Ink Composition Preventing Premature Cross-Linking

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Solution Overview

Problem

Aqueous inkjet inks with added polymer fine particles for improved image strength and rub-off resistance face issues with nozzle clogging due to cross-linking reactions, leading to hardening and poor re-dispersion, which affects printing stability and maintenance.

Innovation Solution

An inkjet ink composition containing polymer particles with reactive functional groups, a reactive compound that reacts with these groups upon energy application, a coloring agent, and a water-soluble organic solvent, which allows for controlled cross-linking and improved rub-off resistance without premature nozzle clogging.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If cross-linking reaction is promoted to improve image strength and rub-off resistance, then image quality improves, but nozzle clogging occurs due to premature hardening

Engineering Contradiction:
Improveimage strengthVSAvoidprinting stability
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent applies preliminary action by incorporating reactive functional groups into polymer particles that remain dormant during ink storage and application. The cross-linking reaction is triggered only after ink ejection onto the substrate through exposure to specific conditions (heat, light, or chemical environment), ensuring image strength enhancement occurs at the desired location and time without causing nozzle clogging during the printing process.

Inventive Principle:
Principle #10Preliminary action

2Strength

If cross-linking reaction occurs to improve rub-off resistance, then image durability improves, but re-dispersion becomes difficult leading to nozzle clogging

Engineering Contradiction:
Improverub-off resistanceVSAvoidre-dispersion ease
Core Design Contradiction:
StrengthVSEase of operation

Solution Approach 1:

The patent applies local quality by creating spatial differentiation in the cross-linking state: the ink formulation contains reactive polymer particles that remain un-crosslinked and dispersible in the liquid ink state for easy re-dispersion and nozzle flow, while undergoing cross-linking only after deposition on the substrate to provide rub-off resistance. This localized transformation ensures both ease of operation during printing and image durability after formation.

Inventive Principle:
Principle #3Local quality

3Strength

If reactive compound is added to enable cross-linking for image strength, then image quality improves, but cross-linking occurs during storage causing hardening

Engineering Contradiction:
Improveimage strengthVSAvoidstorage stability
Core Design Contradiction:
StrengthVSStability of the object's composition

Solution Approach 1:

The patent incorporates reactive functional groups into polymer particles during manufacturing as a preliminary preparation, but designs the system so that the actual cross-linking reaction does not occur during storage. The reactive groups remain dormant until triggered by post-deposition conditions (heat, light, or chemical environment on the substrate), thereby maintaining storage stability while enabling image strength enhancement when needed.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The ink composition ensures easy re-dispersion and maintenance by preventing premature cross-linking, enhancing image strength and resistance while maintaining printing stability and efficiency.

Implementation Method 1

a reactive compound having a functional group that reacts with the reactive functional group of the (a) particles of the polymer compound by energy application

Methodology Applied
Scientific EffectCross-linking reaction: Chemical Bonding

Implementation Method 2

applying energy to the ink composition that has been applied onto the recording medium

Methodology Applied
Scientific EffectEnergy application:

Data Source

PatentEP2626390B1Ink composition and image forming method
Publication Date: 2019.12.18 FUJIFILM CORP
  • EP2626390B1 patent drawing

AI summary

An inkjet ink composition includes: (a) particles of a polymer compound having at least one reactive functional group selected from the group consisting of an epoxy group, an acetoacetoxy group, a halomethyl group, a carboxylic acid anhydride, an amino group, a hydroxyl group, a phenolic hydroxyl group, and a carboxy group;(b) a reactive compound having a functional group that reacts with the reactive functional group of the (a) particles of the polymer compound by energy application; (c) a coloring agent; and (d) a water-soluble organic solvent.