled transfer of ions into the first drift chamber, wherein: —the first ion gate is designed as a field switching ion gate having at least a first counter electrode and a first injection electrode; wherein—a first ionization chamber is formed between the first counter electrode and the first injection electrode, into which first ionization chamber ions to be analyzed by ion mobility spectrometry can be fed from an ionization source. The invention also relates to an ion mobility spectrometer which has at least a first drift chamber and a first switchable ion gate for the controlled transfer of ions into the first drift chamber and a second drift chamber separated from the first drift chamber and a second switchable ion gate for the controlled transfer of ions into the second drift chamber. The invention also relates to a method for analyzing samples by ion mobility spectrometry by means of an ion mobility spectrometer, e.g. an ion mobility spectrometer of the aforementioned type, wherein by means of an ionization source ions to be analyzed are produced from the sample and are provided in an ionization chamber of the ion mobility spectrometer.