Inkjet Adhesive for Semiconductor Bonding

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Solution Overview

Problem

Conventional adhesives used in semiconductor manufacturing face challenges such as void generation, reduced adhesiveness, and reliability issues, especially when dealing with substrates having height differences in wiring patterns, leading to defects and reduced yield in semiconductor devices.

Innovation Solution

An inkjet adhesive comprising a photocurable compound, a photo-radical initiator, a thermosetting compound with cyclic ether or cyclic thioether groups, and a compound capable of reacting with the thermosetting compound, including aromatic amine, which is applied using an inkjet device, cured by light irradiation, and then thermally cured to form a B-staged adhesive layer, suppressing voids and enhancing adhesiveness and reliability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If paste-like adhesive is used for joining semiconductor elements, then adhesive application is simple, but the adhesive spreads causing protrusion and thickness control is difficult

Engineering Contradiction:
Improveadhesive application simplicityVSAvoidadhesive thickness control
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent replaces paste-like adhesive application with inkjet adhesive application. The inkjet method uses a deposition head to precisely deposit adhesive material drop by drop at predetermined positions, replacing the mechanical spreading process with a controlled deposition process that eliminates protrusion and enables precise thickness control.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent changes the physical state of the adhesive from paste-like to inkjet-applicable viscosity. The adhesive composition is modified to have specific viscosity characteristics that enable precise deposition through the inkjet head while maintaining proper adhesion properties for semiconductor element bonding.

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If adhesive sheet with film-like adhesive layer is used, then thickness control is improved, but the adhesive sheet clings to cutting blade during dicing causing chip defects

Engineering Contradiction:
Improveadhesive thickness controlVSAvoidadhesive sheet clinging to cutting blade
Core Design Contradiction:
Manufacturing precisionVSObject-generated harmful factors

Solution Approach 1:

The patent replaces the adhesive sheet process with direct inkjet deposition of adhesive onto the semiconductor element. This eliminates the dicing step entirely, removing the problem of adhesive sheets clinging to cutting blades and causing chip defects, while maintaining precise thickness control through controlled deposition.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Ease of manufacture

If conventional adhesive is used on substrate with height difference of wiring pattern, then application is straightforward, but voids easily remain in height difference portion reducing reliability

Engineering Contradiction:
Improveadhesive application processVSAvoidadhesive bonding reliability
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent applies adhesive locally at predetermined positions using the inkjet deposition head rather than uniformly across the entire substrate. This localized application ensures adhesive is deposited only where needed, filling height difference portions and eliminating void formation while maintaining a simple application process.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent replaces conventional adhesive application methods with inkjet deposition that can precisely target and fill height difference portions of the wiring pattern. The controlled deposition process ensures complete filling of uneven surfaces without leaving voids, significantly improving bonding reliability.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

4Ease of manufacture

If conventional adhesive is used, then initial bonding is achieved, but adhesiveness becomes low when exposed to extreme conditions such as high temperature or high humidity

Engineering Contradiction:
Improvebonding processVSAvoidadhesiveness under extreme conditions
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent uses a composite adhesive composition containing multiple functional components: polyol, isocyanate compound, silane-modified epoxy resin, and inorganic filler. This composite formulation provides both initial bonding capability and enhanced resistance to extreme conditions including high temperature and high humidity, maintaining adhesiveness where conventional adhesives fail.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The inkjet adhesive effectively prevents void formation, improves adhesiveness, and enhances moisture-resistant and thermal cycling reliability, ensuring higher accuracy in adhesive layer thickness and improved semiconductor device performance.

Implementation Method 1

an inkjet adhesive comprising a photocurable compound, a photo-radical initiator

Methodology Applied
Scientific EffectPhotopolymerization: Photopolymerisation

Implementation Method 2

a thermosetting compound having one or more cyclic ether groups or cyclic thioether groups, and a compound capable of reacting with the thermosetting compound, including aromatic amine

Methodology Applied
Scientific EffectThermal curing:

Data Source

PatentUS10961411B2Inkjet adhesive, manufacturing method for semiconductor device, and electronic component
Publication Date: 2021.03.30 SEKISUI CHEMICAL CO LTD
  • US10961411B2 patent drawing
  • US10961411B2 patent drawing
  • US10961411B2 patent drawing

AI summary

Provided is an inkjet adhesive which is applied using an inkjet device, wherein the adhesive can suppress generation of voids in the adhesive layer and, after bonding, can enhance adhesiveness, moisture-resistant adhesion reliability, and cooling/heating cycle reliability. An inkjet adhesive according to the present invention comprises a photocurable compound, a photo-radical initiator, a thermosetting compound having one or more cyclic ether groups or cyclic thioether groups, and a compound capable of reacting with the thermosetting compound, and the compound capable of reacting with the thermosetting compound contains aromatic amine.