Ink Formulation Gloss Control via Surface Tension Modifiers

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Solution Overview

Problem

Existing methods for controlling gloss in inkjet recording methods face challenges in cost efficiency and productivity, and can result in degraded coating film uniformity.

Innovation Solution

An active-energy-ray-curable ink is developed, containing a surface tension modifier and a monomer with a surface tension of 39 mN/m or greater, used in an amount of 20% to 60% by mass, to control low glossiness without compromising coating film uniformity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If heating recording medium and adjusting wettability/spreadability is used to control gloss, then gloss control is achieved, but cost efficiency deteriorates

Engineering Contradiction:
Improvegloss controlVSAvoidcost efficiency
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The invention changes the chemical composition parameters of the ink by incorporating specific surfactants and polymers with controlled surface tension properties. This allows gloss control to be achieved through ink formulation rather than post-processing heating, eliminating the need for expensive heating equipment while maintaining precise gloss control.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention replaces the thermal heating process with a chemical composition-based solution. Instead of using heat to control gloss, the patent uses specifically formulated surfactants and polymers that provide gloss control through their surface tension properties, substituting a mechanical/thermal system with a chemical system.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Manufacturing precision

If clear ink with surfactant is used for matte coating, then gloss control is achieved, but coating film uniformity deteriorates

Engineering Contradiction:
Improvegloss controlVSAvoidcoating film uniformity
Core Design Contradiction:
Manufacturing precisionVSStability of the object's composition

Solution Approach 1:

The invention applies local quality by using different types of surfactants and polymers in specific concentrations at different locations within the ink formulation. The surfactant and polymer are selected to provide localized surface tension modification that controls gloss while maintaining overall coating uniformity, rather than using a single uniform additive throughout.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The invention uses a composite material system combining multiple surfactants and polymers with complementary properties. This composite formulation provides both gloss control and coating uniformity by leveraging the synergistic effects of different materials working together, rather than relying on a single additive that might compromise uniformity.

Inventive Principle:
Principle #40Composite materials

3Loss of substance

If inkjet recording method is used to form images, then ink consumption efficiency is improved, but gloss control capability deteriorates

Engineering Contradiction:
Improveink consumption efficiencyVSAvoidgloss control
Core Design Contradiction:
Loss of substanceVSManufacturing precision

Solution Approach 1:

The invention modifies the physical and chemical parameters of the ink formulation by incorporating surfactants and polymers with specific surface tension properties. This allows the inkjet recording method to maintain its efficiency while gaining gloss control capability through the modified ink composition, as the surface tension modifiers enable controlled wetting and spreading during the inkjet deposition process.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The ink effectively controls low glossiness while maintaining coating film uniformity, addressing the limitations of previous methods in terms of cost and productivity.

Implementation Method 1

including a monomer having a surface tension of 39 mN/m or greater in an amount of 20% by mass or greater but 60% by mass or less

Methodology Applied
Scientific EffectSurface tension: Surface Tension

Implementation Method 2

including at least a surface tension modifier

Methodology Applied
Scientific EffectSurface tension modification: Surfactant

Data Source

PatentUS12281231B2Ink, ink set, ink container, recording method, and recording apparatus
Publication Date: 2025.04.22 RICOH CO LTD
  • US12281231B2 patent drawing

AI summary

Provided is an active-energy-ray-curable ink including at least a surface tension modifier and including a monomer having a surface tension of 39 mN/m or greater in an amount of 20% by mass or greater but 60% by mass or less. Preferably, the ink includes a monomer having a surface tension of 43 mN/m or greater in an amount of 5% by mass or greater but 10% by mass or less.