Inert Anode Electroplating Replenisher

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Electroplating processors using consumable anodes are complex and costly, while inert anode systems face challenges in maintaining metal ion concentration and generating defects, necessitating a more efficient and cost-effective solution for semiconductor manufacturing.

Innovation Solution

An electroplating processor with an inert anode and a vessel-catholyte replenisher system that circulates electrolyte and adds metal ions through a catholyte membrane or directly, maintaining metal ion concentration and reducing chamber complexity and maintenance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If consumable anodes are used, then metal ion concentration is maintained effectively, but device complexity and cost increase

Engineering Contradiction:
Improvemetal ion concentrationVSAvoidanode replacement system complexity
Core Design Contradiction:
Quantity of substanceVSDevice complexity

Solution Approach 1:

The patent extracts the anode function from the plating chamber by using a separate replenisher system. The replenisher contains the consumable anode material and transfers metal ions to the plating bath through a membrane, separating the consumption function from the plating function and reducing chamber complexity.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent introduces a membrane as an intermediary between the replenisher and the plating chamber. This membrane allows selective transfer of metal ions while keeping the consumable anode material contained in the replenisher, enabling maintenance of metal ion concentration without direct anode replacement in the chamber.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Quantity of substance

If consumable anodes are used, then metal ion replenishment is achieved, but maintenance requirements increase

Engineering Contradiction:
Improvemetal ion concentrationVSAvoidanode maintenance
Core Design Contradiction:
Quantity of substanceVSEase of repair

Solution Approach 1:

The consumable anode is extracted from the plating chamber and placed in a separate replenisher system. This allows the anode to be consumed and replenished outside the main chamber, reducing maintenance interruptions to the plating process and improving ease of repair.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The replenisher system is designed to automatically transfer metal ions from the consumable anode to the plating bath through the membrane. This self-service mechanism reduces the need for manual intervention and maintenance of the anode system.

Inventive Principle:
Principle #25Self-service

3Device complexity

If inert anodes are used, then device complexity is reduced, but metal ion concentration cannot be maintained

Engineering Contradiction:
Improveanode system complexityVSAvoidmetal ion concentration
Core Design Contradiction:
Device complexityVSQuantity of substance

Solution Approach 1:

The membrane acts as an intermediary that enables metal ion transfer from the replenisher to the plating chamber while using inert anodes. This allows the inert anode system to maintain metal ion concentration through the replenisher-membrane mechanism, resolving the contradiction between simplicity and effectiveness.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The metal ion replenishment function is extracted from the anode itself and placed in a separate replenisher system. This allows inert anodes to be used in the plating chamber while maintaining metal ion concentration through the external replenisher, combining the benefits of simplicity and effectiveness.

Inventive Principle:
Principle #2Taking out (Extraction)

4Ease of repair

If inert anodes are used, then maintenance is reduced, but gas generation causes defects

Engineering Contradiction:
Improveanode maintenanceVSAvoidgas generation
Core Design Contradiction:
Ease of repairVSObject-generated harmful factors

Solution Approach 1:

The harmful gas generation is extracted from the plating chamber by placing the consumable anode in a separate replenisher system. The gas is generated in the replenisher rather than in the plating chamber, preventing defects on the workpiece while maintaining reduced maintenance requirements.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The membrane serves as an intermediary that separates the gas generation zone (replenisher) from the plating zone. This allows gas to be generated in the replenisher without affecting the plating process, eliminating defects while maintaining the benefits of the inert anode system.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This solution simplifies the electroplating processor design, maintains stable metal ion concentration, and increases uptime by centralizing copper replenishment, allowing for higher plating rates and improved feature morphology without the need for frequent maintenance.

Implementation Method 1

The vessel-catholyte replenisher adds metal ions into the vessel-catholyte by moving ions of a bulk metal through a catholyte membrane in the vessel-catholyte replenisher

Methodology Applied
Scientific EffectIon transport through membrane: Semipermeable Membrane

Implementation Method 2

use of inert anodes has led to other disadvantages, especially related to maintaining the metal ion concentration in a cost effective manner compared to consumable anodes and the generation of gas at the inert anode

Methodology Applied
Scientific EffectGas generation at electrode: Electrolysis

Implementation Method 3

Metal ions in the electrolyte plate out onto the wafer, creating a metal layer on the wafer

Methodology Applied
Scientific EffectElectroplating: Electroplating

Data Source

PatentUS10227707B2Inert anode electroplating processor and replenisher
Publication Date: 2019.03.12 APPLIED MATERIALS INC
  • US10227707B2 patent drawing
  • US10227707B2 patent drawing
  • US10227707B2 patent drawing

AI summary

An electroplating processor has a vessel holding an electrolyte. An inert anode in the vessel has an anode wire within an anode membrane tube. A head for holds a wafer in contact with the electrolyte in the vessel. The wafer is connected to a cathode. A catholyte replenisher is connected to the vessel. The catholyte replenisher adds metal ions into the catholyte by moving ions of a bulk metal through a catholyte membrane in the catholyte replenisher.