Inkjet Image Fixability on Coated Paper via Polyurethane Resin After-Treatment

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Solution Overview

Problem

Existing image forming methods for commercial printing on coated papers fail to achieve good fixability and anti-blocking due to the papers' low water absorbability, which affects the quality of inkjet-printed images.

Innovation Solution

An image forming method involving the discharge of an inkjet ink containing water-dispersible pigments, wetters, surfactants, and penetrants, followed by an after-treatment liquid with water-dispersible polyurethane resin and waxes, specifically designed to improve image adherence and resistance on coated papers.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If an aqueous ink set is used on coated papers for commercial printing, then the inkjet recording can be performed, but the images have poor fixability and anti-blocking due to low water absorbability of the coated papers

Engineering Contradiction:
Improveinkjet recording capabilityVSAvoidimage fixability and anti-blocking
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The patent introduces a specific after-treatment liquid as an intermediary substance between the aqueous ink and the coated paper. This after-treatment liquid contains polyurethane resin, polyester resin, and wax components that act as mediators to improve image fixability and anti-blocking properties on water-resistant coated papers without requiring the paper to absorb water

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent changes the chemical composition parameters of the after-treatment liquid, specifically incorporating polyurethane resin with specific molecular weight, polyester resin, and wax components in controlled ratios. These parameter changes enable the after-treatment liquid to provide both fixability and anti-blocking properties that standard aqueous ink systems cannot achieve alone

Inventive Principle:
Principle #35Parameter changes

2Adaptability or versatility

If the coated papers for commercial printing are used, then the commercial printing requirement is met, but the images cannot achieve good anti-friction and fixability

Engineering Contradiction:
Improvecommercial printing applicabilityVSAvoidimage quality (fixability and anti-friction)
Core Design Contradiction:
Adaptability or versatilityVSManufacturing precision

Solution Approach 1:

The after-treatment liquid serves as a mediator that bridges the gap between the requirements of commercial printing (using coated papers) and the need for high-quality image fixability and anti-friction properties. The specific formulation of polyurethane resin, polyester resin, and wax components in the after-treatment liquid enables both commercial printing applicability and manufacturing precision

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The after-treatment liquid employs a composite material system combining polyurethane resin, polyester resin, and wax components. This composite approach leverages the complementary properties of each material: polyurethane for adhesion, polyester for durability, and wax for anti-friction and anti-blocking, thereby achieving high-quality images on commercially viable coated papers

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method effectively enhances image fixability and anti-blocking on coated papers, ensuring high-quality prints with improved durability and resistance.

Implementation Method 1

the dispersed phase of the water-dispersible polyurethane resin dispersed in the water has a median diameter of from 0.01 to 0.10 μm

Methodology Applied
Scientific EffectDispersion: Dispersion (of waves)

Implementation Method 2

an inkjet ink including a water-dispersible pigment, a wetter, a surfactant, a penetrant and water

Methodology Applied
Scientific EffectSurfactant: Surfactant

Implementation Method 3

a penetrant and water on a surface of a recording medium

Methodology Applied
Scientific EffectPenetration: Permeation

Data Source

PatentEP2752303B1Image forming method
Publication Date: 2014.12.24 RICOH CO LTD
  • EP2752303B1 patent drawing
  • EP2752303B1 patent drawing
  • EP2752303B1 patent drawing

AI summary

An image forming method includes discharging an Inkjet ink including a water-dispersible colorant, a wetter, a surfactant, a penetrant and water on a surface of a recording medium; and applying an after-treatment liquid including a water-dispersible polyurethane resin having a median diameter of from 0.01 to 0.10 µm, water and at least one of a polyethylene wax and a paraffin wax on the surface of the recording medium on which the inkjet ink is discharged.