Ink Jet Ink Composition with Polyether Siloxane for Storage Stability

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Solution Overview

Problem

Ink jet ink compositions for sublimation transfer textile printing face challenges with poor storage stability and image blur due to the decomposition of siloxane surfactants, which affects the surface activity and dispersibility of sublimation dyes.

Innovation Solution

The use of polyether siloxane with a weight average molecular weight of 1000 or more and 5 or more siloxane repeating units, combined with a resin dispersant, maintains high surface activity and stability, even upon decomposition, ensuring low surface tension and improved dispersibility of sublimation dyes, thereby reducing image blur and enhancing storage stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a siloxane surfactant is added to improve surface activity and dispersibility of sublimation dye, then the ink composition shows good initial performance, but the siloxane surfactant decomposes over time leading to poor storage stability and image blur

Engineering Contradiction:
Improvesurface activityVSAvoidstorage stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent changes the molecular weight parameter of the siloxane surfactant to 1000 or more and specifies having 5 or more siloxane repeating units. This parameter change makes the siloxane surfactant more resistant to decomposition while maintaining surface activity, thereby resolving the contradiction between initial performance and storage stability.

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If a dispersant is used to improve dispersibility of sublimation dye, then dispersion quality improves, but image blur increases due to interaction with siloxane surfactant

Engineering Contradiction:
ImprovedispersibilityVSAvoidimage blur
Core Design Contradiction:
Manufacturing precisionVSObject-generated harmful factors

Solution Approach 1:

The patent uses a composite approach by combining a resin dispersant with a high molecular weight siloxane surfactant (molecular weight 1000 or more). The resin dispersant provides effective dispersibility while the stable siloxane surfactant maintains appropriate surface tension without excessive decomposition, thereby achieving good dispersibility while minimizing image blur.

Inventive Principle:
Principle #40Composite materials

3Duration of action of stationary object

If the ink composition is stored for long term to ensure availability, then storage duration increases, but surface tension increases and storage stability decreases due to decomposition

Engineering Contradiction:
Improvestorage durationVSAvoidsurface tension stability
Core Design Contradiction:
Duration of action of stationary objectVSReliability

Solution Approach 1:

The patent specifies that the siloxane surfactant should have a molecular weight of 1000 or more and contain 5 or more siloxane repeating units. This parameter change significantly reduces the decomposition rate of the siloxane surfactant, allowing the ink composition to maintain stable surface tension even after long-term storage, thereby enabling extended storage duration while preserving reliability.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The ink jet ink composition achieves high storage stability and produces high-quality images with reduced blur, even after long-term storage, by maintaining low surface tension and effective dispersibility of sublimation dyes, ensuring reliable ejection and high-quality printing.

Implementation Method 1

the siloxane surfactant is considered to be good at lowering surface tension

Methodology Applied
Scientific EffectSurfactant: Surfactant

Implementation Method 2

the sublimation dye is sublimated by vapor or heat, for example, to dye the print target medium (fabric, for example)

Methodology Applied
Scientific EffectSublimation: Sublimation

Data Source

PatentEP3375829B1Ink jet ink composition and recording method
Publication Date: 2021.06.30 SEIKO EPSON CORP
  • EP3375829B1 patent drawingFigure 1
  • EP3375829B1 patent drawing

AI summary

An ink jet ink composition includes a sublimation dye, a dispersant for the sublimation dye, and polyether siloxane having a weight average molecular weight of 1000 or more and having 5 or more siloxane repeating units.