Ink Formulation with Polyhydroxy Compounds for Nozzle Clogging Prevention

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Solution Overview

Problem

Conventional inks for inkjet recording face challenges with nozzle clogging and dispersion instability due to high concentrations of non-self-dispersible pigments and compounds with multiple hydroxyl groups, which affect image density and medium curling.

Innovation Solution

The ink formulation includes a pigment, a dispersant, a penetrating agent, water, a compound with two hydroxyl groups, a compound with three hydroxyl groups, and a compound with four or more hydroxyl groups, optimized in specific weight percentages to maintain image density while preventing nozzle clogging and medium curling.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If the concentration of non-self-dispersible pigment is increased to improve image density, then image density is improved, but nozzle clogging occurs

Engineering Contradiction:
Improveimage densityVSAvoidnozzle clogging
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

A compound having four or more hydroxyl groups (e.g., glucose, fructose, galactose, mannose, sorbitol, xylitol, erythritol, or their derivatives) is introduced as an intermediary substance to mediate between the pigment particles and the ink solvent. This compound prevents pigment aggregation and nozzle clogging while maintaining high pigment concentration (7-20% by weight) for achieving high image density, resolving the contradiction between image quality and system reliability.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent changes the chemical parameter of the ink formulation by incorporating specific compounds with four or more hydroxyl groups in controlled amounts (25-50% by weight). This parameter change modifies the ink's interaction with pigment particles, enabling stable dispersion of high concentrations of non-self-dispersible pigment without causing nozzle clogging, thus simultaneously achieving high image density and reliable operation.

Inventive Principle:
Principle #35Parameter changes

2Stability of the object's composition

If the concentration of compound with four or more hydroxyl groups is increased to prevent medium curling, then medium curling is reduced, but ink formulation complexity increases

Engineering Contradiction:
Improvemedium curlingVSAvoidink formulation complexity
Core Design Contradiction:
Stability of the object's compositionVSDevice complexity

Solution Approach 1:

The patent optimizes the concentration parameter of compounds with four or more hydroxyl groups to be within 25-50% by weight of the total ink. This parameter optimization effectively prevents medium curling while maintaining formulation simplicity and cost-effectiveness, avoiding excessive complexity in the ink formulation.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite ink formulation that combines non-self-dispersible pigment, dispersant, penetrating agent, water, and compounds with two, three, and four or more hydroxyl groups in specific proportions. This composite approach achieves multiple functions (high image density, nozzle clogging prevention, medium curling control) through a coordinated system rather than complex individual components.

Inventive Principle:
Principle #40Composite materials

3Manufacturing precision

If the pigment concentration is increased to improve image density, then image density is improved, but dispersion stability deteriorates

Engineering Contradiction:
Improveimage densityVSAvoiddispersion stability
Core Design Contradiction:
Manufacturing precisionVSStability of the object's composition

Solution Approach 1:

The compound with four or more hydroxyl groups acts as a mediator that enhances pigment dispersion stability even at high concentrations (7-20% by weight). This intermediary substance prevents pigment aggregation and maintains uniform distribution throughout the ink, enabling both high image density and stable dispersion.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent develops a composite ink system combining multiple components (pigment, dispersant, penetrating agent, water, and compounds with 2, 3, and 4+ hydroxyl groups) in optimized ratios. This composite formulation achieves synergistic effects where the combination of components provides superior dispersion stability at high pigment concentrations compared to individual substances alone.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This formulation allows for higher image density with reduced nozzle clogging and medium curling, ensuring stable ink dispersion and improved printing performance even after long-term suspension of the ink ejecting apparatus.

Implementation Method 1

the ink contains a compound having four or more hydroxyl groups in the molecule... curling of a recording medium due to evaporation of moisture after image formation can be prevented

Methodology Applied
Scientific EffectHydrogen bonding:

Implementation Method 2

combined with a dispersant to disperse the pigment in an ink... difficult to maintain a dispersed state thereof by themselves

Methodology Applied
Scientific EffectDispersion: Dispersion (of waves)

Data Source

PatentUS8003714B2Ink, ink set, ink cartridge and ink ejecting apparatus
Publication Date: 2011.08.23 FUJIFILM BUSINESS INNOVATION CORP
  • US8003714B2 patent drawing
  • US8003714B2 patent drawing
  • US8003714B2 patent drawing

AI summary

An ink comprising a pigment, a dispersant, a penetrating agent, water, a compound having two hydroxyl groups in the molecule, a compound having three hydroxyl groups in the molecule, and a compound having four or more hydroxyl groups in the molecule,the content of the pigment being in the range of from about 7% by weight to about 20% by weight;the content of the compound having two hydroxyl groups in the molecule being in the range of from about 1% by weight to about 10% by weight;the content of the compound having three hydroxyl groups in the molecule being in the range of from about 2% by weight to about 20% by weight; andthe content of the compound having four or more hydroxyl groups in the molecule being in the range of from about 25% by weight to about 50% by weight.