Ink Formulation for High-Speed Inkjet Printing

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Solution Overview

Problem

Inkjet recording technologies face challenges in achieving high optical density and fixability while preventing feathering and strike-through, especially at high conveying speeds, as existing inks either suffer from low fixability or inadequate optical density due to limitations in permeation time and viscosity.

Innovation Solution

An ink formulation with a viscosity of 5 mPa·s or more, static surface tension between 27.1 mN/m and 35.0 mN/m, and dynamic surface tension between 30.5 mN/m and 37.0 mN/m, incorporating a pigment, water-soluble organic solvent, and surfactant, which controls permeation time and surface tension to balance optical density and fixability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Duration of action of stationary object

If superpermeable ink is used to improve fixability, then permeation speed increases, but optical density decreases

Engineering Contradiction:
ImprovefixabilityVSAvoidoptical density
Core Design Contradiction:
Duration of action of stationary objectVSIllumination intensity

Solution Approach 1:

The patent applies parameter changes by precisely controlling the viscosity of the ink within 3-15 mPa·s and the surface tension within 25-35 mN/m. These parameter adjustments optimize the balance between permeation speed (for fixability) and pigment retention (for optical density), resolving the contradiction between fast drying and high color density.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite materials by formulating ink with specific combinations of solvents (glycol ethers, diols, carboxylic acid esters) and surfactants. This composite approach creates an ink system that achieves both rapid permeation for fixability and sufficient pigment concentration for optical density, combining the benefits of different material properties.

Inventive Principle:
Principle #40Composite materials

2Illumination intensity

If overlay ink is used to improve optical density, then permeation time increases, but fixability worsens

Engineering Contradiction:
Improveoptical densityVSAvoidfixability
Core Design Contradiction:
Illumination intensityVSDuration of action of stationary object

Solution Approach 1:

The patent reverses the overlay ink approach by using parameter changes to reduce viscosity to 3-15 mPa·s and adjust surface tension to 25-35 mN/m. These changes accelerate permeation time to seconds or less while maintaining high optical density through optimized pigment-solvent-surfactant interactions, thus improving both optical density and fixability simultaneously.

Inventive Principle:
Principle #35Parameter changes

3Speed

If ink viscosity is reduced to improve ejection stability, then permeation speed increases, but feathering increases

Engineering Contradiction:
Improvepermeation speedVSAvoidfeathering
Core Design Contradiction:
SpeedVSObject-generated harmful factors

Solution Approach 1:

The patent applies parameter changes by setting viscosity within 3-15 mPa·s and surface tension within 25-35 mN/m, creating an optimal balance where the ink permeates quickly enough for high-speed printing but maintains sufficient cohesion to prevent feathering. This resolves the contradiction between permeation speed and feathering suppression.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite materials by combining specific solvent types (glycol ethers, diols, carboxylic acid esters) with surfactants in controlled amounts. This composite formulation ensures rapid permeation while the surfactant system maintains ink cohesion, preventing feathering even at low viscosities required for high-speed ejection.

Inventive Principle:
Principle #40Composite materials

4Productivity

If conveying speed is increased to improve productivity, then printing speed increases, but image quality deteriorates due to insufficient permeation time

Engineering Contradiction:
Improveprinting speedVSAvoidimage quality
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent applies parameter changes by reducing ink viscosity to 3-15 mPa·s and adjusting surface tension to 25-35 mN/m, which dramatically increases permeation speed. This allows the ink to fully permeate and fix to the paper within the reduced contact time at high conveying speeds, maintaining image quality (optical density and color fastness) while achieving high productivity.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The ink achieves high optical density and fixability with reduced feathering and strike-through, suitable for high-speed recording, maintaining ejection stability and preventing contamination of conveying rollers.

Implementation Method 1

a static surface tension of 27.1 mN/m or more and 35.0 mN/m or less, which is measured at 25°C by a Wilhelmy method, and a dynamic surface tension of 30.5 mN/m or more and 37.0 mN/m or less, which is measured at 25°C by a maximum bubble pressure method

Methodology Applied
Scientific EffectSurface tension: Surface Tension

Implementation Method 2

an ink droplet applied to the surface of the recording medium (plain paper) permeates a gap between cellulose fibers constituting the plain paper

Methodology Applied
Scientific EffectPermeation: Permeation

Implementation Method 3

the ink has a viscosity of 5 mPa·s or more at 25°C

Methodology Applied
Scientific EffectViscosity:

Data Source

PatentEP3196262B2Ink, ink cartridge, and image recording method
Publication Date: 2023.06.07 CANON KK
  • EP3196262B2 patent drawingFigure 1~2
  • EP3196262B2 patent drawing
  • EP3196262B2 patent drawing

AI summary

Provided is an ink containing a pigment, a water-soluble organic solvent, and a surfactant represented by the following general formula (1), and having a viscosity at 25°C of 5 mPa·s or more. The ink has a static surface tension of 27.1 mN/m or more and 35.0 mN/m or less, which is measured at 25°C by a Wilhelmy method. The ink also has a dynamic surface tension at a bubble life time of 150 msec of 30.5 mN/m or more and 37.0 mN/m or less, which is measured at 25°C by a maximum bubble pressure method.