Inkjet-Printed Nanoparticle Alignment for Liquid Crystals

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Solution Overview

Problem

Current methods for patterned alignment of liquid crystals are complex, costly, and require multiple fabrication steps, limiting the development of low-cost electro-optical devices such as adaptive lenses and Bragg diffraction gratings.

Innovation Solution

Ink-jet printing of nanoparticles capped with a protective layer of hydrocarbon chains and a single solvent with specific viscosity and surface tension, allowing for precise and versatile patterned alignment of liquid crystals on various substrates, including flexible ones.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional methods (rubbing, ion-beam deposition, photoalignment) are used for liquid crystal alignment, then alignment quality can be achieved, but the process complexity and manufacturing cost increase significantly

Engineering Contradiction:
Improvealignment qualityVSAvoidprocess complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent replaces mechanical rubbing methods with inkjet printing of nanoparticle suspensions. Instead of using velvet cloths or rubbing machines to align liquid crystals, the invention uses inkjet printers to deposit functional nanoparticle patterns that self-organize to provide alignment. This substitution eliminates mechanical complexity while maintaining alignment quality.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The invention changes the fundamental parameter of alignment layer deposition from complex physical/chemical processes (ion-beam, plasma, photoalignment) to a simple inkjet printing process. By controlling nanoparticle suspension parameters (concentration, solvent composition, drying conditions), the patent achieves reliable alignment with a single-step printing process, dramatically reducing process complexity.

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If multiple fabrication steps are used for patterned alignment, then precise alignment patterns can be created, but production time and cost increase

Engineering Contradiction:
Improvealignment pattern precisionVSAvoidproduction speed
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The patent combines multiple fabrication steps into a single inkjet printing operation. Instead of separate steps for depositing alignment layers, creating patterns, and treating surfaces, the invention directly prints functional nanoparticle patterns that perform all functions simultaneously. This merging maintains pattern precision while dramatically increasing production speed.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The nanoparticle suspensions are formulated to self-organize and self-align after deposition without requiring additional processing steps. The particles automatically arrange themselves to create the desired alignment patterns, eliminating the need for post-deposition treatments or multiple fabrication steps, thus improving productivity while maintaining precision.

Inventive Principle:
Principle #25Self-service

3Manufacturing precision

If traditional alignment methods are used, then liquid crystal alignment can be achieved, but the methods are not suitable for flexible substrates

Engineering Contradiction:
Improvealignment qualityVSAvoidsubstrate flexibility
Core Design Contradiction:
Manufacturing precisionVSAdaptability or versatility

Solution Approach 1:

The inkjet printing method is universally applicable to various substrate types including flexible polymers, glass, and plastics. The nanoparticle suspensions can be deposited on any surface that accepts inkjet printing, making the alignment process adaptable to flexible substrates where conventional rubbing and ion-beam methods fail. This universality maintains alignment quality across different substrate types.

Inventive Principle:
Principle #6Universality (Multi-functionality)

4Manufacturing precision

If conventional alignment layers are used, then homogeneous alignment can be achieved, but patterned alignment requires complex photolithography

Engineering Contradiction:
Improvealignment uniformityVSAvoidpatterning complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The inkjet printing process enables direct local patterning of nanoparticle suspensions to create spatially varying alignment patterns. Different regions of the substrate receive different nanoparticle patterns during printing, allowing simultaneous creation of both uniformly aligned regions and locally patterned regions without requiring photolithography. This local quality control achieves both homogeneous and patterned alignment with a single process.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables quick, simple, and adaptable liquid crystal alignment with high precision, reducing production costs and enabling the creation of low-cost electro-optical devices with improved scalability and substrate flexibility.

Implementation Method 1

a single solvent exhibiting a single evaporation rate

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 2

nanoparticles capped with a protective layer of hydrocarbon chains

Methodology Applied
Scientific EffectHydrophobic interaction: Hydrophobe

Data Source

PatentUS10788713B2Patterned liquid crystal alignment using ink-jet printed nanoparticles and use thereof to produce patterned, electro-optically addressable devices; ink-jet printable compositions
Publication Date: 2020.09.29 KENT STATE UNIV
  • US10788713B2 patent drawing
  • US10788713B2 patent drawing
  • US10788713B2 patent drawing

AI summary

Ink-jet printable compositions including nanoparticles capped with a protective layer of hydrocarbon chains and a single solvent exhibiting a single evaporation rate and having a specifically defined viscosity and surface tension that result in uniform and printable alignment layers for liquid crystal materials. Patterned liquid crystal-containing cells are also disclosed including one or more layers including the same or different nanoparticles capped with a protective layer of hydrocarbon chains printed on a surface of a substrate or even another nanoparticle-containing layer. Methods for producing the cells are also disclosed, including the step of printing a pattern on one or more portions of a cell surface utilizing a composition comprising the capped nanoparticles. Devices including the cells are also disclosed.