Ink Composition with High-Tg Fixing Polymer for UV-Stable Prints

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Solution Overview

Problem

Existing inks lack effective methods for fixing pigments at high temperatures and UV protection, leading to issues with abrasion resistance and color stability.

Innovation Solution

Inks containing a fixing polymer with a glass-transition temperature higher than 80% of other polymers, along with an ultraviolet-absorbing agent, and a printing apparatus with a dryer and melting device for heat fixation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If a polymer is added to disperse pigment and improve abrasion resistance, then abrasion resistance is improved, but pigment fixation at high temperatures deteriorates

Engineering Contradiction:
Improveabrasion resistanceVSAvoidpigment fixation
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent divides the polymer function into two separate components: a fixing polymer (with high glass-transition temperature of 80°C or higher) responsible for pigment fixation, and other polymers (with lower glass-transition temperatures) responsible for dispersion and abrasion resistance. This segmentation allows each component to optimize its specific function without interfering with the other, resolving the contradiction between abrasion resistance and pigment fixation.

Inventive Principle:
Principle #1Segmentation

2Ease of operation

If existing ink composition is used, then basic printing function is achieved, but UV protection and color stability deteriorate

Engineering Contradiction:
Improveprinting functionVSAvoidUV damage
Core Design Contradiction:
Ease of operationVSObject-affected harmful factors

Solution Approach 1:

The patent incorporates an ultraviolet-absorbing agent into the ink composition before printing, which proactively absorbs UV radiation before it can damage the printed record. This preliminary protective action prevents color fading and degradation, addressing the UV protection issue while maintaining basic printing functionality.

Inventive Principle:
Principle #10Preliminary action

3Stability of the object's composition

If pigment dispersing polymer is added, then pigment dispersion is improved, but high-temperature fixation capability deteriorates

Engineering Contradiction:
Improvepigment dispersionVSAvoidfixation temperature
Core Design Contradiction:
Stability of the object's compositionVSTemperature

Solution Approach 1:

The patent segments the polymer roles by using a fixing polymer with high glass-transition temperature (80°C or higher) that maintains effectiveness at high temperatures for pigment fixation, while separate polymers handle dispersion functions. This segmentation ensures that dispersion improvement does not compromise high-temperature fixation capability.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enhances pigment fixation and UV protection, improving abrasion resistance and color stability in printed records.

Implementation Method 1

The melting device is configured to subject the ink on the object to heat that causes the fixing polymer to melt and to fix the ink to the object accordingly

Methodology Applied
Scientific EffectMelting: Melting

Implementation Method 2

The dryer is configured to heat the object to expedite evaporation of the medium

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 3

At least one of the inks contains an ultraviolet-absorbing agent different from the coloring agents

Methodology Applied
Scientific EffectAbsorption (EM radiation): Absorption (EM radiation)

Data Source

PatentUS12479213B2Ink, ink set and printer
Publication Date: 2025.11.25 KYOCERA CORP
  • US12479213B2 patent drawing
  • US12479213B2 patent drawing
  • US12479213B2 patent drawing

AI summary

An ink contains a medium, a coloring agent, a fixing polymer, and one or more kinds of polymers other than the fixing polymer. The coloring agent is dissolved or dispersed in the medium. The fixing polymer has a glass-transition temperature higher than the ordinary temperature and is dispersed in the medium. The one or more kinds of polymers each have a glass-transition temperature higher than the ordinary temperature and are dissolved or dispersed in the medium. The fixing polymer is higher in glass-transition temperature than 80 mass % or more of the one or more kinds of polymers contained in the ink and each having a glass-transition temperature higher than the ordinary temperature.