Ink Composition J-Aggregate Infrared Absorption

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Solution Overview

Problem

Inkjet printing technologies face challenges in achieving infrared absorbing images with excellent rub resistance, light fastness, and jetability, as existing solutions like oxonol colorants have limitations in stability and absorption capacity.

Innovation Solution

An ink composition for inkjet printing is developed, comprising a specific oxonol colorant, resin particles, and a water-soluble organic solvent, which forms a J-aggregate to enhance stability and light fastness, and includes self-dispersing resin particles to improve dot shape and ink stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If oxonol colorants are used to form infrared absorbing images, then infrared absorption capacity is improved, but rub resistance and light fastness deteriorate

Engineering Contradiction:
Improveinfrared absorption capacityVSAvoidrub resistance and light fastness
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The patent uses a composite ink composition containing oxonol colorant (for infrared absorption), resin particles (for stability and rub resistance), and water-soluble organic solvent (for jetability). This composite approach allows the ink to simultaneously achieve high infrared absorption capacity while maintaining excellent rub resistance and light fastness through the synergistic effects of its components.

Inventive Principle:
Principle #40Composite materials

2Quantity of substance

If ink composition is optimized for infrared absorption, then absorption capacity is improved, but jetability deteriorates

Engineering Contradiction:
Improveinfrared absorption capacityVSAvoidjetability
Core Design Contradiction:
Quantity of substanceVSEase of operation

Solution Approach 1:

The patent carefully controls the concentration parameters of each component: oxonol colorant (0.1-10 mass%), resin particles (1-20 mass%), and water-soluble organic solvent (5-50 mass%). By optimizing these parameter ranges, the ink achieves both high infrared absorption capacity and excellent jetability, as the solvent content ensures proper flow characteristics while the colorant concentration provides sufficient absorption.

Inventive Principle:
Principle #35Parameter changes

3Stability of the object's composition

If resin particles are added to improve stability, then ink stability is improved, but dot shape quality deteriorates

Engineering Contradiction:
Improveink stabilityVSAvoiddot shape quality
Core Design Contradiction:
Stability of the object's compositionVSManufacturing precision

Solution Approach 1:

The patent specifies that resin particles should have a particle size of 0.1-10 μm, creating local quality differentiation where the particle size is optimized to be small enough not to interfere with dot shape formation, yet large enough to provide stability. This local optimization allows the resin to enhance ink stability while maintaining excellent dot shape quality.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The ink composition achieves improved rub resistance, light fastness, and ink stability, ensuring high-quality infrared absorbing images with enhanced absorption capacity and jetability.

Implementation Method 1

By using a specific oxonol colorant and, the ink composition achieves improved rub resistance, light fastness, and ink stability, ensuring high-quality infrared absorbing images with enhanced absorption capacity and jetability.

Methodology Applied
Scientific EffectJ-aggregate formation:

Implementation Method 2

an ink composition for ink jet printing with which an infrared absorbing image having excellent rub resistance, light fastness, and infrared absorption capacity can be obtained

Methodology Applied
Scientific EffectInfrared absorption: Absorption (EM radiation)

Data Source

PatentEP3757179B1Ink composition for ink jet printing, image forming method, and recorded material
Publication Date: 2024.03.13 FUJIFILM CORP
  • EP3757179B1 patent drawingFigure 1
  • EP3757179B1 patent drawing
  • EP3757179B1 patent drawing

AI summary

Provided are an ink composition for ink jet printing, and an image forming method and a recorded material using the ink composition for ink jet printing. The ink composition for ink jet printing includes: a colorant represented by the following Formula 1; resin particles; a water-soluble organic solvent; and water. In Formula 1, Y1 and Y2 each independently represent a non-metal atomic group which forms an aliphatic ring or a heterocycle, M+ represents a proton or a monovalent alkali metal cation or organic cation, L1 represents a methine chain consisting of 5 or 7 methine groups, and a methine group at a center of the methine chain has a specific substituent.