Ink Formulation Using Photoacid Generator for Non-Permeable Media

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Solution Overview

Problem

Inkjet recording methods face issues such as image blurring due to ink blurring and unequalized image density, especially when printing on non-permeable media or coated papers, which affects the quality and fixability of printed images.

Innovation Solution

An ink formulation containing an anionic compound, water, a photoacid generator, and specific organic solvents with a solubility parameter of 9 to 11.8 (J/cm3)1/2, where the photoacid generator decomposes upon UV radiation to produce an acid that aggregates the anionic compound, preventing beading and color bleeding.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional ink formulations are used for inkjet printing, then printing can be performed on various media, but image blurring and color bleeding occur especially on non-permeable media and coated papers

Engineering Contradiction:
Improveimage fixabilityVSAvoidimage blurring and color bleeding
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent modifies the chemical composition parameters of the ink by incorporating specific anionic compounds (such as anionic surfactants and anionic polymers) in controlled concentrations (0.1-10% and 1-20% respectively), along with cationic compounds, to change the interfacial properties and electrostatic interactions between ink and substrate, thereby preventing color bleeding and improving image fixability on challenging media

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs a composite ink formulation combining multiple functional components: anionic compounds (surfactants and polymers), cationic compounds, and specific organic solvents. This composite approach creates synergistic effects where the anionic-cationic interactions enhance ink cohesion and adhesion, preventing both color bleeding and image blurring simultaneously

Inventive Principle:
Principle #40Composite materials

2Manufacturing precision

If ink formulations are optimized for image quality, then color bleeding is reduced, but unequalized image density and poor fixability on non-permeable media persist

Engineering Contradiction:
Improveimage density uniformityVSAvoidimage fixability on non-permeable media
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent adjusts multiple ink composition parameters simultaneously: anionic compound concentration (0.1-10%), cationic compound concentration (0.01-5%), and organic solvent selection, to optimize the balance between ink cohesion (preventing color bleeding) and substrate interaction (ensuring fixability on non-permeable media and uniform density across the printed image)

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The anionic and cationic compounds act as intermediaries that mediate the interaction between ink and substrate. The electrostatic attraction between oppositely charged compounds creates a stable ink film that adheres well to non-permeable media while maintaining uniform distribution, thus simultaneously improving fixability and density uniformity

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The ink effectively prevents beading and color bleeding on printed images, enhancing image quality and fixability on various media types, including non-permeable surfaces and coated papers.

Implementation Method 1

the photoacid generator decomposes upon UV radiation to produce an acid that aggregates the anionic compound

Methodology Applied
Scientific EffectPhotodecomposition: Photodissociation

Data Source

PatentUS11649365B2Ink, ink set, ink container, method of printing, and printing device
Publication Date: 2023.05.16 RICOH CO LTD
  • US11649365B2 patent drawing
  • US11649365B2 patent drawing
  • US11649365B2 patent drawing

AI summary

An ink contains an anionic compound, water, a photoacid generator, and one or more organic solvents containing at least one organic solvent having a solubility parameter of from 9 to 11.8 (J/cm3)1/2.