Ink Formulation Wax Solubility Nozzle Clogging

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Solution Overview

Problem

Inkjet printers face challenges in achieving high image fixability, abrasion resistance, and stability due to pigment adherence issues on plain paper, with added wax causing nozzle clogging and discharging instability.

Innovation Solution

An ink formulation incorporating a pigment, a water-soluble solvent with an SP value of 9.0 to 11.0, and wax, with a specific mass ratio of wax to solvent, improving compatibility and stability while preventing wax precipitation in nozzles.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If wax is added to improve image fixability, then image fixability and abrasion resistance are improved, but wax precipitates in nozzles causing discharging instability

Engineering Contradiction:
Improveimage fixabilityVSAvoiddischarging stability
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

A water-soluble surfactant is introduced as an intermediary substance to mediate between the wax and water-based ink components. The surfactant forms micelles that solubilize wax molecules, preventing their precipitation in nozzles while still allowing the wax to provide its fixability function on the printed image.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The solubility parameters of the ink formulation are changed by selecting specific water-soluble solvents and surfactants with appropriate HLB values and critical micelle concentrations. This allows the wax to remain solubilized under inkjet operating conditions while maintaining its functionality on the printed surface.

Inventive Principle:
Principle #35Parameter changes

2Strength

If a large amount of resins is added to improve binding property, then pigment binding is improved, but the ink formulation becomes complex and may affect discharging stability

Engineering Contradiction:
Improvebinding propertyVSAvoidink formulation complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The function of resin binding is extracted and replaced by using inorganic particles with surface treatments that provide binding functionality without requiring large amounts of organic resin. This simplifies the ink formulation while maintaining pigment binding capability.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

Composite inorganic particles are used that combine multiple functions: pigment binding, dispersion stability, and controlled release. These composite particles replace complex resin systems with a simpler inorganic-based solution.

Inventive Principle:
Principle #40Composite materials

3Quantity of substance

If pigments are placed on the surface of plain paper to achieve high image density, then image density and saturation are improved, but image fixability deteriorates because pigments easily come off

Engineering Contradiction:
Improveimage densityVSAvoidimage fixability
Core Design Contradiction:
Quantity of substanceVSStrength

Solution Approach 1:

Composite inorganic particles combining pigment with binder materials are used to create a unified structure that provides both high density and strong adhesion. The inorganic composite particles prevent pigment detachment while maintaining surface concentration for high image density.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The pigment particles are segmented into smaller sizes with controlled surface properties, allowing them to pack more densely on the paper surface while individual particles maintain strong adhesion through surface treatment.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enhances image fixability, abrasion resistance, and storage stability while maintaining discharging stability, preventing wax precipitation in nozzles and ensuring consistent ink performance.

Implementation Method 1

a water soluble solvent including a solvent having an SP value of from 9.0 to 11.0

Methodology Applied
Scientific EffectSolvation: Solvation

Data Source

PatentUS10280321B2Ink, ink container, inkjet recording device, and recorded matter
Publication Date: 2019.05.07 RICOH CO LTD
  • US10280321B2 patent drawing
  • US10280321B2 patent drawing
  • US10280321B2 patent drawing

AI summary

An ink includes a pigment, a wax, a water soluble solvent including a solvent having an SP value of from 9.0 to 11.0, and water, wherein the mass ratio of the content of the wax in the ink to the content of the solvent having an SP value of from 9.0 to 11.0 is in a range of from 1.0:2.5 to 1.0:25.0.