Inkjet Decorative Laminate Coating for Adhesion and Pattern Alignment

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Solution Overview

Problem

The manufacturing of decorative laminates using inkjet technology faces challenges with adhesion issues between acrylate ink layers and melamine resin, particularly at high ink coverages, and dimensional instability of decor paper during thermosetting resin impregnation, which affects the alignment of embossed wood grain patterns.

Innovation Solution

A method involving the use of aqueous pigmented inkjet inks with an inorganic pigment and polymeric binder in a specific ratio, applied to an ink acceptance layer on fully impregnated base paper, allowing for improved adhesion and dimensional stability, enabling precise alignment of wood grain patterns and simplifying the manufacturing process by eliminating the need for intermediate decor printers and warehouses.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If acrylate inkjet inks are used for printing decorative patterns, then excellent image quality is achieved, but adhesion problems occur between the ink layer and melamine resin protective layer

Engineering Contradiction:
Improveimage qualityVSAvoidadhesion between ink layer and protective layer
Core Design Contradiction:
Manufacturing precisionVSStrength

Solution Approach 1:

A primer layer is introduced as an intermediary between the acrylate inkjet printed decorative pattern and the melamine resin protective layer. This primer layer serves as a bonding interface that ensures proper adhesion of the protective layer to the printed pattern, eliminating the adhesion problems that would otherwise occur between the non-porous acrylate ink layer and the melamine resin.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The coating structure is segmented into distinct functional layers: the acrylate inkjet printed decorative pattern layer, a primer layer in between, and the melamine resin protective layer. This segmentation allows each layer to perform its specific function optimally - the ink layer provides the decorative pattern, the primer provides adhesion, and the protective layer provides durability.

Inventive Principle:
Principle #1Segmentation

2Ease of manufacture

If decor paper is impregnated with thermosetting resin after inkjet printing, then dimensional instability occurs affecting alignment of embossed wood grain patterns

Engineering Contradiction:
Improveintegration of printing and impregnation processesVSAvoidalignment of embossed wood grain with decorative pattern
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The inkjet printing of the decorative pattern is performed preliminarily before the impregnation with thermosetting resin. This preliminary action allows the decorative pattern to be established on the paper substrate before the resin impregnation and subsequent embossing processes, ensuring that the pattern alignment is maintained throughout manufacturing.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

A primer layer is applied as an intermediary coating between the inkjet printed decorative pattern and the thermosetting resin impregnation. This primer layer acts as a stable interface that prevents dimensional instability from affecting the alignment of the decorative pattern during the embossing process, ensuring precise alignment between the printed pattern and the embossed wood grain.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Productivity

If gravure printing is used for manufacturing decorative paper rolls, then production efficiency is maintained, but flexibility for variable data printing and short production runs is limited

Engineering Contradiction:
Improveproduction efficiencyVSAvoidflexibility for variable data printing
Core Design Contradiction:
ProductivityVSAdaptability or versatility

Solution Approach 1:

The mechanical gravure printing system is replaced with an inkjet printing system. This substitution eliminates the need for physical printing plates and allows for digital, variable data printing. The inkjet system maintains production efficiency while providing the flexibility to quickly change decorative patterns and produce short runs without the constraints of gravure printing setup.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach ensures excellent image quality and adhesion, reduces storage needs, minimizes paper loss, and allows for rapid design changes and cost-efficient short print runs, enhancing product variety and adaptability to market trends.

Implementation Method 1

jetting ink droplets having a volume of up to 30 pL of one or more aqueous pigmented inkjet inks onto the dried ink acceptance layer

Methodology Applied
Scientific EffectInkjet deposition: Deposition (physical)

Implementation Method 2

The ink acceptance layer contains an inorganic pigment P and a polymeric binder B in a weight ratio P/B larger than 1.5, wherein the decorative layer includes the paper substrate impregnated by a thermosetting resin, an ink acceptance layer containing an inorganic pigment P and a polymeric binder B having a weight ratio of inorganic pigment to polymeric binder (P/B ratio) of larger than 1.5

Methodology Applied
Scientific EffectAdhesion: Adhesive

Implementation Method 3

The cause of these adhesion problems is that the water vapour produced during the polycondensation of the melamine cannot penetrate through the polymerized acrylate ink layer

Methodology Applied
Scientific EffectPolycondensation:

Implementation Method 4

the water vapour produced during the polycondensation of the melamine

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 5

curing the resin mixture (5, 21) by means of a heated press (7)

Methodology Applied
Scientific EffectThermal curing: Heat Treatment

Data Source

PatentEP3212427B1Manufacturing methods of decorative laminates by inkjet
Publication Date: 2023.09.20 AGFA NV
  • EP3212427B1 patent drawingFigure 1~4

AI summary

Manufacturing method of decorative laminates including the steps of: a) printing an ink acceptance layer by jetting droplets having a volume of 1 to 200 nL onto a paper substrate; b) forming a decorative layer by jetting ink droplets having a volume of up to 30 pL of one or more aqueous pigmented inkjet inks onto the dried ink acceptance layer; and c) heat pressing the decorative layer into a decorative laminate; wherein the ink acceptance layer contains an inorganic pigment P and a polymeric binder B in a weight ratio P/B larger than 1.5.