Inhibited Starch Emulsifiers for Stable Foams

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Solution Overview

Problem

There is a need for highly stable emulsions and foams in the food and personal care industries that utilize natural and sustainable products while maintaining the stability of Pickering particulate emulsifiers, which conventional starches fail to achieve due to gelatinization and dissolution issues.

Innovation Solution

Inhibited starch products with a protein content of 0.2-8 wt% and a median primary particle size of 0.2-5 microns, which can stabilize emulsions and foams even under extreme conditions such as high pH, temperature, and shear, by retaining their granular structure and resisting fragmentation during cooking and processing.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional starches are used as emulsifiers, then they are natural and sustainable, but they fail to provide long-term stability due to gelatinization and dissolution

Engineering Contradiction:
Improveemulsion stabilityVSAvoidstarch granular structure
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent applies parameter changes by controlling the particle size of starch to a specific range (0.2-5 microns median primary particle size) and adjusting protein content (0.2-8 wt%) to prevent gelatinization and dissolution, thereby maintaining emulsion stability under extreme conditions including high temperature and shear

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite material system by combining starch with specific protein content (0.2-8 wt%) to form a hybrid emulsifier that leverages both the natural sustainability of starch and the stabilizing properties of protein, achieving Pickering-like stability without requiring chemical modifications

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If starch is gelatinized to improve processing, then it becomes more functional, but it loses emulsifying capability and stability

Engineering Contradiction:
Improveprocessing functionalityVSAvoidemulsifying capability
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent maintains emulsifying capability by controlling the gelatinization parameter - keeping starch particles in a specific size range (0.2-5 microns) and protein content (0.2-8 wt%) that prevents complete gelatinization, allowing the starch to remain functional for emulsification while retaining stability under processing conditions including heat and shear

Inventive Principle:
Principle #35Parameter changes

3Reliability

If Pickering particulate emulsifiers are used to achieve extreme stability, then long-term stability is obtained, but natural and sustainable products are compromised

Engineering Contradiction:
Improvelong-term stabilityVSAvoidchemical modifications
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent replaces complex chemical Pickering emulsifiers with a simpler, natural starch-based system that achieves comparable stability. The starch particles (0.2-5 microns) with protein content (0.2-8 wt%) act as natural Pickering emulsifiers, providing extreme long-term stability without requiring synthetic chemical modifications or crosslinking agents

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent creates a natural composite emulsifier system combining starch and protein that mimics the stability mechanism of Pickering emulsions. The specific particle size (0.2-5 microns) and protein content (0.2-8 wt%) create a hybrid material that achieves Pickering-like stability while remaining entirely natural and sustainable

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The inhibited starches effectively stabilize emulsions and foams, providing long-term stability and retaining emulsifying capability even in cooked systems, making them suitable for various food and personal care products without the need for chemical modifications or crosslinking agents.

Implementation Method 1

The particles (e.g., colloidal silica, titanium oxide or clays, latex, fat crystals, aggregated proteins, cocoa powder and others) are also able to adsorb onto the interface between the two phases to stabilize the emulsion and/or foam.

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

Synthetic surfactants, adsorbed to the interface of the two phases, typically have been used to increase the stability of emulsions and foams by, e.g., decreasing the interfacial tension, among other physical principles.

Methodology Applied
Scientific EffectSurface tension reduction: Surface Tension

Data Source

PatentUS20240182602A1Inhibited starches, methods for making and using them, and emulsions and foams including them
Publication Date: 2024.06.06 TATE & LYLE SOLUTIONS USA LLC
  • US20240182602A1 patent drawing
  • US20240182602A1 patent drawing
  • US20240182602A1 patent drawing

AI summary

The present disclosure provides inhibited starches, methods of making inhibited starches, and emulsions and foams including them, and food and beverage products including them.