Ink Formulation for Coated Paper Fixability

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Solution Overview

Problem

Inkjet recording methods face challenges with pigment inks on coated papers due to poor water resistance and light resistance, leading to issues with image density, gloss level, and fixability, as the water-containing organic solvents in these inks permeate slowly and remain on the paper surface, causing driability and transfer problems.

Innovation Solution

An ink formulation containing a wax, specific organic solvents with solubility parameters between 9 and 11 and saturated vapor pressures between 20 mmHg and 400 mmHg at 100°C, which promotes solvent permeation and volatilization, enhancing image density, gloss level, and fixability on both plain and coated papers.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If pigment inks using water-insoluble pigment are used on coated paper, then water resistance and light resistance are improved, but the water-containing organic solvent permeates slowly and remains on the surface causing poor driability and fixability

Engineering Contradiction:
Improvewater resistance and light resistanceVSAvoiddriability and fixability
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The patent changes the parameters of the organic solvent system by selecting specific solvents with controlled volatility and solubility characteristics. The solvent composition is optimized to achieve appropriate permeation speed through coated paper while maintaining the water-resistant pigment properties, thereby resolving the contradiction between reliability and ease of operation.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses a composite ink formulation combining water-insoluble pigment particles with a carefully selected mixture of organic solvents and water-soluble components. This composite approach allows the ink to exhibit both the water resistance of pigments and the controlled permeation characteristics needed for good driability and fixability on coated paper.

Inventive Principle:
Principle #40Composite materials

2Ease of operation

If dye inks using water-soluble dye are used, then good driability and fixability are achieved, but water resistance and light resistance are poor

Engineering Contradiction:
Improvedriability and fixabilityVSAvoidwater resistance and light resistance
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The patent extracts the water-solubility characteristic from the colorant system by using water-insoluble pigments instead of water-soluble dyes. This extraction allows the ink to maintain good permeation and fixability properties while the pigment particles provide inherent water and light resistance, resolving the contradiction between ease of operation and reliability.

Inventive Principle:
Principle #2Taking out (Extraction)

3Manufacturing precision

If the water-containing organic solvent permeates slowly through coated paper, then image density and gloss level may be improved, but the solvent remains on the surface causing transfer and scratch issues

Engineering Contradiction:
Improveimage density and gloss levelVSAvoidtransfer and scratch
Core Design Contradiction:
Manufacturing precisionVSObject-affected harmful factors

Solution Approach 1:

The patent adjusts the volatility parameters of the organic solvent system to achieve optimal evaporation characteristics. The selected solvents have vapor pressures and boiling points that allow sufficient time for permeation and image formation, but then evaporate completely to leave no residual solvent that could cause transfer or scratch problems, thus resolving the contradiction between manufacturing precision and harmful factors.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The ink achieves high image density, gloss level, and fixability on coated papers by optimizing solvent properties, ensuring effective spreading and uniform wax distribution, thereby improving image quality and durability.

Implementation Method 1

a speed at which a water-containing organic solvent contained in the inks permeates the coated paper is slow

Methodology Applied
Scientific EffectPermeation: Permeation

Implementation Method 2

a compound having a saturated vapor pressure at 100° C. of 20 mmHg or greater but 400 mmHg or less

Methodology Applied
Scientific EffectEvaporation: Evaporation

Data Source

PatentUS10131805B2Ink, ink stored container, inkjet recording apparatus, and printed matter
Publication Date: 2018.11.20 RICOH CO LTD
  • US10131805B2 patent drawing
  • US10131805B2 patent drawing
  • US10131805B2 patent drawing

AI summary

Provided is an ink containing a wax, a plurality of organic solvents, and water, wherein the plurality of organic solvents include a compound having a solubility parameter of 9 or greater but 11 or less and a compound having a saturated vapor pressure at 100° C. of 20 mmHg or greater but 400 mmHg or less.