Inductive Heating Alkane Dehydrogenation Catalyst

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Solution Overview

Problem

Current dehydrogenation processes of alkanes face challenges such as high temperature requirements, catalyst deactivation due to carbon formation, and costly materials needed to prevent corrosion, which lead to inefficiencies and frequent catalyst regeneration.

Innovation Solution

A reactor system using a catalytic mixture with ferromagnetic material, where catalyst particles are in intimate contact with ferromagnetic material, heated by an alternating magnetic field, reducing the need for high temperatures and minimizing parasitic reactions like coking and cracking.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If high temperature processes (above 450°C) are used for dehydrogenation, then conversion is improved, but catalyst deactivation due to carbon formation worsens

Engineering Contradiction:
ImproveconversionVSAvoidcatalyst stability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The invention changes the heating method from conventional external heating to inductive heating, which enables precise temperature control and maintains optimal reaction temperature (450-650°C) while preventing excessive temperature that causes carbon formation. This parameter control resolves the contradiction between maintaining high conversion and preventing catalyst deactivation

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The inductive heating system provides real-time temperature monitoring and control through the induction coil, creating a feedback mechanism that adjusts heating power to maintain optimal temperature. This prevents temperature excursions that would lead to coking while ensuring sufficient conversion, thus resolving the contradiction between productivity and reliability

Inventive Principle:
Principle #23Feedback

2Productivity

If high temperature processes are used for dehydrogenation, then conversion is improved, but energy consumption increases

Engineering Contradiction:
ImproveconversionVSAvoidenergy consumption
Core Design Contradiction:
ProductivityVSUse of energy by moving object

Solution Approach 1:

The inductive heating system heats the catalyst bed directly through electromagnetic induction without requiring external furnaces or heat exchangers. The catalyst particles themselves with ferromagnetic properties serve as the heating element, eliminating energy losses through reactor walls and reducing overall energy consumption while maintaining high conversion

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The invention replaces conventional thermal heating mechanisms (furnaces, heat exchangers, thermal conduction) with electromagnetic induction heating. This substitution enables more efficient energy transfer directly to the catalyst particles, reducing energy consumption while achieving the same or better conversion rates

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Temperature

If conventional heating methods are used, then heating is achieved, but temperature control accuracy worsens

Engineering Contradiction:
Improveheating capabilityVSAvoidtemperature control accuracy
Core Design Contradiction:
TemperatureVSMeasurement precision

Solution Approach 1:

The inductive heating system incorporates real-time temperature monitoring through thermocouples or other sensors positioned within the catalyst bed, with feedback control adjusting the induction coil power to maintain precise temperature. This feedback mechanism achieves accurate temperature control that conventional external heating cannot provide

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The heating is applied segmentally through the induction coil positioned around specific zones of the catalyst bed, allowing independent temperature control of different reactor sections. This segmentation enables precise temperature profiling along the reactor length, improving temperature control accuracy compared to uniform conventional heating

Inventive Principle:
Principle #1Segmentation

Data Source

PatentUS10987646B2Dehydrogenation of alkanes
Publication Date: 2021.04.27 HALDOR TOPSOE AS
  • US10987646B2 patent drawing
  • US10987646B2 patent drawing
  • US10987646B2 patent drawing

AI summary

A reactor system for dehydrogenation of alkanes in a given temperature range upon bringing a reactant stream including alkanes into contact with a catalytic mixture. The reactor system includes a reactor unit arranged to accommodate the catalytic mixture, where the catalytic mixture includes catalyst particles and a ferromagnetic material. The catalyst particles are arranged to catalyze the dehydrogenation of alkanes. The ferromagnetic material is ferromagnetic at least at temperatures up to an upper limit of the given temperature range. The reactor system moreover includes an induction coil arranged to be powered by a power source supplying alternating current and being positioned so as to generate an alternating magnetic field within the reactor unit upon energization by the power source, whereby the catalytic mixture is heated to a temperature within the temperature range by means of the alternating magnetic field. Also, a catalytic mixture and a method of dehydrogenating alkanes.