Inkjet Nozzle Stability via TiO2 Particle Control

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Solution Overview

Problem

Inkjet printing methods face challenges with long-term discharging stability, particularly with single-pass printing, as pigments in white inks tend to settle in nozzles, leading to printing failures due to the high pigment specific gravity of white pigments.

Innovation Solution

A liquid discharging apparatus and method using an ink composition containing water, an organic solvent, at least two kinds of urethane resins, and titanium oxide, with a titanium oxide content of 20-30% by mass and a volume average particle diameter of 300-630 nm, which is circulated through a liquid discharging head with a nozzle, enhancing discharging stability and hiding power.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If white ink with high pigment specific gravity is used for single-pass printing, then printing speed is improved, but pigment settles in nozzles causing discharging failure

Engineering Contradiction:
Improveprinting speedVSAvoiddischarging stability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent changes the particle size parameter of titanium oxide from conventional larger sizes to specifically 300-630 nm range, and adjusts pigment content to 20-30% by mass. These parameter modifications prevent sedimentation while maintaining high hiding power, enabling stable single-pass printing with white ink

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses a composite ink formulation combining titanium oxide pigment with specific resin components and solvents. This composite structure ensures uniform dispersion and prevents pigment settling, resolving the contradiction between high productivity and discharging reliability

Inventive Principle:
Principle #40Composite materials

2Illumination intensity

If titanium oxide content is increased to improve hiding power, then image quality is improved, but ink viscosity increases affecting discharging

Engineering Contradiction:
Improvehiding powerVSAvoidink viscosity
Core Design Contradiction:
Illumination intensityVSStress or pressure

Solution Approach 1:

The patent optimizes titanium oxide particle size to 300-630 nm and content to 20-30% by mass. This parameter combination achieves high hiding power while controlling viscosity by reducing inter-particle aggregation, allowing smooth ink discharge

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces specific resin components and surfactants as intermediaries between titanium oxide particles and the continuous phase. These intermediaries improve dispersion and reduce viscosity, enabling high pigment content without compromising flowability

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides high printing stability and excellent hiding power even with single-pass printing methods by preventing titanium oxide settling and maintaining uniform dispersion, ensuring consistent ink flow and image quality.

Implementation Method 1

white inks using white pigments have a high pigment specific gravity. Therefore, if printing apparatuses are suspended for a long period, the pigments settle in the nozzles

Methodology Applied
Scientific EffectSedimentation: Sedimentation

Implementation Method 2

an individual liquid chamber having a circulation flow path through which the ink is circulated

Methodology Applied
Scientific EffectCirculation flow: Convection

Data Source

PatentUS11745515B2Liquid discharging apparatus and liquid discharging method
Publication Date: 2023.09.05 RICOH CO LTD
  • US11745515B2 patent drawing
  • US11745515B2 patent drawing
  • US11745515B2 patent drawing

AI summary

Provided is a liquid discharging apparatus including: a storage storing an ink containing water, an organic solvent, at least two kinds of urethane resins, and titanium oxide; and a liquid discharging head. The liquid discharging head includes an individual liquid chamber having a circulation flow path through which the ink is circulated. The liquid discharging head has a nozzle communicating with the individual liquid chamber and through which a liquid droplet of the ink is discharged. The content of the titanium oxide in the ink is 20% by mass or greater but 30% by mass or less. The volume average particle diameter of the titanium oxide is 300 nm or greater but 630 nm or less.