Ink Jet Composition With Sulfo Group Surface Concentration

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Solution Overview

Problem

Ink jet printing faces challenges in achieving both ejection stability and color development property, as water-based inks struggle to provide sufficient coating film strength, and ink jet inks containing polyester resin with high sulfo groups compromise color development when aiming for improved ejection stability.

Innovation Solution

An ink jet composition comprising water, a polyester resin with sulfo groups, and a colorant, where the sulfo groups are concentrated at the surface of particles, enhancing hydrophilicity and dispersion stability, and the colorant is localized within the particles to prevent poor dispersion, thereby maintaining ejection stability and improving color development.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If an ink jet ink containing polyester resin with high sulfo groups is used to improve ejection stability, then ejection stability is improved, but color development property is degraded

Engineering Contradiction:
Improveejection stabilityVSAvoidcolor development property
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent applies local quality by creating particles with non-uniform sulfo group distribution, where the surface has a higher abundance ratio of sulfo groups compared to the center. This localized concentration of hydrophilic groups at the particle surface improves ejection stability while the interior structure maintains color development property, thus resolving the contradiction between these two requirements.

Inventive Principle:
Principle #3Local quality

2Ease of operation

If a water-based ink is used to improve handleability and safety, then handleability and safety are improved, but coating film strength is insufficient

Engineering Contradiction:
Improvehandleability and safetyVSAvoidcoating film strength
Core Design Contradiction:
Ease of operationVSStrength

Solution Approach 1:

The patent uses composite materials by combining water-based ink with polyester resin particles that have specific structural characteristics. The particles contain colorant and polyester resin with sulfo groups distributed in a specific pattern (higher concentration at surface), creating a composite structure that provides both the safety of water-based formulation and the film strength of resin-containing ink.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution achieves excellent ejection stability and color development on various recording media, with enhanced fixing properties, adhesion strength, and water resistance, while reducing production costs and energy consumption.

Implementation Method 1

the sulfo groups have a high abundance ratio at a surface of each of the particles as compared to that at a center thereof

Methodology Applied
Scientific EffectHydrophilicity: Hydrophile

Implementation Method 2

enhancing hydrophilicity and dispersion stability

Methodology Applied
Scientific EffectDispersion: Dispersion (of waves)

Implementation Method 3

a heating step of heating a recording medium to which the ink jet composition is adhered

Methodology Applied
Scientific EffectHeating: Heating

Implementation Method 4

enhanced fixing properties, adhesion strength, and water resistance

Methodology Applied
Scientific EffectAdhesion: Adhesive

Data Source

PatentUS12091565B2Ink jet composition and ink jet recording method
Publication Date: 2024.09.17 SEIKO EPSON CORP
  • US12091565B2 patent drawing

AI summary

An ink jet composition of the present disclosure includes: water; a polyester resin having sulfo groups; and a colorant, the colorant is contained in particles formed from a material containing the polyester resin, and the sulfo groups have a high abundance ratio at a surface of each of the particles as compared to that at a center thereof.