Water-Based Ink Set Dynamic Surface Tension Control

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Solution Overview

Problem

Conventional ink-jet recording methods face challenges in reducing bleeding between black and yellow inks and color unevenness when using ordinary paper, as existing solutions either worsen bleeding or deteriorate color mixing quality.

Innovation Solution

A water-based ink set is developed, comprising black, yellow, magenta, and cyan inks, with specific dynamic surface tension relationships (σ1000Bk ≥ 35 mN/m, |σ30Y−σ30Bk| ≤ 5 mN/m, σ30M ≥ 30 mN/m, σ30C ≥ 30 mN/m, σ30Y > σ30M, σ30Y > σ30C, and σ30Y + σ30M/C ≤ 93 mN/m) to prevent blurring, bleeding, and color unevenness.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-generated harmful factors

If a compound such as a surfactant for enhancing penetrability is added to ink, then bleeding between Bk ink and Y ink is improved, but color unevenness in a portion formed by color mixing deteriorates

Engineering Contradiction:
Improvebleeding between Bk ink and Y inkVSAvoidcolor unevenness in color mixing portion
Core Design Contradiction:
Object-generated harmful factorsVSManufacturing precision

Solution Approach 1:

The patent changes the chemical composition parameters of the ink by specifying precise proportions of surfactants (0.01-5 wt%), penetrants (1-20 wt%), and humectants (10-40 wt%). This parameter optimization allows the ink to achieve both reduced bleeding and improved color mixing uniformity, resolving the contradiction between these two quality attributes.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs a composite ink formulation combining multiple functional components: surfactants for surface tension control, penetrants for paper penetration enhancement, and humectants for drying rate control. This composite approach enables simultaneous improvement of bleeding resistance and color mixing uniformity that cannot be achieved with single additives.

Inventive Principle:
Principle #40Composite materials

2Manufacturing precision

If an alkyl ether of polyhydric alcohol is added as a penetrant to improve color unevenness, then color mixing quality is improved, but bleeding between Bk ink and Y ink becomes serious

Engineering Contradiction:
Improvecolor unevenness in color mixing portionVSAvoidbleeding between Bk ink and Y ink
Core Design Contradiction:
Manufacturing precisionVSObject-generated harmful factors

Solution Approach 1:

The patent optimizes the concentration parameter of alkyl ether of polyhydric alcohol penetrant to a specific range (1-20 wt%), preventing excessive penetration that causes bleeding while maintaining sufficient penetrability for uniform color mixing. This precise parameter control resolves the contradiction between color mixing quality and bleeding prevention.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies different functional components with specific local roles: penetrants (alkyl ethers of polyhydric alcohols) are concentrated in amounts that provide sufficient penetration for color mixing uniformity without causing excessive bleeding, while surfactants and humectants are distributed to balance surface tension and drying characteristics locally within the ink formulation.

Inventive Principle:
Principle #3Local quality

3Ease of manufacture

If conventional inks are used for recording on ordinary paper, then cost and environmental friendliness are improved, but bleeding between colors in boundary regions deteriorates

Engineering Contradiction:
Improvecost and environmental friendlinessVSAvoidbleeding between colors in boundary regions
Core Design Contradiction:
Ease of manufactureVSObject-generated harmful factors

Solution Approach 1:

The patent modifies the physical-chemical parameters of conventional ink formulations by adjusting surfactant concentration (0.01-5 wt%), penetrant content (1-20 wt%), and humectant ratios (10-40 wt%). These parameter changes enable the ink to maintain compatibility with ordinary paper (reducing cost and environmental impact) while preventing color bleeding through optimized surface tension and penetration characteristics.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The ink set effectively prevents blurring of black ink, reduces bleeding between inks, and enhances overall penetrability to achieve sharp text and vivid color prints with reduced color unevenness on ordinary paper.

Implementation Method 1

it is effective to set the dynamic surface tension of the Bk ink at a lifetime of 1,000 ms to 35 mN/m or larger

Methodology Applied
Scientific EffectSurface tension: Surface Tension

Data Source

PatentUS7604340B2Water-based ink set for ink-jet recording
Publication Date: 2009.10.20 BROTHER KOGYO KK
  • US7604340B2 patent drawing
  • US7604340B2 patent drawing

AI summary

Provided is a water-based ink set for ink-jet recording for reducing bleeding between a black (Bk) ink and a yellow (Y) ink and for reducing color unevenness in a portion formed by color mixing of color inks. The water-based ink set for ink-jet recording includes at least a Bk ink, a Y ink, a magenta (M) ink and a cyan (C) ink. In this configuration, the following relationships are satisfied:σ1000Bk≧35 mN/m;  (1)|σ30Y−σ30Bk|≦5 mN/m;  (2)σ30M≧30 mN/m, σ30C≧30 mN/m;  (3)σ30Y>σ30M, σ30Y>σ30C; and  (4)σ30Y+σ30M≦93 mN/m, σ30Y+σ30C≦93 mN/m,  (5)wherein σ30Bk, σ30Y, σ30M and σ30C are dynamic surface tensions of the Bk ink, the Y ink, the M ink and the C ink, respectively, at a lifetime of 30 ms as measured by a maximum bubble pressure method at a measurement temperature of 25° C., and σ1000Bk is a dynamic surface tension of the black ink at a lifetime of 1,000 ms as measured by the maximum bubble pressure method at a measurement temperature of 25° C.