Water-Based Ink Solvent Vapor Pressure Optimization

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Solution Overview

Problem

Water-based inks for ink-jet recording often fail to effectively suppress nozzle clogging and achieve satisfactory drying on recording media due to inappropriate selection of liquid and solid components and their ratios.

Innovation Solution

A water-based ink composition comprising a liquid component with a first water-soluble organic solvent (propylene glycol) and a second water-soluble organic solvent (tripropylene glycol) along with water, and a solid component including specific resins, where the ratio of these components is optimized to prevent nozzle clogging and enhance drying performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If water-based ink is used for ink-jet recording, then drying property on recording medium is improved, but nozzle clogging occurs

Engineering Contradiction:
Improvedrying propertyVSAvoidnozzle clogging
Core Design Contradiction:
TemperatureVSReliability

Solution Approach 1:

The patent changes the physical and chemical parameters of the ink composition by specifying precise vapor pressure ranges for organic solvents (first solvent: 7-100 Pa, second solvent: 0.1-1 Pa at 20°C) and content ratios ((A+B+C)/D = 2-6, (B+C)/D = 0.2-1.0) to simultaneously achieve rapid drying and prevent nozzle clogging. This parameter optimization resolves the contradiction between drying performance and nozzle reliability.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs a composite liquid component system combining water with multiple organic solvents having different vapor pressure characteristics. The first water-soluble organic solvent (higher vapor pressure) provides rapid evaporation for quick drying, while the second water-soluble organic solvent (lower vapor pressure) prevents excessive evaporation that causes nozzle clogging. This composite approach balances drying speed and nozzle reliability.

Inventive Principle:
Principle #40Composite materials

2Reliability

If liquid component ratio is increased to prevent nozzle clogging, then drying property deteriorates

Engineering Contradiction:
Improvenozzle clogging suppressionVSAvoiddrying state
Core Design Contradiction:
ReliabilityVSTemperature

Solution Approach 1:

The patent optimizes the balance between liquid and solid components by controlling the ratio (A+B+C)/D within 2-6 and (B+C)/D within 0.2-1.0, where A, B, and C represent different liquid components and D represents solid component. This precise parameter control ensures sufficient liquid content for nozzle flowability while maintaining adequate solid content for proper drying, resolving the trade-off between preventing clogging and achieving satisfactory drying.

Inventive Principle:
Principle #35Parameter changes

3Temperature

If solid component ratio is increased to improve drying property, then nozzle clogging worsens

Engineering Contradiction:
Improvedrying stateVSAvoidnozzle clogging
Core Design Contradiction:
TemperatureVSReliability

Solution Approach 1:

The patent controls the solid component content (D) relative to liquid components through optimized ratios, ensuring (A+B+C)/D falls within 2-6. This prevents excessive solid content that would cause nozzle clogging while maintaining sufficient solid content for proper drying and film formation, thus resolving the contradiction between drying performance and nozzle reliability.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The optimized composition effectively suppresses nozzle clogging and achieves a satisfactory drying state on the recording medium, while also improving the flexibility and anti-scratching properties of the printed material.

Implementation Method 1

a first water-soluble organic solvent of which vapor pressure at 20°C is not less than 7 Pa; a second water-soluble organic solvent of which vapor pressure at 20°C is not more than 1 Pa

Methodology Applied
Scientific EffectVapor pressure: Vapour Pressure

Data Source

PatentEP3976719B1Water-based ink for ink-jet recording and ink-jet recording apparatus
Publication Date: 2023.11.22 BROTHER KOGYO KK
  • EP3976719B1 patent drawingFigure 1
  • EP3976719B1 patent drawing
  • EP3976719B1 patent drawing

AI summary

A water-based ink for ink-jet recording includes: a liquid component which is liquid at 20℃; and a solid component which is solid at 20℃. The liquid component includes: a first water-soluble organic solvent of which vapor pressure at 20℃ is not less than 7 Pa; a second water-soluble organic solvent of which vapor pressure at 20℃ is not more than 1 Pa; and water. The solid component includes at least one resin selected from the group consisting of: acrylic acid-based resin, maleate ester-based resin, vinyl acetate-based resin, carbonate-based resin, styrene-based resin, ethylene-based resin, propylene-based resin, urethane-based resin, vinyl chloride-based resin and copolymer resin thereof.