Ink Set Surface Tension Control for Bleeding Prevention

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Solution Overview

Problem

Current inkjet recording methods face challenges in producing high-speed, high-resolution color images with minimal bleeding at color boundaries on regular paper with poor ink absorbability or without an aqueous ink-receiving layer, particularly when using inks with high pigment concentration or solid content.

Innovation Solution

An ink set comprising two aqueous inks with different colors, where one ink contains a water-dispersible colorant without a surfactant-based dispersant and the other contains a surfactant-based dispersant, along with specific ratios of wetting agents and water-dispersible resins, to ensure aggregation and improved wettability, reducing bleeding and enhancing image quality.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If inks with high pigment concentration or solid content are used to increase image density, then image density is improved, but ink discharge reliability deteriorates

Engineering Contradiction:
Improveimage densityVSAvoidink discharge reliability
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent adjusts the surface tension of high-concentration inks by adding specific surfactants (anionic, cationic, or nonionic types) to ensure the surface tension is within the range of 20-40 mN/m. This parameter change allows the ink to maintain proper flow and discharge characteristics from the recording head while preserving the high pigment concentration needed for dense images.

Inventive Principle:
Principle #35Parameter changes

2Speed

If ink permeability is enhanced to increase ink dry speed, then ink dry speed is improved, but bleeding occurs in the printed image

Engineering Contradiction:
Improveink dry speedVSAvoidbleeding
Core Design Contradiction:
SpeedVSObject-generated harmful factors

Solution Approach 1:

The patent employs a two-component ink system where one ink contains a water-dispersible colorant without surfactant-based dispersant and the other contains a surfactant-based dispersant. This creates local differences in surface tension and permeability characteristics, allowing controlled ink absorption that prevents bleeding while maintaining acceptable drying speed.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent uses composite ink formulations combining different types of surfactants (anionic, cationic, nonionic) with water-dispersible colorants and resins. This composite approach creates an ink system with balanced surface tension and controlled permeability, achieving both fast drying and bleeding prevention.

Inventive Principle:
Principle #40Composite materials

3Manufacturing precision

If multi-pass printing is employed to suppress ink permeation and increase image density, then image density is improved, but printing speed deteriorates

Engineering Contradiction:
Improveimage densityVSAvoidprinting speed
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The patent modifies the ink's surface tension and composition to achieve optimal permeability characteristics in a single pass. By adjusting surfactant concentration and type, the ink is formulated to provide sufficient density without requiring multiple passes, thereby maintaining high printing speed.

Inventive Principle:
Principle #35Parameter changes

4Object-generated harmful factors

If pectin is added as a thickener to prevent bleeding, then bleeding is prevented, but discharge stability after downtime deteriorates

Engineering Contradiction:
ImprovebleedingVSAvoiddischarge stability
Core Design Contradiction:
Object-generated harmful factorsVSReliability

Solution Approach 1:

The patent removes pectin and similar thickening agents from the ink formulation. Instead, it relies on surfactant-based surface tension control and optimized pigment dispersion to prevent bleeding, thereby maintaining discharge stability and avoiding the clogging problems associated with thickening agents.

Inventive Principle:
Principle #2Taking out (Extraction)

5Object-generated harmful factors

If ink surface tension is reduced to improve wetting and prevent bleeding, then bleeding is reduced, but ink discharge reliability deteriorates

Engineering Contradiction:
ImprovebleedingVSAvoidink discharge reliability
Core Design Contradiction:
Object-generated harmful factorsVSReliability

Solution Approach 1:

The patent optimizes surfactant concentration and type to achieve a balanced surface tension range (20-40 mN/m). This parameter optimization ensures sufficient wetting to prevent bleeding while maintaining proper flow characteristics for reliable discharge from the recording head, avoiding both bleeding and discharge failures.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The ink set enables high-speed printing of sharp, high-resolution color images with reduced bleeding and improved storage stability, suitable for regular paper with poor ink absorbability, by controlling the surface tension and adhesion properties of the mixed ink.

Implementation Method 1

one ink contains a water-dispersible colorant without a surfactant-based dispersant and the other contains a surfactant-based dispersant, along with specific ratios of wetting agents and water-dispersible resins, to ensure aggregation and improved wettability

Methodology Applied
Scientific EffectAggregation: Coagulation

Implementation Method 2

the other contains a surfactant-based dispersant

Methodology Applied
Scientific EffectSurfactant: Surfactant

Implementation Method 3

improved wettability, reducing bleeding and enhancing image quality

Methodology Applied
Scientific EffectWetting: Wetting

Data Source

PatentUS8435339B2Ink set, ink cartridge, inkjet recording method, and inkjet recording apparatus
Publication Date: 2013.05.07 RICOH CO LTD
  • US8435339B2 patent drawing
  • US8435339B2 patent drawing
  • US8435339B2 patent drawing

AI summary

An ink set includes at least two aqueous inks A and B with different colors, the inks A and B used in an inkjet recording method in which the inks A and B are superimposed for formation of a color image, wherein the ink A contains water-dispersible colorant A1 free of a surfactant-based dispersant, and anionic compound A2, and wherein the ink B contains water-dispersible colorant B1 containing a surfactant-based dispersant.