Ink Composition for Semiconductor Nanorod Alignment

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Solution Overview

Problem

The challenge lies in developing an ink composition that enhances the dispersion stability and migration properties of semiconductor nanorods in solvents, particularly for ultra-small LED devices, where existing solvents fail to maintain alignment and stability due to low viscosity and rapid volatilization, leading to sedimentation and agglomeration issues.

Innovation Solution

An ink composition comprising semiconductor nanorods with a diameter of 300 nm to 900 nm, coated with metal oxides like alumina or silica, and a mixed solvent system with a dielectric constant ≤20, viscosity of 60 cps to 110 cps, and volatilization temperature between 200° C. to 400° C., which includes additives such as malonic acid, silane-based coupling agents, and fluorine-based surfactants to improve stability and alignment.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If conventional solvents with low viscosity are used, then the ink composition flows easily, but the semiconductor nanorods sediment and aggregate rapidly

Engineering Contradiction:
ImproveflowabilityVSAvoiddispersion stability
Core Design Contradiction:
Ease of operationVSStability of the object's composition

Solution Approach 1:

The patent changes the viscosity parameter of the solvent from low (conventional) to high (60-110 cps), which directly addresses the contradiction by preventing sedimentation and aggregation of semiconductor nanorods while maintaining adequate flowability for inkjet printing and electrode coverage

Inventive Principle:
Principle #35Parameter changes

2Speed

If conventional solvents with low dielectric constant are used, then the migration speed is high, but the alignment precision is poor

Engineering Contradiction:
Improvemigration speedVSAvoidalignment precision
Core Design Contradiction:
SpeedVSManufacturing precision

Solution Approach 1:

The patent optimizes the dielectric constant parameter to a specific range (1-20) that balances migration speed and alignment precision. This parameter change enables semiconductor nanorods to migrate at appropriate speeds while achieving normal alignment of 80% or more, resolving the contradiction between speed and precision

Inventive Principle:
Principle #35Parameter changes

3Ease of operation

If conventional solvents are used, then the ink composition is easy to apply, but the storage stability is poor due to rapid volatilization

Engineering Contradiction:
ImproveapplicabilityVSAvoidstorage stability
Core Design Contradiction:
Ease of operationVSDuration of action of stationary object

Solution Approach 1:

The patent changes the volatilization temperature parameter from low (conventional) to high (200-400°C), which directly improves storage stability by preventing rapid solvent evaporation. The high volatilization temperature maintains ink composition stability during storage while still allowing easy application through controlled drying

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The ink composition achieves excellent migration properties and storage stability, with greater than 80% normal alignment and storage stability of over 7 hours, effectively addressing the dispersion and sedimentation issues of semiconductor nanorods.

Implementation Method 1

the method of mounting the ultra-small LED devices on the disposed electrodes still have difficulties of disposing and mounting the ultra-small LED devices on the electrodes as intended due to size limitations of the ultra-small LED devices

Methodology Applied
Scientific EffectDielectrophoresis: Electrophoresis

Implementation Method 2

a volatilization temperature of 200° C. to 400° C.

Methodology Applied
Scientific EffectVolatilization: Evaporation

Data Source

PatentUS20240166898A1Ink composition, layer and display device using same
Publication Date: 2024.05.23 SAMSUNG SDI CO LTD
  • US20240166898A1 patent drawing
  • US20240166898A1 patent drawing
  • US20240166898A1 patent drawing

AI summary

Disclosed are an ink composition, a layer manufactured using the ink composition, and a display device including the same. The ink composition includes (A) semiconductor nanorods; and (B) a mixed solvent that simultaneously satisfies three specific conditions.