Induction Heated Aromatization Reactor for Hydrocarbon Processing

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Solution Overview

Problem

Current industrial processes for aromatization of higher hydrocarbons face challenges such as catalyst deactivation due to carbon formation, high energy consumption, and the need for expensive materials to prevent corrosion, which result in inefficient and unstable reactions.

Innovation Solution

A reactor system using a catalytic mixture of ferromagnetic materials and catalysts, where induction heating provides controlled heat for the dehydrogenation reaction, reducing carbon formation and maintaining lower reaction temperatures to enhance catalyst stability and energy efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If high temperatures (500-700°C) are used for dehydrogenation and aromatization, then reaction rate and conversion are improved, but carbon formation increases leading to catalyst deactivation and metal dusting corrosion

Engineering Contradiction:
Improvereaction rateVSAvoidcarbon formation
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

A heat transfer fluid acts as an intermediary medium to provide controlled heating to the reactor. This allows maintaining necessary reaction temperatures while avoiding direct flame contact and localized overheating that causes carbon formation. The fluid mediates heat transfer in a controlled manner, preventing thermal runaway and reducing parasitic reactions.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention changes the heating method from direct fire heating to indirect fluid heating, and optimizes temperature parameters to stay below the threshold for excessive carbon formation. By carefully controlling the heating temperature and distribution, the system maintains high reaction rates while minimizing carbon deposition on catalyst and reactor walls.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If frequent catalyst regeneration is performed to remove carbon deposits, then catalyst activity is maintained, but production time is lost and operational complexity increases

Engineering Contradiction:
Improvecatalyst activityVSAvoidproduction time
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The invention takes preliminary action to prevent carbon formation by using controlled heat transfer fluid heating and optimizing reaction conditions. By preventing carbon deposits before they form, the need for frequent regeneration is eliminated, maintaining continuous production without interruption.

Inventive Principle:
Principle #9Preliminary anti-action

3Reliability

If expensive alloys are used for reactor and piping materials, then resistance to metal dusting corrosion is improved, but capital cost increases

Engineering Contradiction:
Improvecorrosion resistanceVSAvoidcapital cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

By changing the heating method to controlled fluid heating with temperatures optimized to stay below carbon formation thresholds, the invention reduces carbon deposition and metal dusting corrosion. This allows using less expensive, more easily manufactured materials while maintaining adequate corrosion resistance, thereby reducing capital costs.

Inventive Principle:
Principle #35Parameter changes

4Loss of energy

If adiabatic reactors with sequential heating are used, then energy efficiency is improved, but temperature control precision deteriorates

Engineering Contradiction:
Improveenergy efficiencyVSAvoidtemperature control
Core Design Contradiction:
Loss of energyVSMeasurement precision

Solution Approach 1:

The heat transfer fluid system incorporates temperature monitoring and control mechanisms that provide feedback to adjust heating rates. This ensures precise temperature control throughout the reactor, maintaining optimal conditions for dehydrogenation while preventing localized overheating that would cause carbon formation.

Inventive Principle:
Principle #23Feedback

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The system achieves improved catalyst stability, reduced parasitic reactions, and increased energy efficiency, allowing for better control of reaction temperatures and higher yields while minimizing catalyst regeneration frequencies.

Implementation Method 1

an induction coil arranged to be powered by a power source supplying alternating current and being positioned so as to generate an alternating magnetic field within the reactor unit upon energization by the power source, whereby the ferromagnetic material is heated to a temperature within said temperature range T by means of said alternating magnetic field

Methodology Applied
Scientific EffectInduction heating: Induction Heating

Implementation Method 2

generate an alternating magnetic field within the reactor unit upon energization by the power source

Methodology Applied
Scientific EffectAlternating magnetic field: Alternating Magnetic Field

Implementation Method 3

the ferromagnetic material is heated to a temperature within said temperature range T by means of said alternating magnetic field

Methodology Applied
Scientific EffectMagnetic hysteresis: Magnetic Hysteresis

Data Source

PatentUS11331638B2Induction heated aromatization of higher hydrocarbons
Publication Date: 2022.05.17 HALDOR TOPSOE AS
  • US11331638B2 patent drawing
  • US11331638B2 patent drawing

AI summary

A reactor system for aromatization of higher hydrocarbons within a given temperature range T upon bringing a reactant stream including higher hydrocarbons into contact with a catalytic mixture. The reactor system includes a reactor unit arranged to accommodate a catalytic mixture. The catalytic mixture includes a catalyst material and a ferromagnetic material. The catalyst material is arranged to catalyze the aromatization of higher hydrocarbons. The ferromagnetic material is ferromagnetic at least at temperatures up to an upper limit of the given temperature range T, where the temperature range T is the range from between about 400° C. and about 700° C. or a subrange thereof. The reactor system also includes an induction coil arranged to be powered by a power source supplying alternating current, whereby the ferromagnetic material is heated to a temperature within the temperature range T by means of an alternating magnetic field.