Ink Composition for PVC Substrates via Vinyl-Penetrating Solvent

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Solution Overview

Problem

Aqueous-based inkjet inks face challenges when printing on non-porous substrates like polyvinyl chloride, including long dry time and poor durability, smudgefastness, colorfastness, waterfastness, abrasion resistance, and weather resistance, as they do not absorb well on non-absorbing surfaces.

Innovation Solution

An organic solvent-based inkjet ink composition is developed, using a vinyl-penetrating solvent, colorant, and non-aqueous carrier solvent, without polymerizable resins or binders, which penetrates the substrate to reduce dry time and enhance durability, incorporating a surface active agent like polyester-modified silicone for improved performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of time

If aqueous-based inkjet ink is used on non-porous substrate, then the ink can be printed, but the dry time is long and durability is poor

Engineering Contradiction:
Improvedry timeVSAvoiddurability
Core Design Contradiction:
Loss of timeVSReliability

Solution Approach 1:

The patent changes the chemical composition parameters of the ink by using a non-aqueous carrier solvent system (comprising carbonyl compounds, esters, and/or ketones) instead of traditional aqueous-based solvents. This parameter change enables the ink to penetrate non-porous substrates effectively, reducing dry time from hours to minutes while simultaneously improving durability through better adhesion and resistance to smudging, rubbing, and weathering.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs a composite solvent system combining multiple components: carbonyl compounds (e.g., methyl ethyl ketone), esters (e.g., ethyl acetate), and optionally ketones (e.g., cyclohexanone). This composite material approach creates synergistic effects where each component contributes to different aspects of performance - penetration, drying speed, and durability - resolving the contradiction between fast drying and long-lasting adhesion on non-porous surfaces.

Inventive Principle:
Principle #40Composite materials

2Productivity

If aqueous-based ink is used on non-absorbent surface, then printing is possible, but absorption is insufficient leading to poor drying

Engineering Contradiction:
Improvedrying efficiencyVSAvoidink absorption
Core Design Contradiction:
ProductivityVSQuantity of substance

Solution Approach 1:

The patent fundamentally changes the solvent parameters from aqueous to non-aqueous composition, specifically using carbonyl compounds, esters, and ketones. These chemical parameter changes give the ink properties that enable it to interact with non-absorbent surfaces through penetration and evaporation rather than absorption, dramatically improving drying efficiency while maintaining adequate substance transfer to the substrate.

Inventive Principle:
Principle #35Parameter changes

3Loss of time

If solvent-based or UV-curable inks are used to overcome drying issues, then drying time is reduced, but achieving desired durability remains challenging

Engineering Contradiction:
Improvedrying timeVSAvoiddurability
Core Design Contradiction:
Loss of timeVSReliability

Solution Approach 1:

The patent uses a carefully formulated composite solvent system combining carbonyl compounds (for penetration and medium drying), esters (for volatility control and finish quality), and optionally ketones (for enhanced substrate interaction). This composite approach achieves both rapid drying and superior durability without requiring UV curing or harsh solvents, outperforming conventional solvent-based or UV-curable inks in terms of both speed and long-term reliability.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The ink composition significantly reduces dry time and increases durability, including smearfastness, rub resistance, and solvent resistance, maintaining performance even with up to 10% water content, while avoiding interference from polymerizable resins.

Implementation Method 1

The dry time and durability improvements are specifically manifested as at least one of: decreased dry time, increased smearfastness, increased rub resistance, increased smudgefastness, increased solvent resistance, increased colorfastness, decreased drying time, etc. This decreased dry time and increased durability can be achieved by the penetration of vinyl-penetrating solvent in the ink into the substrate material.

Methodology Applied
Scientific EffectPenetration: Permeation

Implementation Method 2

The ink may also include surface active agent such as polyester-modified silicone or polyether-modified silicone.

Methodology Applied
Scientific EffectSurface activity: Surfactant

Implementation Method 3

An organic solvent-based inkjet ink composition is developed, using a vinyl-penetrating solvent, colorant, and non-aqueous carrier solvent

Methodology Applied
Scientific EffectEvaporation: Evaporation

Data Source

PatentUS8562730B2Ink composition for inkjet printing on substrate material comprising polyvinyl chloride
Publication Date: 2013.10.22 MATTHEWS INTERNATIONAL CORP

AI summary

There is disclosed an ink composition and a method of printing and using ink on substrate material comprising polyvinyl chloride with thermal inkjet, drop on demand piezo inkjet, or continuous inkjet by depositing ink comprising vinyl-penetrating solvent, colorant and non-aqueous carrier solvent, the ink being free from polymerizable resins and binders.