Ink Jet Ink Composition with Cyclic Amide for Textile Hue Stability

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Solution Overview

Problem

Ink jet textile printing faces challenges in maintaining color stability and light fastness, particularly for hues in the range of 260 to 310 degrees, as existing ink compositions experience temporal hue changes due to differences in light fastness between dyes and are prone to clogging and low ejection reliability.

Innovation Solution

An ink jet ink composition containing a dye with copper or chromium, such as C.I. Reactive Blue 13 or C.I. Acid Blue 193, combined with 5% to 30% cyclic amide with a normal boiling point between 190°C to 260°C, which enhances dye solubility and stability, and an alkyl polyol for moisture retention, reducing temporal hue changes and improving ejection reliability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional ink compositions are used for textile printing, then color reproduction is achieved, but temporal hue changes occur due to differences in light fastness between dyes

Engineering Contradiction:
Improvecolor reproduction accuracyVSAvoidtemporal hue stability
Core Design Contradiction:
Manufacturing precisionVSStability of the object's composition

Solution Approach 1:

The patent changes the chemical composition parameters of the ink by incorporating specific cyclic amides with controlled boiling points (190-260°C) and using dyes containing copper or chromium. These parameter changes stabilize the hue of blue colors (260-310 degrees) while maintaining color reproduction accuracy, resolving the contradiction between initial color quality and long-term hue stability.

Inventive Principle:
Principle #35Parameter changes

2Stability of the object's composition

If ink compositions are optimized for color stability, then light fastness improves, but ejection reliability deteriorates due to clogging and poor continuous ejection stability

Engineering Contradiction:
Improvelight fastnessVSAvoidejection reliability
Core Design Contradiction:
Stability of the object's compositionVSReliability

Solution Approach 1:

The patent optimizes physical parameters of the ink composition by selecting cyclic amides with specific boiling points (190-260°C) and controlling viscosity within the range of 1.5-10 mPa·s at 25°C. These parameter changes ensure the ink maintains stability for light fastness while preserving adequate流动性 for reliable ejection and preventing nozzle clogging.

Inventive Principle:
Principle #35Parameter changes

3Manufacturing precision

If dyes with high color developability are used, then color intensity improves, but hue changes occur during long-term outdoor exposure

Engineering Contradiction:
Improvecolor developabilityVSAvoidhue stability during exposure
Core Design Contradiction:
Manufacturing precisionVSStability of the object's composition

Solution Approach 1:

The patent creates a composite ink system combining dyes containing copper or chromium with specific cyclic amides. This composite formulation achieves high color developability through the dye components while the cyclic amide matrix stabilizes the hue during long-term outdoor exposure, particularly for blue colors in the 260-310 degree range, preventing the hue changes that occur with conventional high-intensity dyes.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The ink composition achieves high color developability and light fastness for hues in the range of 260 to 310 degrees without color mixing, while maintaining continuous ejection stability and reducing the formation of foreign matter, outperforming traditional methods in color reproduction and durability.

Implementation Method 1

5% to 30% by mass of a cyclic amide that is liquid at a normal temperature of 25 °C and has a normal boiling point at 1 atm in the range of 190°C to 260°C

Methodology Applied
Scientific EffectSolvation: Solvation

Implementation Method 2

an alkyl polyol for moisture retention

Methodology Applied
Scientific EffectHygroscopy: Absorption (physical)

Data Source

PatentEP3342927B1Ink jet ink composition for textile printing, ink set, and recording method
Publication Date: 2019.08.14 SEIKO EPSON CORP
  • EP3342927B1 patent drawingFigure 1~2
  • EP3342927B1 patent drawing
  • EP3342927B1 patent drawing

AI summary

An ink jet ink composition for textile printing including a dye containing copper or chromium and 5% to 30% by mass of a cyclic amide that is liquid at normal temperature and that has a normal boiling point in the range of 190°C to 260°C, wherein the hue angle ∠h° defined by the CIELAB color space on a recording medium ranges from 260 to 310 degrees.