In-situ Oxygen Analyzer with Solid Electrolyte Sensor

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Solution Overview

Problem

Existing oxygen analyzer technologies struggle to accurately measure oxygen levels in combustion processes due to interference from non-oxygen gases like carbon monoxide and combustibles, leading to inefficiencies and safety concerns.

Innovation Solution

An improved oxygen analyzer system that includes a zirconia-based oxygen sensor with catalytic beads, capable of detecting changes in oxygen concentration over time to quantify carbon monoxide and unburned fuel presence, thereby enhancing combustion control.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If traditional oxygen sensors are used in combustion processes, then oxygen concentration can be measured, but measurement precision deteriorates due to interference from non-oxygen gases like carbon monoxide and combustibles

Engineering Contradiction:
Improveoxygen concentration measurement accuracyVSAvoidinterference from non-oxygen gases
Core Design Contradiction:
Measurement precisionVSObject-affected harmful factors

Solution Approach 1:

The patent segments the measurement function by using multiple sensors: a primary oxygen sensor for oxygen concentration measurement and a secondary sensor for detecting interfering gases like carbon monoxide and combustibles. This segmentation allows the system to distinguish between oxygen signals and interference signals, thereby improving measurement precision while accounting for harmful factors.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent introduces an intermediary processing system that receives signals from both the oxygen sensor and the interfering gas sensor. This intermediary system processes and differentiates the signals to compensate for interference effects, enabling accurate oxygen measurement even in the presence of non-oxygen gases.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Object-generated harmful factors

If combustion efficiency is maximized to reduce emissions, then harmful gas production decreases, but measurement reliability deteriorates due to increased interference from combustibles

Engineering Contradiction:
Improvegreenhouse gas emissionsVSAvoidoxygen sensor reliability
Core Design Contradiction:
Object-generated harmful factorsVSReliability

Solution Approach 1:

The patent implements a feedback mechanism where the secondary sensor continuously monitors interfering gases and provides correction signals to the oxygen measurement system. This feedback loop maintains measurement reliability even when combustion conditions change and interfere with the primary oxygen sensor, allowing the system to operate at maximum efficiency while compensating for variable interference levels.

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The patent changes the measurement parameters by monitoring not only oxygen concentration but also the concentration of interfering substances. By measuring multiple parameters simultaneously and analyzing their relationships, the system can distinguish between actual oxygen variations and variations caused by combustion efficiency changes, thereby maintaining reliability under different operating conditions.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The system provides precise and reliable measurements of oxygen concentration, enabling effective detection of carbon monoxide and unburned fuel, which improves combustion efficiency, safety, and stability.

Implementation Method 1

The response of the sensor to differential oxygen concentrations with fixed partial pressure on the reference electrode, e.g., using air, can be calculated using the Nernst Equation

Methodology Applied
Scientific EffectNernst Equation: Nernst Effect

Implementation Method 2

The oxygen sensor has catalytic beads that are configured to be disposed between the process gas and the sensing electrode

Methodology Applied
Scientific EffectCatalysis: Catalysis

Data Source

PatentUS12281999B2In-situ oxygen analyzer with solid electrolyte oxygen sensor and ancillary output
Publication Date: 2025.04.22 ROSEMOUNT INC
  • US12281999B2 patent drawing
  • US12281999B2 patent drawing
  • US12281999B2 patent drawing

AI summary

An improved oxygen analyzer includes a controller configured to receive an oxygen sensor signal and provide an oxygen concentration output. A probe is configured to extend into a source of combustion process gas. An oxygen sensor is disposed within the probe and has a sensing electrode mounted to one side of a solid electrolyte and a reference electrode mounted to an opposite side of the solid electrolyte. The oxygen sensor has catalytic beads that are configured to be disposed between the process gas and the sensing electrode. Measurement circuitry is operably coupled to the oxygen sensor and the controller and is configured to provide the controller with the oxygen sensor signal based on an electrical response of the oxygen sensor. The controller is configured to detect a behavior of the oxygen sensor concentration output over time to provide at least one ancillary output.